Laminate of conductor and insulating film, coil, rotating electrical machine, insulating coating, and insulating film
A technology of insulating film and laminated body, which is applied to insulators, insulating cables, conductors, etc., can solve the problems of electronic equipment damage, insulation damage, insulation film deterioration, etc., and achieve the effect of excellent partial discharge resistance characteristics.
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[0086] Hereinafter, the present invention will be further specifically described by way of examples.
manufacture example 1
[0089] 400.8 g of 4,4'- diamino diphenyl ether and 4109 g of NMP were put into the 10-L 4-neck flask equipped with the stirrer and the thermometer, and it heated up to 40 degreeC, stirring in nitrogen, and dissolved it. Next, 220.0 g of pyromellitic anhydride and 279.5 g of biphenyltetracarboxylic dianhydride were gradually added to the solution. It stirred for 1 hour after completion|finish of addition, and obtained the polyimide coating material which melt|dissolved the aromatic polyamic acid represented by following formula (I) at the density|concentration of 18.0 mass %. In addition, in the following formula (I), n is an integer of 2 or more.
[0090] [chemical 1]
[0091]
[0092] (polyimide coating 2)
manufacture example 2
[0094] 400.5 g of 4,4'- diamino diphenyl ether and 3780 g of NMP were put into the 10-L 4-necked flask equipped with a stirrer and a thermometer, and it heated up to 40 degreeC, stirring in nitrogen, and dissolved it. Next, 425.2 g of pyromellitic anhydride was gradually added to the solution. It stirred for 1 hour after completion|finish of addition, and obtained the polyimide paint which melt|dissolved the aromatic polyamic acid represented by following formula (II) at the density|concentration of 17.9 mass %. In addition, in the following formula (II), n is an integer of 2 or more.
[0095] [Chem 2]
[0096]
[0097] (polyimide coating 3)
[0098] UPIA (registered trademark)-AT (U-varnish-A) manufactured by Ube Industries, Ltd. was used. This is a polyimide paint containing an aromatic polyamic acid obtained by reacting 4,4'-diaminodiphenyl ether and biphenyltetracarboxylic dianhydride.
[0099] (polyamideimide coating)
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