A kind of one-component polyurethane sealant and low temperature, fast preparation method

A polyurethane sealant, one-component technology, used in polyurea/polyurethane adhesives, adhesives, adhesive types, etc. Waste of resources and water resources and other issues, to achieve the effect of reducing equipment costs and labor costs, less reaction side reactions, and high production efficiency

Active Publication Date: 2022-02-08
SHANDONG NORTH MODERN CHEM IND
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  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0003] The one-step method is to prepare prepolymer in the presence of fillers. The general method is to mix polyols, plasticizers and fillers in a reactor, heat to 120-150°C, and then vacuum dehydrate to consume the moisture in the system. After the moisture content reaches the specified requirements, cool down to below 60°C, add polyisocyanate, catalyst and functional additives and stir to get the finished product. When the system cools down to below 60°C, a large amount of tap water is needed to cool down, because the temperature is too high to add isocyanate and The risk of implosion in the system after the catalyst is increased. The conventional one-step method mainly has the following problems: first, the preparation time is long, and resources, especially water resources, are seriously wasted; The water is removed completely, so there are many side reactions in the system, and the reaction is difficult to control;
[0004] The two-step method is to prepare the PU prepolymer first, and then add fillers, catalysts, functional additives and other raw materials. First, polyols and polyisocyanates are used to prepare polyurethane prepolymers for use. It takes 4 to 5 hours. Among them, polyols and aromatic isocyanates The reactivity of polyol and aliphatic isocyanate is relatively low, and it is necessary to add a catalyst to react at 60-80°C for 3-6 hours. The tap water is cooled to 50°C for standby; secondly, raw materials such as plasticizer, water remover, filler, catalyst and functional additive are added to the polyurethane prepolymer, and this process takes 2 to 4 hours;
[0005] And because the performance of a single prepolymer cannot satisfy the single-component polyurethane sealant of many different properties, so to prepare a variety of polyurethane prepolymers with different characteristics, multiple reactors for preparing prepolymers are required; and because the prepolymer High activity, long storage time, self-crosslinking and thickening will occur, and the content of active group NCO will decrease, which will affect the performance and storage stability of the prepared polyurethane sealant

Method used

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  • A kind of one-component polyurethane sealant and low temperature, fast preparation method
  • A kind of one-component polyurethane sealant and low temperature, fast preparation method

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preparation example Construction

[0069] The present invention also includes the preparation method of one-component polyurethane sealant, comprises the following steps:

[0070] ①In parts by weight, add 15-30 parts of plasticizer to the reaction kettle, heat up to 60-100°C, add 15-55 parts of filler, 0.2-2 parts of water remover, 0.00001-0.002 parts of catalyst, stir 0.5 ~ 1 hour, stop heating to obtain a uniform paste, the viscosity of the paste is generally 0.4 × 10 6 ~8×10 6 mPa s;

[0071] ② Add 8-45 parts of polyol and 1-10 parts of polyisocyanate to the paste obtained in step ①, control the temperature at 45-80°C, stir for 0.5-1 hour, add 0.00001-0.02 parts of catalyst to it, the function aids 0 to 10 parts of agent, continue to stir and react for 10 to 30 minutes, and control the temperature at 45 to 60°C to obtain a single-component polyurethane sealant masterbatch with a viscosity of generally 0.4×10 6 ~8×10 6 mPa s;

[0072] ③Add the remaining parts by weight of the catalyst and the remaining p...

Embodiment 1

[0092] A one-component polyurethane sealant, consisting of the following raw materials: polyol 8kg, polyisocyanate 1kg, plasticizer 15kg, water remover 0.2kg, filler 15kg and catalyst 0.1kg;

[0093] Described polyol is polyether polyol;

[0094] Described polyisocyanate is diphenylmethane diisocyanate;

[0095] Described plasticizer is phenyl alkyl sulfonate;

[0096] The water removal agent is p-toluenesulfonyl isocyanate;

[0097] The filler is nanometer calcium carbonate;

[0098] The catalyst is dibutyltin dilaurate.

Embodiment 2

[0100] A one-component polyurethane sealant, consisting of the following raw materials: 45kg polyol, 10kg polyisocyanate, 30kg plasticizer, 2kg water remover, 55kg filler, 15kg functional additive and 1kg catalyst;

[0101] Described polyol is polyester polyol;

[0102] Described polyisocyanate is toluene diisocyanate;

[0103] Described plasticizer is didecyl phthalate;

[0104] Described dewatering agent is triethyl orthoformate;

[0105] The filler is carbon black;

[0106] The catalyst is N-ethylmorpholine;

[0107] The functional auxiliary agent is a thixotropic hydrophobic fumed silica.

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Abstract

A kind of one-component polyurethane sealant and the one-component polyurethane sealant of the low-temperature, fast preparation method have high tensile strength, shear strength and tear strength, moderate viscosity, and good storage stability; the single-component polyurethane sealant of the present invention The preparation method of the component polyurethane sealant takes a short time, and the preparation of the product can be completed in 2 to 3 hours, and the production efficiency is high; the reaction temperature during the preparation process does not exceed 100°C, the high-temperature reaction time is kept for a short time, and there are few side reactions. Low energy consumption, the preparation method of the one-component polyurethane sealant of the present invention, the preparation process is simple and easy to operate, and can be completed by using existing equipment, and the preparation of the prepolymer is no longer limited to the reaction kettle, which greatly reduces the Equipment cost and labor cost; the preparation process of the one-component polyurethane sealant of the present invention, the prepolymer molecule always coexists with the filler and the functional auxiliary molecule during the production and formation process, and the organic material and the inorganic material can better cooperate and interweave , The shear, tensile strength and elongation at break of the product.

Description

technical field [0001] The invention relates to the technical field of adhesives, in particular to a single-component polyurethane sealant and a low-temperature, rapid preparation method. Background technique [0002] The one-component moisture-curing polyurethane sealant is composed of NCO-terminated polyurethane prepolymers, fillers, plasticizers, catalysts, and functional additives. There are two methods for preparing one-component moisture-curing polyurethane sealants: One-step and two-step methods. [0003] The one-step method is to prepare prepolymer in the presence of fillers. The general method is to mix polyols, plasticizers and fillers in a reactor, heat to 120-150°C, and then vacuum dehydrate to consume the moisture in the system. After the moisture content reaches the specified requirements, cool down to below 60°C, add polyisocyanate, catalyst and functional additives and stir to get the finished product. When the system cools down to below 60°C, a large amount...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09J175/08C09J175/06
CPCC09J175/08C09J175/06
Inventor 董斌杜厚俊王玉东张健伟赵玉萍安靖
Owner SHANDONG NORTH MODERN CHEM IND
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