Polymer, curable resin composition and use thereof
A polymer and cured product technology, applied in the direction of optical filters, etc., can solve the problem of insufficient transparency of the cured film, and achieve the effect of excellent heat resistance and coloring
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preparation example Construction
[0279]
[0280] The method for preparing the curable resin composition is not particularly limited, and a known method may be used. For example, a method of mixing and dispersing the above-mentioned components using various mixers and dispersers is mentioned. The mixing / dispersing step is not particularly limited, and may be performed by a known method. In addition, other generally performed steps may be further included. In addition, when the said curable resin composition contains a coloring material, it is preferable to prepare through the dispersion|distribution treatment process of a coloring material.
[0281] As the dispersion treatment process of the above-mentioned coloring material, for example, the following method can be enumerated: first, weighing each predetermined amount of coloring material (preferably an organic pigment), a dispersant, and a solvent, and using a disperser to disperse the coloring material particles to obtain a liquid Pigment dispersion (als...
Embodiment
[0324] The following examples are given to illustrate the present invention in more detail, but the present invention is not limited to these examples. In addition, unless otherwise stated, "part" means "mass part", and "%" means "mass %".
[0325] In this example, measurement conditions of various physical properties and the like are as follows.
[0326]
[0327] Utilize HLC-8220GPC (manufactured by Tosoh Corporation), use tetrahydrofuran as eluent, use TSK-gelSuperHZM-M (manufactured by Tosoh Corporation) as column, measure by gel permeation chromatography, and calculate by standard polystyrene conversion weight average molecular weight.
[0328]
[0329] Accurately weigh about 1 g of the copolymer solution in an aluminum cup, add about 2 g of acetone to dissolve it, and let it stand at room temperature for about 2 hours to allow it to dry naturally. Then, after drying in vacuum at 140 degreeC for 1.5 hours with the vacuum dryer (made by EYELA company), it cooled natur...
Synthetic example 1
[0349] Preparation of Copolymer Solution 1
[0350] Prepare a detachable flask equipped with a thermometer, a stirrer, a gas inlet tube, a condenser tube, and a drop tank inlet as a reaction tank. On the other hand, as a monomer drop tank, prepare 10.0 parts of dimethyl-2,2 '-[Oxybis(methylene)]bis-2-acrylate (hereinafter referred to as MD), 29.5 parts of tert-butyl methacrylate (hereinafter referred to as "t-BMA"), 15.0 parts of methyl 2-hydroxyethyl acrylate (hereinafter referred to as "HEMA"), 1.0 parts of methyl methacrylate (hereinafter referred to as "MMA"), 44.5 parts of mono(2-acryloyloxyethyl) succinate ( Hereinafter referred to as "HOA-MS"), 2 parts of t-butyl peroxide (2-ethylhexanoate) ("perbutyl (registered trademark) O" manufactured by NOF Corporation; hereinafter referred to as "PBO"), 33 Parts of propylene glycol monomethyl ether acetate (hereinafter referred to as "PGMEA") was fully stirred and mixed, and dropped into the tank as a chain transfer agent, and 1...
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