Polyurethane plastic material and preparation method thereof

A plastic material and polyurethane technology, applied in the field of polyurethane plastic material and its preparation, can solve the problems of large foaming ratio of plastic material, failure to meet national standards, and great influence of air humidity, and achieve average bubble size, stable speed, and stable response Effect

Active Publication Date: 2020-09-22
山东蓝岳新材料科技有限公司
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  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The present invention aims at preparing polyurethane plastic materials in the existing single-component moisture curing construction, which is greatly affected by air humidity, and the foaming ratio of the prepared plastic materials is too large, and even forms an open-pore structure, resulting in bubbling and water seepage in the plastic materials And other phenomena, can not meet the national standard, provide a polyurethane plastic material with a stable closed microporous structure, so that the physical and mechanical properties of the polyurethane plastic material are better, reduce the construction conditions, and make the construction more convenient and simple

Method used

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  • Polyurethane plastic material and preparation method thereof

Examples

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Comparison scheme
Effect test

Embodiment 1

[0047] A kind of polyurethane plastic material, the raw material that its preparation adopts and consumption are as shown in table 1:

[0048] Table 1 Embodiment 1 raw material ratio table

[0049] raw material name parts by mass 330N 55 220 30 210 15 Chlorinated paraffin 50 BYK-W961 1 Iron Oxide Red 3 1010 1 heavy calcium 150 Titanium dioxide 5 light calcium 10 MDI-50 20 ALT-101 2 phosphoric acid 0.3

[0050] The preparation method of the polyurethane plastic material of the present embodiment is as follows:

[0051] (1) Polyether polyol (330N, 220, 210), plasticizer (chlorinated paraffin), wetting and dispersing agent (BYK-W961), inorganic filler (heavy calcium, titanium dioxide, light calcium), colorant (Red iron oxide) and antioxidant (1010) were put into the reaction kettle, dehydrated at a temperature of 110-120°C and a pressure of -0.1MPa until the water content of the system was low...

Embodiment 2

[0057] A kind of polyurethane plastic material, the raw material that its preparation adopts and consumption are as shown in table 2:

[0058] Table 2 Embodiment 2 raw material ratio table

[0059] raw material name parts by mass 330N 60 220 30 210 10 Epoxidized soybean oil 50 BYK-W961 1 Iron Oxide Red 3 1010 1 heavy calcium 150 talcum powder 5 light calcium 20 MDI-50 20 RGT23416 2 phosphoric acid 0.3

[0060] The preparation method of the polyurethane plastic material of the present embodiment:

[0061] Different from Example 1, the plasticizer of the present embodiment adopts epoxy soybean oil; Inorganic filler adopts heavy calcium, talcum powder and light calcium; Oxazolidine adopts RGT23416; In step (1) and step (2), Cool down to 60°C after dehydration.

[0062] Others are the same as in Embodiment 1, and will not be repeated here.

[0063] In this example, a polyurethane plastic ma...

Embodiment 3

[0065] A kind of polyurethane plastic material, the raw material that its preparation adopts and consumption are as shown in table 3:

[0066] Table 3 Embodiment 3 raw material ratio table

[0067] raw material name parts by mass 330N 70 220 30 Chlorinated paraffin 35 Epoxidized soybean oil 15 BYK-W961 1 Iron Oxide Red 3 1010 1 heavy calcium 130 Kaolin 5 light calcium 20 MDI-50 20 ALT-101 2 phosphoric acid 0.3

[0068] The preparation method of the polyurethane plastic material of the present embodiment:

[0069] Different from Example 1, the polyether polyol of the present embodiment adopts 330N and 220; Plasticizer adopts epoxy soybean oil and chlorinated paraffin; Inorganic filler adopts heavy calcium, kaolin and light calcium; Step (1) and In step (2), the temperature is lowered to 55°C after dehydration.

[0070] Others are the same as in Embodiment 1, and will not be repeated here...

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Abstract

The invention relates to a polyurethane plastic material, which is prepared from the following raw materials by mass: 35-55wt% of polyether polyol; 7-15wt% of isocyanate; 10-20wt% of a plasticizer; 15-25wt% of an inorganic filler; 1-3.0wt% of a colorant; 0.5-2.0wt% of a wetting dispersant; 0.1-3.0wt% of an antioxidant; 1-5wt% of oxazolidine; and 0.1-2wt% phosphoric acid. The invention also discloses a preparation method of the polyurethane plastic material, and the method comprises the following steps of: (1) adding polyether polyol and additives into a reaction kettle, performing dehydratinguntil the water content of the system is lower than 0.05%, and conducting cooling; (2) adding isocyanate, carrying out reaction for 2-3h, and carrying out dehydration and cooling; (3) adding oxazolidine and phosphoric acid; and (4) uniformly mixing the product with water and a catalyst, and conducting flattening and curing to obtain the polyurethane plastic material. The polyurethane plastic material prepared according to the invention has a stable micropore structure and unshrinkable foam pores, is convenient to construct and has low requirements on construction conditions.

Description

technical field [0001] The invention relates to a polyurethane plastic material and a preparation method thereof, belonging to the technical field of polyurethane plastic venues. Background technique [0002] In recent years, the use of polyurethane plastic materials has become more and more common, and the laying sites include stadiums, schools, public fitness places, etc. The plastic material has a certain hardness and good flatness. The introduction of a closed microporous structure in it can absorb shocks, play a cushioning effect, protect the athletes' joints, reduce the risk of injury, and increase the elasticity of the material, which helps to improve sports performance. [0003] The laying of traditional polyurethane plastic sites generally adopts the method of two-component construction. The process of two-component construction requires operators to mix ingredients at the construction site. During the operation of ingredients, the ratio of the two components is pro...

Claims

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Application Information

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IPC IPC(8): C08G18/76C08G18/12C08G18/66C08G18/48C08G18/32C08G18/22C08L75/08C08L91/06C08L91/00C08K13/02C08K3/32C08G101/00
CPCC08G18/7671C08G18/7621C08G18/7607C08G18/12C08G18/4812C08G18/4825C08G18/4829C08G18/227C08G18/222C08G18/4854C08L75/08C08K2003/329C08G18/3271C08L91/06C08K13/02C08K3/32C08L91/00
Inventor 徐学平孙秀利
Owner 山东蓝岳新材料科技有限公司
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