Additive composition and method for producing a polymer composition using the same
A composition and additive technology, applied in organic chemistry, carboxylic acid anhydride preparation, carboxylate preparation, etc., can solve problems such as ineffectiveness, inconsistent shrinkage of molded parts, etc.
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Embodiment 1
[0027] This example illustrates the synthesis of a calcium salt of 1,2-cyclohexanedicarboxylate with a high BET specific surface area.
[0028] Cis-1,2-cyclohexanedicarboxylic anhydride (16.75 g, 108.60 mmol) and water (165 mL) were added to a 500 mL round bottom flask equipped with a mechanical stirrer and reflux condenser. The slurry was raised to 70°C and stirred at this temperature for 1 hour. Remove the heating mantle from the flask. A sodium dodecylbenzenesulfonate (SDBS) solution prepared by dissolving SDBS (1.60 g, 90%, 4.00 mmol) in water (10 mL) was then added to the flask. After stirring for 10 minutes, a lime slurry made by mixing calcium hydroxide (8.04 g, 108.60 mmol) and water (50 mL) was added to the flask. The reaction mixture was stirred for 2 hours.
[0029] The white precipitate was collected by suction filtration and washed with copious amounts of water and dried overnight at 110°C. The dry weight was 23.00 g (93% yield). FTIR and NMR spectra were con...
Embodiment 2
[0031] This example illustrates the synthesis of a calcium salt of 1,2-cyclohexanedicarboxylate with a high BET specific surface area.
[0032] Water (15,800 g) and 50% sodium hydroxide solution (2181.90 g, 27.26 mol) were added to a 50 liter Chemglass reactor equipped with a mechanical stirrer and temperature control. After stirring for 5 minutes, molten cis-1,2-cyclohexanedicarboxylic anhydride (2,100 g, 13.62 mol) was added to the reactor. The resulting mixture was stirred at 200 rpm for 10 minutes to obtain a clear solution. A SDBS solution prepared by dissolving SDBS (30 g, 90%, 77.60 mmol) in water (2,700 g) was then added to the reactor. After mixing for 20 minutes, anhydrous CaCl 2 (1,613g, 96%, 14.53mol) of CaCl dissolved in water (7,797g) 2 The solution was added to the reactor. The mixture was stirred at 200 rpm for 2 hours.
[0033] The white precipitate was collected by a filter press and washed with approximately 60 gallons of water until the conductivity of...
Embodiment 3
[0035] This example illustrates the synthesis of a calcium salt of 1,2-cyclohexanedicarboxylate with a high BET specific surface area.
[0036] Water (600 g), 50% NaOH solution (103.80 g, 1.30 mol) and cis-1,2-cyclohexanedicarboxylic anhydride (100 g, 0.65 mol) were added to a 4,000 mL beaker equipped with a mechanical stirrer. After stirring for 10 minutes, the mixture became a clear solution. Lutensol TDA10 (8.42 g, 13.20 mmol) was then added to the beaker. After mixing for 10 minutes, the CaCl 2 2H 2 A calcium chloride solution prepared by dissolving O (96.7 g, 0.66 mol) in water (4,000 g) was added to the beaker. The reaction mixture was stirred for 2 hours.
[0037] The slurry was diluted in 1.5 L wash methanol. The resulting white precipitate was collected by suction filtration and washed with copious amounts of water, then dried overnight at 110°C. Dry weight 140 g (95% yield). FTIR and NMR spectra were consistent with the expected calcium cis-1,2-cyclohexanedica...
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