Anode and secondary battery comprising anode
A negative electrode and negative active material technology, applied in the direction of secondary batteries, battery electrodes, circuits, etc., can solve the problems of difficulty in maintaining high charging and discharging capacity, battery life performance and fast charging performance, etc., to achieve improved Effects of life performance and quick charging performance, improvement of quick charging performance, and reduction in volume expansion
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Embodiment 1
[0074] Embodiment 1: the manufacture of negative electrode
[0075] A negative electrode active material comprising a core and a coating layer (thickness 285 nm) provided on the core and containing carbon nanofibers (average diameter: 285 nm) was used. The core is obtained by adding flake natural graphite (D 50 : 250nm) spheroidization, the spheroidized flaky natural graphite is acid-treated, and then formed by controlling the internal pore volume through the CIP process, and contains natural graphite (sphericity 0.95, D 50 : 11 μm) and an amorphous carbon layer (4% by weight) disposed on spheroidized natural graphite. The anode active material contained oxygen, nitrogen, and hydrogen, and in the anode active material, the content of oxygen was 1,700 ppm by weight, the content of nitrogen was 250 ppm by weight, and the content of hydrogen was 250 ppm by weight. The content of the coating layer in the negative electrode active material was 4.2% by weight. The pore volume o...
Embodiment 2
[0077] Example 2: Manufacture of Negative Electrode
[0078] Negative electrode is manufactured in the same manner as Example 1, the difference is that the natural graphite contained in the core is flake natural graphite (D 50 : 400nm) modified and spheroidized (sphericity 0.95) natural graphite (D 50 : 12 μm).
Embodiment 3
[0079] Embodiment 3: the manufacture of negative electrode
[0080] An anode was fabricated in the same manner as in Example 1, except that the content of oxygen (based on the total amount of the anode active material) was 2,000 ppm by weight.
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