Fluorine-containing hazardous waste stabilized solidified body and preparation method thereof
A solidified, hazardous waste technology, applied in chemical instruments and methods, transportation and packaging, etc., to achieve the effect of simple process, small number of equipment, and uniform physical state
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[0040] The preparation method of the fluorine-containing hazardous waste stabilized solidification body as described in the first aspect of the present invention involved in the second aspect of the present invention can be understood as a method for stabilizing and solidifying fluorine-containing hazardous waste, or a method for stabilizing and solidifying fluorine-containing hazardous waste. A method for stabilizing and solidifying hazardous waste materials containing fluorine, comprising the following steps:
[0041] (1) Detection of hazardous waste to be treated: take an appropriate amount of fluorine-containing hazardous waste, and detect the content of inorganic fluoride, cyanide and heavy metal in its leachate. If it is equal to the allowable landfill control limit of hazardous waste in the National Hazardous Waste Landfill Pollution Control Standard, then the fluorine-containing hazardous waste is a fluorine-containing hazardous waste raw material that needs to be solid...
Embodiment 1
[0058] (1) Detection of hazardous waste to be treated: take an appropriate amount of fluorine-containing hazardous waste to be treated, and conduct a leaching toxicity test. The result shows that the index of inorganic fluoride is 2158mg / L, the index of beryllium is 0.4mg / L, and the index of cyanide is 52mg / L , and in the national safety landfill pollution control standard, the index of inorganic fluoride should be controlled below 120mg / L, the index of beryllium should be controlled below 0.2mg / L, and the index of cyanide should be controlled below 6mg / L. Obviously, the initial leaching toxicity of this hazardous waste far exceeds the national safety landfill pollution control standard, and solidification and stabilization treatment is required.
[0059] (2) Ready-mixed reaction: Add 100kg of fluorine-containing hazardous waste to be treated into the stirring reactor, add 14kg (the mass ratio of curing agent to fluorine-containing hazardous waste raw materials is 0.14:1) quick...
Embodiment 2
[0069] (1) Detection of hazardous waste to be treated: take an appropriate amount of fluorine-containing hazardous waste to be treated, and conduct a leaching toxicity test. The result shows that the index of inorganic fluoride is 3652mg / L, the index of lead is 2.2mg / L, and the index of cyanide is 75mg / L , and in the national safety landfill pollution control standard, the index of inorganic fluoride should be controlled below 120mg / L, the index of lead should be controlled below 1.2mg / L, and the index of cyanide should be controlled below 6mg / L. Obviously, the initial leaching toxicity of this hazardous waste far exceeds the national safety landfill pollution control standard, and solidification and stabilization treatment is required.
[0070] (2) Ready-mixed reaction: Add 100kg of fluorine-containing hazardous waste to be treated into the stirring reactor, add 25kg (the mass ratio of curing agent to fluorine-containing hazardous waste raw material is 0.25:1) quicklime and 20...
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