Protective film having variable adhesive force for foldable display and foldable display device including same
A protective film and display technology, applied to film/sheet adhesives, household appliances, identification devices, etc., can solve the problem of protective film detachment
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[0079] Hereinafter, the present disclosure will be described in detail with reference to examples. However, the embodiments according to the present disclosure may be modified into various forms, and the scope of the present disclosure should not be construed as being limited to the embodiments described below. The examples in this specification are provided so that those skilled in the art will more fully describe the present disclosure.
[0080] Production of (meth)acrylate resins
[0081] Production Examples 1 to 8
[0082] The components were mixed together in the amounts described in Table 1 below, and each mixture was subjected to solution polymerization to produce a (meth)acrylate resin.
[0083] [Table 1]
[0084]
[0085] In Table 1 above, 2-EHA is 2-ethylhexyl acrylate, LA is lauryl acrylate, and MA is methyl acrylate. In addition, BPMA is 4-benzoylphenyl (meth)acrylate, BPMAm is N-(2-benzoylphenyl)acrylamide, AA is acrylic acid, 4-HBA is 4-hydroxybutyl acry...
Embodiment 1
[0090] 0.03 parts by weight of an epoxy compound-based curing agent BXX-5240 was added and dispersed in the (meth)acrylate resin produced in Production Example 1, whereby an adhesive composition was prepared. Next, the adhesive composition was applied on a U483 50-μm PET film (Toray Co., Ltd.), then dried and cured to a final thickness of 25 μm, thereby manufacturing a foldable display protective film.
Embodiment 2 to 5 and comparative example 1 to 4
[0092] A foldable display protective film was manufactured in the same manner as in Example 1 above, except that a curing agent and / or a photoinitiator was added and dispersed in the (meth)acrylate resin as described in Table 2 below.
[0093] [Table 2]
[0094]
[0095] In Table 2 above, BXX-5240 is an epoxy-based curing agent, TKA-100 and MHG-80B are isocyanate-based curing agents, and IRG 184 is Irgacure 184.
[0096] Evaluation of Physical Properties
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