Rigid functional ligand-cyclometalated bridge-functional ligand type iridium complex framework
An iridium complex and cyclometal technology, which is applied in the field of high-performance luminescent materials in the technical field of organometallic complexes, can solve the problems of unfavorable organometallic iridium complex performance improvement, limited space for performance regulation, etc., to increase structural diversity And the effect of property control space, optimal performance, and important application value
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Embodiment 1
[0024] The organometallic iridium complex Ir1 chemical formula of the present embodiment is C 46 h 40 f 4 Ir 2 N 4 o 4 , the structural formula is Refer to attached figure 1 , and its synthesis method is as follows: 2 equivalents of peripheral functionalized ligand 1 equivalent of ring metal bridge ligand And 2 equivalents of iridium trichloride were put into the reaction vessel. Under a nitrogen atmosphere, a mixed solvent of ethylene glycol ether and water (volume ratio: 3:1) was added into the reaction vessel. Heating to 110° C. for 24 hours in a nitrogen atmosphere; stopping heating, cooling to room temperature, adding deionized water to the reaction mixture solution, solids were precipitated, filtered and dried. Add the dried solid, β-diketone ligand, and anhydrous sodium carbonate into ethylene glycol ether at a ratio of 1:2:10, and heat to 110°C for 24 hours in a nitrogen atmosphere. After the reaction, the reaction mixture was poured into 30 mL of deionize...
Embodiment 2
[0026] The organometallic iridium complex Ir2 chemical formula of the present embodiment is C 54 h 60 Ir 2 N 4 o 4 , the structural formula is Refer to attached figure 1 , and its synthesis method is as follows: 2 equivalents of peripheral functionalized ligand 1 equivalent of ring metal bridge ligand And 2 equivalents of iridium trichloride were put into the reaction vessel. Under a nitrogen atmosphere, a mixed solvent of ethylene glycol ether and water (volume ratio: 3:1) was added into the reaction vessel. Heating to 110° C. for 24 hours in a nitrogen atmosphere; stopping heating, cooling to room temperature, adding deionized water to the reaction mixture solution, solids were precipitated, filtered and dried. Add the dried solid, β-diketone ligand, and anhydrous sodium carbonate into ethylene glycol ether at a ratio of 1:2:10, and heat to 110°C for 24 hours in a nitrogen atmosphere. After the reaction, the reaction mixture was poured into 30 mL of deionized wat...
Embodiment 3
[0028] The organometallic iridium complex Ir3 chemical formula of the present embodiment is C 66 h 52 Ir 2 N 4 o 12 S 4 , the structural formula is Refer to attached figure 1 , and its synthesis method is as follows: 2 equivalents of peripheral functionalized ligand 1 equivalent of ring metal bridge ligand And 2 equivalents of iridium trichloride were put into the reaction vessel. Under a nitrogen atmosphere, a mixed solvent of ethylene glycol ether and water (volume ratio: 3:1) was added into the reaction vessel. Heating to 110° C. for 24 hours in a nitrogen atmosphere; stopping heating, cooling to room temperature, adding deionized water to the reaction mixture solution, solids were precipitated, filtered and dried. Add the dried solid, β-diketone ligand, and anhydrous sodium carbonate into ethylene glycol ether at a ratio of 1:2:10, and heat to 110°C for 24 hours in a nitrogen atmosphere. After the reaction, the reaction mixture was poured into 30 mL of deioniz...
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