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Dyeable permanent antistatic flame-retardant polyolefin material as well as preparation method and application thereof

A permanent antistatic, polyolefin technology, applied in the field of polymer materials, can solve the problems of easy migration of antistatic agents, non-dyeable, difficult to identify, etc., and achieve the effect of bright color appearance

Inactive Publication Date: 2020-03-27
SHANDONG DONGHONG PIPE IND
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Existing mining plastics and their composite pipes have the following defects: 1. Polyolefin materials such as carbon black, graphene and carbon nanotubes that use carbon materials as antistatic agents are black, and only black pipes can be prepared by this material. And it cannot be dyed, which cannot meet the requirements of the current standardized mine construction for color marking of pipes; 2. The antistatic agent of pipes made of polyolefin materials modified by traditional migratory antistatic agents is easy to migrate, and the antistatic effect is easy to fade with time. Attenuation, the loss of antistatic performance is large, which is not conducive to the long-term safe use of pipes; 3. Plastic pipes and composite pipes with colored lines are difficult to identify due to the thin marking lines of the pipes, and the pipes marked with paint are painted by brushing and spraying. or dip coating on the surface of the product, it is easy to cause the paint to fall off due to friction and washing, it is not easy to mark for a long time, and it can only provide temporary or short-term antistatic
[0004] When the permanent antistatic agent is used to modify polyolefin, the dosage is relatively large. Although the polyolefin can be permanently antistatic, the compatibility between the permanent antistatic agent and polyolefin is poor, resulting in the deterioration of the modified polyolefin material. The mechanical properties are significantly reduced, making it difficult to apply to the mine environment
In addition, the price of permanent antistatic agent is high, and when it is used in large quantities, it will significantly increase the cost of pipelines

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0041] According to the formula: HDPE-high-density polyethylene 50 parts, compatibilizer (EVA resin + maleic anhydride grafted polyethylene, mass ratio 1:1) 10 parts, permanent antistatic agent-polyoxyethylene-polyamide synthesis 15 parts, non-ionic antistatic masterbatch 5 parts, lubricant (polyethylene wax + oxidized polyethylene wax, mass ratio 1:1) 2.5 parts, antioxidant (168+1010+1076) 0.5 parts, organic NP Flame Retardant - Melamine Polyphosphate Flame Retardant 17 parts. After mixing evenly at high speed, the established production process is used to granulate through a twin-screw extruder to produce dyeable permanent antistatic and flame retardant polyethylene materials.

[0042] In the nonionic antistatic masterbatch, 60 parts of polyethylene, 10 parts of EVA, 25 parts of nonionic antistatic agent-polyethylene glycol amide, and 5 parts of dispersant-polyethylene wax.

[0043] Antioxidant 168 is a phosphite antioxidant, antioxidant 1010 is tetrakis [β-(3,5-di-tert-butyl...

Embodiment 2

[0063] According to the formula: 50 parts of HDPE, 12 parts of compatibilizer (a mixture of EVA and POE, the mass ratio is 1:1), 12 parts of permanent antistatic agent-polyoxyethylene-polyamide compound, non-ionic antistatic master 8 parts of grains, 2.5 parts of lubricant (polyethylene wax+EBS, mass ratio 1:1), 0.5 parts of antioxidant (antioxidant 1010+168, mass ratio 1:1) and organic NP flame retardant-tripolymer 15 parts of cyanamide polyphosphate flame retardant. After mixing evenly at high speed, use the established production process (same as in Example 1) to granulate through a twin-screw extruder to produce a dyeable permanent antistatic flame retardant polyethylene material.

[0064] In the nonionic antistatic masterbatch, 60 parts of polyethylene, 10 parts of EVA, 25 parts of nonionic antistatic agent-polyethylene glycol amide, and 5 parts of dispersant-polyethylene wax.

[0065] The performance test results of the prepared dyeable permanent antistatic flame retard...

Embodiment 3

[0074] According to the formula: 50 parts of HDPE, 10 parts of compatibilizer (a mixture of EVA and POE, the mass ratio is 1:2), 18 parts of permanent antistatic agent-polyoxyethylene-polyamide compound, non-ionic antistatic master 2 parts of grains, 2.5 parts of lubricant (polyethylene wax + EBS, mass ratio 1:1), 0.5 parts of antioxidant (antioxidant 1076+16, mass ratio 1:1), organic NP flame retardant - melamine 20 parts of polyphosphate flame retardant. After mixing evenly at high speed, the established production process is used to granulate through a twin-screw extruder to produce dyeable permanent antistatic and flame retardant polyethylene materials.

[0075] In the nonionic antistatic masterbatch, 60 parts of polyethylene, 10 parts of EVA, 25 parts of nonionic antistatic agent-polyethylene glycol amide, and 5 parts of dispersant-polyethylene wax.

[0076] The performance test results of the prepared dyeable permanent antistatic flame retardant polyethylene material ar...

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PUM

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Abstract

The invention discloses a dyeable permanent antistatic flame-retardant polyolefin material and a preparation method thereof. The dyeable permanent antistatic flame-retardant polyolefin material comprises a polyolefin matrix, a flame retardant, a compatilizer and an antistatic agent, and the antistatic agent comprises a permanent antistatic agent and a nonionic antistatic agent. The polyolefin material has dyeable, permanent antistatic and flame-retardant properties, can meet the requirements of MT181-1988 standard mining pipes, and can also meet the requirements of standardized mines.

Description

technical field [0001] The invention relates to the field of polymer materials, in particular to a dyeable permanent antistatic flame retardant polyolefin material and its preparation method and application. Background technique [0002] The information disclosed in this background section is only intended to increase the understanding of the general background of the present invention, and is not necessarily taken as an acknowledgment or any form of suggestion that the information constitutes the prior art already known to those skilled in the art. [0003] With the advancement of standardized mine construction, coal mine underground pipes (such as water supply pipes, drainage pipes, positive pressure air pipes and spray pipes, etc.) Internal fluid transfer type. Existing mining plastics and their composite pipes have the following defects: 1. Polyolefin materials such as carbon black, graphene and carbon nanotubes that use carbon materials as antistatic agents are black, ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/06C08L23/14C08L23/12C08L23/08C08L51/06C08L71/02C08L77/00C08L23/30C08K5/52C08K5/134C08K5/526C08K5/20C08J3/22
CPCC08L23/06C08L23/14C08L23/12C08J3/226C08L2201/02C08L2201/04C08L2203/18C08L2205/08C08L2203/16C08L2203/20C08L2205/035C08L2207/062C08L2205/025C08K2201/014C08L2207/14C08J2323/06C08J2423/06
Inventor 倪奉尧范作庆刘树孔伟川李冰晶
Owner SHANDONG DONGHONG PIPE IND
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