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Preparation of all-solid-state super capacitor based on hydrogel electrolyte

An electrolyte and hydrogel technology, applied in the field of preparation of all-solid-state supercapacitors based on hydrogel electrolytes, can solve the problems of high cost, non-renewability, poor biocompatibility, etc., and achieve high safety, simple preparation method, Simple assembly process

Inactive Publication Date: 2020-01-03
INST OF CHEM IND OF FOREST PROD CHINESE ACAD OF FORESTRY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At this stage, hydrogels are mainly prepared from petroleum-based raw materials, which have disadvantages such as high cost, poor biocompatibility, and non-renewability.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0014] Embodiment 1: Preparation of soybean protein-polyacrylamide composite hydrogel

[0015] The soybean protein is fully dispersed in the aqueous solution by heating to obtain a soybean protein dispersion, and then acrylamide monomer, cross-linking agent N, N'-methylenebisacrylamide and calcium chloride, and initiator ammonium persulfate are added. Control the mass ratio of soybean protein, acrylamide, initiator, and cross-linking agent to 1:5:0.02:0.01, and the mass ratio of soybean protein to calcium chloride to 10:1. Heat at 80°C for 24 hours to make it fully cross-linked and polymerized , to obtain soybean protein-polyacrylamide composite hydrogel.

Embodiment 2~ Embodiment 11

[0016] Embodiment 2~Example 11 Preparation of soybean protein-polyacrylamide composite hydrogel electrolyte

[0017] The soybean protein-polyacrylamide composite hydrogel obtained in Example 1 was immersed in an ion solution of a certain concentration at room temperature, and fully replaced to obtain a soybean protein-polyacrylamide composite hydrogel electrolyte dissolved in ions. The type and concentration of the ionic solution, as well as the conductivity of the prepared soybean protein-polyacrylamide composite hydrogel electrolyte, are detailed in Table 1.

Embodiment 12

[0018] Example 12 Preparation of an all-solid supercapacitor based on soybean protein-polyacrylamide composite hydrogel electrolyte

[0019] The soybean protein-polyacrylamide composite hydrogel electrolyte prepared in Example 4 was used as the electrolyte, and the carbon nanotube paper was used as the electrode, and the carbon nanotube paper was directly adhered to both sides of the soybean protein-polyacrylamide composite hydrogel electrolyte. side, an all-solid capacitor assembled into a sandwich structure without any adhesives, separators, or substrates.

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PUM

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Abstract

The invention provides an all-solid-state capacitor based on a hydrogel electrolyte and an assembling method thereof in view of the defects of a super capacitor based on a liquid electrolyte. The assembling method comprises the following steps: soybean protein-polyacrylamide composite hydrogel is formed by taking a mixed solution of soybean protein and acrylamide as a prepolymer, adding an initiator ammonium persulfate, a cross-linking agent N, N'-methylene bisacrylamide and calcium chloride and carrying out heating and cross-linking; the composite hydrogel is immersed into an ionic solution at room temperature for replacement to obtain a hydrogel electrolyte in which ions are dissolved; and on the basis, carbon nanotube electrodes are directly adhered to the two sides of the hydrogel electrolyte to obtain an all-solid-state capacitor with a sandwich structure, wherein any adhesive, diaphragm or substrate is not needed. The prepared hydrogel electrolyte has the characteristics of simple preparation method, biocompatibility, environmental friendliness and the like. The assembled all-solid-state super capacitor has the advantages of simple assembly process, excellent electrochemicalperformance, high safety and the like. The invention discloses a preparation method of the all-solid-state capacitor.

Description

technical field [0001] The invention relates to the preparation of a soybean protein composite hydrogel electrolyte and its application in a supercapacitor. Background technique [0002] Supercapacitors, also known as electrochemical supercapacitors, are electrical energy storage devices between traditional capacitors and batteries. Compared with traditional capacitors, they have higher output power; compared with batteries, they have higher Energy Density. Therefore, it combines the advantages of traditional capacitors and storage batteries, which is conducive to expanding its application in high-power and high-energy power supplies. In addition, supercapacitors also have the advantages of short rate time, wide operating range, short charging time, and long cycle life. In recent years, with the rapid development of flexible electronic devices, supercapacitors, as one of the main energy supply devices for electronic products, how to adapt to the requirements of flexible el...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01G11/56H01G11/36H01G11/84C08F289/00C08F220/56C08F222/38
CPCC08F289/00H01G11/36H01G11/56H01G11/84C08F220/56C08F222/385Y02E60/13
Inventor 王春鹏张盖同南静娅王利军储富祥
Owner INST OF CHEM IND OF FOREST PROD CHINESE ACAD OF FORESTRY
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