Preparation method of low-odor foamed polypropylene material

A foamed polypropylene, low-odor technology, applied in the field of polypropylene materials, can solve the problems of worsening odor, application limitations of foamed polypropylene materials, and endangering the health of occupants in the car, so as to reduce irritating odor and reduce the amount of organic matter. , improve the effect of environmental protection

Inactive Publication Date: 2020-01-17
SUZHOU RUNJIA ENGINEER PLASTIC
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the material will contain organic small molecule compounds with volatile characteristics and pungent odor to varying degrees; such substances are represented by formaldehyde. During the use of expanded polypropylene materials, (especially when the temperature is high) It will be emitted, which not only worsens the smell in the car, but also seriously endangers the health of the people in the car, which greatly limits the application of expanded polypropylene materials.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0022] The invention provides a method for preparing a low-odor foamed polypropylene material, comprising the following steps:

[0023] (1) Weigh 100 parts by mass of polypropylene resin, 12 parts by mass of sodium borohydride cyclohexanol solution, 10 parts by mass of talc powder, 0.5 parts by mass of antioxidant and 1 part by mass of heat stabilizer, and mix them under the condition of 150°C 2h; in this process, the formaldehyde contained in the material reacts with sodium borohydride in cyclohexanol, and sodium borohydride can reduce formaldehyde to methanol and emit it, thereby reducing the formaldehyde content in the material and making the material The irritating odor and the amount of volatile harmful substances are reduced, which improves the environmental protection of polypropylene materials; at the same time, cyclohexanol can also dissolve formaldehyde and other harmful organic substances that cannot be reduced;

[0024] Among them: the flow rate of polypropylene re...

Embodiment 2

[0036] The invention provides a method for preparing a low-odor foamed polypropylene material, comprising the following steps:

[0037] (1) Weigh 100 parts by mass of polypropylene resin, 10 parts by mass of sodium borohydride cyclohexanol solution, 15 parts by mass of talc powder, 1 part by mass of antioxidant and 2 parts by mass of heat stabilizer, and mix them under the condition of 100°C 3h;

[0038] Among them: the flow rate of polypropylene resin under a load of 2.16kg at a temperature of 230°C is 30-45g / min;

[0039] The concentration of sodium borohydride cyclohexanol solution (i.e. the percentage of sodium borohydride in the solution) is 20wt%;

[0040] The particle size of the talc powder is between 10-15µm, and it is coated with epoxy resin; the coating makes the talc powder more compatible with the matrix material;

[0041] The antioxidant is a hindered phenolic antioxidant; the thermal stabilizer is a phenolic thermal stabilizer;

[0042] (2) Send the mixture o...

Embodiment 3

[0049] The invention provides a method for preparing a low-odor foamed polypropylene material, comprising the following steps:

[0050] (1) Weigh 100 parts by mass of polypropylene resin, 5 parts by mass of sodium borohydride cyclohexanol solution, 20 parts by mass of talc powder, 2 parts by mass of antioxidant and 0.5 part by mass of heat stabilizer, and mix them under the condition of 135°C 1h;

[0051] Among them: the flow rate of polypropylene resin under a load of 2.16kg at a temperature of 230°C is 30-45g / min;

[0052] The concentration of sodium borohydride cyclohexanol solution (i.e. the percentage of sodium borohydride in the solution) is 30wt%;

[0053] The particle size of the talc powder is between 10-15µm, and it is coated with epoxy resin; the coating makes the talc powder more compatible with the matrix material;

[0054] The antioxidant is a hindered phenolic antioxidant; the thermal stabilizer is a phenolic thermal stabilizer;

[0055] (2) Send the mixture ...

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Abstract

The invention relates to a preparation method of a low-odor foamed polypropylene material, and the method comprises the following steps of: weighing polypropylene resin, a sodium borohydride alcohol solution and auxiliary materials, and mixing for at least 1h under the condition that the temperature is not lower than 100 DEG C; then melting, extruding, cooling and setting; after that, mixing withsodium bicarbonate and performing injection molded. The method introduces a sodium borohydride cyclohexanol solution; sodium borohydride can reduce formaldehyde to methanol, cyclohexanol can dissolveformaldehyde and other harmful organic substances and bring them out when vaporized; therefore, the content of the formaldehyde and other harmful organic substances in the material can be effectivelyreduced, the pungent smell of the material and the amount of the harmful substances the can be volatilized are reduced, and the environmental protection of the polypropylene material is improved; at the same time, the mechanical properties test results show that the introduction of the sodium borohydride cyclohexanol solution has no effect on the overall mechanical properties of the material.

Description

technical field [0001] The invention relates to the field of polypropylene materials, in particular to a method for preparing low-odor foamed polypropylene materials. Background technique [0002] In recent years, due to its lightweight characteristics, foamed polypropylene materials have become more and more widely used in the automotive field. However, the material will contain organic small molecule compounds with volatile characteristics and pungent odor to varying degrees; such substances are represented by formaldehyde. During the use of expanded polypropylene materials, (especially when the temperature is high) It will emit, which not only worsens the smell in the car, but also seriously endangers the health of the people in the car, which greatly limits the application of expanded polypropylene materials. Contents of the invention [0003] The invention overcomes the disadvantages of the prior art, and provides a preparation method of foamed polypropylene material...

Claims

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Application Information

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IPC IPC(8): C08L23/12C08K13/06C08K9/10C08K3/34C08K3/38C08K5/05C08J9/08
CPCC08J9/08C08J9/0095C08J9/009C08J9/0066C08J9/0023C08J2323/12C08J2203/02C08K13/06C08K9/10C08K3/34C08K3/38C08K5/05
Inventor 汪理文郑帅孟迪余君翁永华
Owner SUZHOU RUNJIA ENGINEER PLASTIC
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