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Developing solution wastewater treatment system

A wastewater treatment system and developer technology, applied in the directions of water/sewage multi-stage treatment, water/sludge/sewage treatment, osmosis/dialysis water/sewage treatment, etc. Biochemical treatment of problems such as the reduction of the carbon-nitrogen ratio of the effluent, to achieve the effects of improving biochemical properties, saving the area occupied by system equipment, and simple operation

Pending Publication Date: 2021-10-15
上海东振环保工程技术有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, this process has the following disadvantages: after the anaerobic biochemical treatment of the developer wastewater, most of the organic carbon in the TMAH is converted into methane and escapes from the water, while most of the organic nitrogen has been converted into ammonia nitrogen but still remains in the water, making the anaerobic The carbon-nitrogen ratio of the oxygen biochemical treatment effluent is greatly reduced
When the A / O biochemical process is used to further remove total nitrogen from the anaerobic effluent, it is necessary to add an external carbon source agent (such as glucose) to meet the demand for carbon source in the denitrification process, so that the operation of the wastewater treatment system cost increase

Method used

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Embodiment 1

[0023] as attached figure 1 Shown, a kind of developing solution wastewater treatment system of the present invention is mainly made up of TMAH decomposition reaction tank 2 and membrane separation tank 4, and TMAH decomposition reaction tank 2 is bioreactor, is anaerobic or low dissolved oxygen environment in the pond, and TMAH decomposition reaction The dissolved oxygen in pool 2 is less than 0.5mg / L, and the TMAH in the developer wastewater is decomposed into organic amine compounds such as trimethylamine, dimethylamine and monomethylamine through the action of hydrolyzing microorganisms; the sludge concentration in TMAH decomposition reaction pool 2 is 8g / L L--20g / L; pH value between 6.5--7.5; its volume load is greater than 2 kgTMAH / m 3 d.

[0024] As a further improvement, the TMAH decomposition reaction tank 2 is a closed water tank, the water inlet is located at the bottom of the reaction tank, the water inlet is connected to the outlet pipe of the external water inle...

Embodiment 2

[0039] Improvement is made on the basis of a kind of developing liquid wastewater treatment system in embodiment 1, as attached figure 2As shown, biological filler is set in the TMAH decomposition reaction tank, so that the hydrolysis microorganisms can attach to the filler, so as to increase the sludge concentration in the reaction tank, thereby improving the efficiency of TMAH decomposition. Biological fillers are commercially available combined fillers or braided fillers.

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Abstract

The invention discloses a developing solution wastewater treatment system, the system mainly comprises a TMAH decomposition reaction tank and a membrane separation tank, a water distributor is arranged in the decomposition reaction tank, and the water distributor uniformly distributes reaction tank inlet water and membrane separation tank circulating reflux at the bottom of the tank; an immersed membrane component is mounted in the membrane separation tank, a perforated aeration pipe is arranged at the lower part of the membrane component, the aeration pipe is connected with an air pipeline outside the tank, membrane wires of the immersed membrane component are shaken through aeration, sludge is prevented from being deposited on the surfaces of the membrane wires, and the reaction tank and the membrane separation tank form a closed loop by the whole system through a connecting pipeline. The treatment system disclosed by the invention does not need to heat wastewater, and is simple to operate and relatively low in energy consumption; the treatment load of the reaction tank is improved, the effective volume of the reaction tank is reduced, and the occupied area of the system is saved; and moreover, the maximum concentration of TMAH (Tetramethyl Ammonium Hydroxide) tolerated by the whole system is 2000mg / L, and the removal rate of the TMAH can reach more than 80%.

Description

technical field [0001] The invention relates to the technical field of wastewater treatment, in particular to a developer wastewater treatment system. Background technique [0002] High-concentration developer wastewater is produced during the production of LCD panels, and the main component of the wastewater is Tetramethylammonium hydroxide (TMAH). TMAH is an organic nitrogen compound with strong alkalinity, corrosiveness and biological toxicity. It is difficult to biodegrade. At high concentrations, it can inhibit the activity of aerobic microorganisms in the wastewater biochemical treatment system, making the total nitrogen of the biochemical system And the removal rate of ammonia nitrogen is reduced, which affects the discharge of treated effluent. [0003] In the invention patent CN111285547A, it is proposed to use anaerobic biochemical process to treat high-concentration developer wastewater, and degrade TMAH into ammonia nitrogen and biogas through anaerobic methanog...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C02F9/14C02F101/38
CPCC02F3/28C02F1/44C02F3/30C02F2101/38
Inventor 肖凡胡伟
Owner 上海东振环保工程技术有限公司
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