Microcapsule composite material for Cd and Pb contaminated soil, preparation method and remediation method
A technology for composite materials and polluted soil, which is applied in the field of microcapsule composite materials and preparation, can solve problems such as poor technical stability, large soil disturbance, and long treatment cycle, so as to reduce bioavailability and mobility and improve adsorption The effect, the effect that the restoration effect is remarkable
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[0077] The invention provides a kind of preparation method of microcapsule composite material, comprising:
[0078] S1, thermally modifying the clay minerals to obtain modified clay minerals;
[0079] The specific preparation method of modified clay mineral includes:
[0080] 1), pretreatment: naturally dry the clay minerals, crush them, and sieve them through a 200-mesh sieve to obtain clay mineral pretreatment products;
[0081] 2), heat treatment: heat-treat the clay mineral pretreated product to obtain a clay mineral heat-treated product; wherein, the heat-treatment temperature is 200°C-600°C, and the heat-treatment time is 5-7 hours;
[0082] 3) Cooling treatment: putting the heat-treated clay mineral product into a drier for cooling to obtain the modified clay mineral.
[0083] S2, prepare calcium magnesium matrix composite material;
[0084] S3. Mixing the modified clay mineral, the calcium-magnesium-based composite material, the sulfate and the pH regulator accordin...
Embodiment 1
[0104] The samples used in the experiment came from Cd and Pb polluted farmland in a certain area of Tianjin, and the total amount of Cd and Pb in the soil samples was detected by the method stipulated in the "Soil Environmental Quality Agricultural Land Soil Pollution Risk Control Standard" (GB15618-2018); Determination of mass effective lead and cadmium The method specified in "Atomic Absorption Method" (GB / T23739-2009) detects the effective concentration of Cd and Pb in soil samples. The test results show that the total amount of Cd in the polluted soil of this farmland is 0.8-1.3mg / kg, the total amount of Pb is 934-680mg / kg, and the pH value is between 7.3-7.8. The goal of soil remediation is to passivate and stabilize the microcapsule composite material After the chemical technology, the effective concentration of cadmium and lead in the soil decreased by 30%.
[0105] The present invention provides a kind of microcapsule composite material of Cd, Pb polluted soil, by w...
Embodiment 2
[0118] The samples used in the experiment came from Cd and Pb polluted farmland in a certain area of Shaoxing, and the total amount of Cd and Pb in the soil samples was detected by the method stipulated in the "Soil Environmental Quality Agricultural Land Soil Pollution Risk Control Standard" (GB15618-2018); Determination of mass effective lead and cadmium The method specified in "Atomic Absorption Method" (GB / T23739-2009) detects the effective concentration of Cd and Pb in soil samples. The test results show that the total amount of Cd in the polluted soil of this farmland is 1.2-3.5mg / kg, the total amount of Pb is 800-1400mg / kg, and the pH value is between 4.9-7.5. The goal of soil remediation is to passivate and stabilize the microcapsule composite material. After the chemical technology, the effective concentration of cadmium and lead in the soil decreased by 30%.
[0119] The present invention provides a kind of microcapsule composite material of Cd, Pb polluted soil, b...
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