Tear-resistant mold silicone rubber and preparation method thereof

A silicone rubber and tear-resistant technology, applied in the field of tear-resistant mold silicone rubber and its preparation, can solve the problem that the silicone rubber mold is not resistant to reactive diluents, the tear resistance of the silicone rubber mold is not high, and the silicone rubber mold is cracked and turned over. The number of times and other problems can be achieved to prevent the breaking of the molecular chain of the silicone rubber, the breaking of the molecular chain of the good silicone rubber, and the corrosion resistance of epoxy resin.

Inactive Publication Date: 2021-11-16
沅陵县成瑞祥粉体材料科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Most of them are accessories molded by epoxy resin, and the molding of epoxy resin is based on the vulcanized two-component liquid silicone rubber as the master mold, that is, the silicone rubber mold is molded. At this stage, silicone rubber molds are common in the market After turning the mold 21 to 25 times, there will be cracks at the edges and corners of the silicone rubber mold, and more seriously, the entire silicone rubber mold will crack. The reasons for the cracking of the silicone rubber mold and the low number of mold turning are: The tear strength is not high, and the silicone rubber mold is not resistant to the erosion of epoxy resin ammonia curing agent and active diluent, etc.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0023] A tear-resistant mold silicone rubber is characterized in that it is composed of the following components by mass: 100 parts of terminal vinyl polydimethylsiloxane, end chain and side chain high vinyl polydimethylsiloxane 10 parts, 21 parts of terminal chain hydroxyl side chain vinyl polydimethylsiloxane, 32 parts of fumed silica, 1.2 parts of catalyst, 19 parts of terminal vinyl polydimethylsiloxane, terminal chain and side chain containing Hydrogen polydimethylsiloxane 78 parts, acetylenic alcohol reaction inhibitor 0.4 part, free radical scavenger 0.13 part.

[0024] Wherein, the catalyst is a vinyl Pt complex catalyst.

[0025] Wherein, the acetylenic alcohol reaction inhibitor is ethynylmethanol.

Embodiment 2

[0027] A tear-resistant mold silicone rubber is characterized in that it is composed of the following components by mass: 115 parts of terminal vinyl polydimethylsiloxane, end chain and side chain high vinyl polydimethylsiloxane 9 parts, terminal chain hydroxyl side chain vinyl polydimethylsiloxane 18 parts, fumed silica 37 parts, catalyst 0.7 parts, terminal vinyl polydimethylsiloxane 25 parts, terminal chain and side chain containing 85 parts of hydropolydimethylsiloxane, 0.3 part of acetylenic alcohol reaction inhibitor, and 0.1 part of free radical scavenger.

[0028] Wherein, the catalyst is a vinyl Pt complex catalyst.

[0029] Wherein, the acetylenic alcohol reaction inhibitor is propargyl alcohol.

Embodiment 3

[0031] A tear-resistant mold silicone rubber is characterized in that it is composed of the following components by mass: 106 parts of terminal vinyl polydimethylsiloxane, end chain and side chain high vinyl polydimethylsiloxane 14 parts, terminal chain hydroxyl side chain vinyl polydimethylsiloxane 16 parts, fumed silica 35 parts, catalyst 1.3 parts, terminal vinyl polydimethylsiloxane 15 parts, terminal chain and side chain containing Hydrogen polydimethylsiloxane 75 parts, acetylenic alcohol reaction inhibitor 0.25 part, free radical scavenger 0.16 part.

[0032] Wherein, the catalyst is a vinyl Pt complex catalyst.

[0033] Wherein, the acetylenic alcohol reaction inhibitor is propynyl alcohol.

[0034] A kind of tear-resistant mold silicone rubber described in the above-mentioned embodiments 1-3 is prepared by the following method:

[0035] A preparation method of tear-resistant mold silicone rubber, is characterized in that, comprises the steps:

[0036] S1. Put the t...

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PUM

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Abstract

The invention discloses tear-resistant mold silicone rubber. The tear-resistant mold silicone rubber is prepared from the following ingredients in parts by mass: 100 to 120 parts of vinyl-terminated polydimethylsiloxane, 5 to 15 parts of terminal chain and side chain high vinyl polydimethylsiloxane, 15 to 25 parts of terminal chain hydroxyl side chain vinyl polydimethylsiloxane, 30 to 45 parts of fumed silica, 0.6 to 1.4 parts of a catalyst, 10 to 30 parts of vinyl-terminated polydimethylsiloxane, 70 to 90 parts of terminal chain and side chain hydrogen-containing polydimethylsiloxane, 0.2 to 0.6 part of alkynol reaction inhibitor and 0.1 to 0.2 part of free radical scavenger. The invention further discloses a preparation method of the tear-resistant mold silicone rubber. The tear-resistant mold silicone rubber is obtained through kneading, vacuumizing, stirring, filtering, defoaming and vulcanization forming. The tear-resistant mold silicone rubber has the advantages of good tear resistance and stable performance.

Description

technical field [0001] The invention relates to the technical field of organic silica gel materials, in particular to a tear-resistant mold silicone rubber and a preparation method thereof. Background technique [0002] With the increasing demand for decorative products in China, Europe, America, India, and the Middle East, a large number of enterprises producing lighting accessories, clothing accessories, shoes and hat accessories, handicrafts, nail accessories, mobile phone accessories, etc. have emerged in China. The vast majority of them are ornaments molded by epoxy resin, and the molding of epoxy resin is based on the vulcanized two-component liquid silicone rubber as the master mold, that is, the silicone rubber mold is molded. After turning over the mold 21 to 25 times, there will be cracks at the edges and corners of the silicone rubber mold, and more seriously, the entire silicone rubber mold will crack. The reasons for the cracking of the silicone rubber mold and ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L83/07C08L83/05C08K7/26
CPCC08L83/04C08L2201/08C08K7/26
Inventor 范红杰
Owner 沅陵县成瑞祥粉体材料科技有限公司
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