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Microcapsule composite material for Cd and Pb contaminated soil, preparation method and remediation method

A technology for composite materials and polluted soil, which is applied in the field of microcapsule composite materials and preparation, can solve problems such as poor technical stability, large soil disturbance, and long treatment cycle, so as to reduce bioavailability and mobility and improve adsorption The effect, the effect that the restoration effect is remarkable

Inactive Publication Date: 2020-05-05
浙江中地净土科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0035] 1. Engineering restoration: If the foreign soil method is adopted, a large amount of foreign soil needs to be taken, and the same amount of contaminated soil needs to be disposed of;
[0036] 2. Physical and chemical treatment: serious damage to soil structure and soil fertility, complicated process control, high treatment unit cost, poor technical stability, and large disturbance to soil
[0038] 4. Bioremediation: The treatment cycle is long, the later plant collection and treatment process is more complicated, and the maintenance management cycle is long
[0039] 5. Constructed wetland: The treatment cycle is long, the plant activity decreases in winter, and the adsorption capacity of heavy metals decreases; the project covers a large area
[0040] 6. Permeable reaction wall: the construction cost is high, and the seasonal change of groundwater affects the treatment effect
There is no direct effect on soil remediation without leaching

Method used

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  • Microcapsule composite material for Cd and Pb contaminated soil, preparation method and remediation method
  • Microcapsule composite material for Cd and Pb contaminated soil, preparation method and remediation method
  • Microcapsule composite material for Cd and Pb contaminated soil, preparation method and remediation method

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Experimental program
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preparation example Construction

[0077] The invention provides a kind of preparation method of microcapsule composite material, comprising:

[0078] S1, thermally modifying the clay minerals to obtain modified clay minerals;

[0079] The specific preparation method of modified clay mineral includes:

[0080] 1), pretreatment: naturally dry the clay minerals, crush them, and sieve them through a 200-mesh sieve to obtain clay mineral pretreatment products;

[0081] 2), heat treatment: heat-treat the clay mineral pretreated product to obtain a clay mineral heat-treated product; wherein, the heat-treatment temperature is 200°C-600°C, and the heat-treatment time is 5-7 hours;

[0082] 3) Cooling treatment: putting the heat-treated clay mineral product into a drier for cooling to obtain the modified clay mineral.

[0083] S2, prepare calcium magnesium matrix composite material;

[0084] S3. Mixing the modified clay mineral, the calcium-magnesium-based composite material, the sulfate and the pH regulator accordin...

Embodiment 1

[0104] The samples used in the experiment came from Cd and Pb polluted farmland in a certain area of ​​Tianjin, and the total amount of Cd and Pb in the soil samples was detected by the method stipulated in the "Soil Environmental Quality Agricultural Land Soil Pollution Risk Control Standard" (GB15618-2018); Determination of mass effective lead and cadmium The method specified in "Atomic Absorption Method" (GB / T23739-2009) detects the effective concentration of Cd and Pb in soil samples. The test results show that the total amount of Cd in the polluted soil of this farmland is 0.8-1.3mg / kg, the total amount of Pb is 934-680mg / kg, and the pH value is between 7.3-7.8. The goal of soil remediation is to passivate and stabilize the microcapsule composite material After the chemical technology, the effective concentration of cadmium and lead in the soil decreased by 30%.

[0105] The present invention provides a kind of microcapsule composite material of Cd, Pb polluted soil, by w...

Embodiment 2

[0118] The samples used in the experiment came from Cd and Pb polluted farmland in a certain area of ​​Shaoxing, and the total amount of Cd and Pb in the soil samples was detected by the method stipulated in the "Soil Environmental Quality Agricultural Land Soil Pollution Risk Control Standard" (GB15618-2018); Determination of mass effective lead and cadmium The method specified in "Atomic Absorption Method" (GB / T23739-2009) detects the effective concentration of Cd and Pb in soil samples. The test results show that the total amount of Cd in the polluted soil of this farmland is 1.2-3.5mg / kg, the total amount of Pb is 800-1400mg / kg, and the pH value is between 4.9-7.5. The goal of soil remediation is to passivate and stabilize the microcapsule composite material. After the chemical technology, the effective concentration of cadmium and lead in the soil decreased by 30%.

[0119] The present invention provides a kind of microcapsule composite material of Cd, Pb polluted soil, b...

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Abstract

The invention discloses a microcapsule composite material for Cd and Pb contaminated soil, a preparation method and a remediation method. The microcapsule composite material comprises the following components in percentage by weight: 20%-50% of modified clay minerals, 30%-50% of a calcium-magnesium-based composite material, 5%-20% of sulfate and 1%-10% of a pH regulator. The microcapsule compositematerial is friendly to the soil environment, does not cause secondary pollution, does not damage the original aggregate structure of the soil, can improve the acid-base buffer capability of the soilto a certain extent, and can improve the water retention of the soil. The treatment effect on Cd and Pb pollution in soil is obvious, the duration time is long, the adaptability to changes of external environment factors is high, and construction is simple.

Description

technical field [0001] The invention relates to the technical field of soil remediation, in particular to a microcapsule composite material for Cd and Pb polluted soil, a preparation method and a remediation method. Background technique [0002] Cadmium is a dangerous environmental pollution element with only two valence states of 0 and +2. The average content of cadmium in the lithosphere is between 0.1 and 0.2 mg / kg. Cadmium often coexists with zinc and lead in nature, and cadmium in soil only involves divalent cadmium and its compounds. Cadmium is easily absorbed by plants. As long as the cadmium content in the soil increases slightly, the cadmium content in plants will increase accordingly. Cadmium is highly toxic and is chemically close to zinc. Therefore, in some biochemical processes, cadmium can be used as a chemical analogue of zinc to replace zinc, destroying various carbonases, dehydrogenases and phosphatases related to human respiration and digestion. Similarl...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09K17/04C09K17/08B09C1/00B09C1/08B01J13/02C05G3/80C05G5/35C09K101/00C09K109/00
CPCB01J13/02B09C1/00B09C1/08B09C2101/00C05B1/02C09K17/04C09K17/08C09K2101/00C09K2109/00
Inventor 陈林蔡晶晶
Owner 浙江中地净土科技有限公司
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