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Purple biaxial-stretching polyester film and preparation method thereof

A biaxially stretched polyester, purple technology, applied in the field of polyester film, can solve the problems of complex preparation process, blue dye migration, haze reduction, etc., and achieve the effects of reduced manufacturing cost, reasonable temperature parameters, and high gloss

Inactive Publication Date: 2019-12-31
ZHEJIANG HESHUN NEW MATERIAL CO LTD +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] Patent CN201610766040.6 discloses a blue polyester film and its preparation method, including ABC three-layer structure, B layer is the middle core layer, the material is super bright polyester slice; A layer is the upper surface dyed layer, the material includes Blue masterbatch, smooth masterbatch and polyester chip, C layer is the dyed layer of the lower surface, the material includes blue masterbatch, smooth masterbatch and polyester chip, the obtained blue polyester film has the same color at 150 ℃ Migration and anti-scratch properties, but because the dyed layer A and C layers are the surface layers of the polyester film, when the dyed layer is exposed to different types of organic solvents during the coating process, there is polyester swelling that causes the blue dye to migrate Risk, the smooth masterbatch used by Sinopec Yizheng Chemical Fiber Co., Ltd. FG611 is a silica system, which has the disadvantage of large haze
[0004] Patent CN200910102022.8 discloses a polyester masterbatch for high-transparency and high-brightness films and its preparation method, including stirring Sachtoperse AB and EG evenly at a weight ratio of 1 to 1.2:1, and configuring it as a dispersion for later use; In the glycol ester BHET melt, sequentially add the dispersion liquid with a mass ratio of SachtoperseAB: BHET = 100ppm to 30000ppm, carry out pre-condensation, final polycondensation, discharge, and pelletize. Since the refractive index of SachtoperseAB is close to that of PET, the obtained parent The glossiness of the BOPET film produced by using pellets increases significantly and the haze decreases significantly, but this method has the problems of complicated preparation process and high production cost.

Method used

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  • Purple biaxial-stretching polyester film and preparation method thereof
  • Purple biaxial-stretching polyester film and preparation method thereof
  • Purple biaxial-stretching polyester film and preparation method thereof

Examples

Experimental program
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Effect test

no. 1 example

[0032] Such as figure 1 , a purple biaxially stretched polyester film, the purple biaxially stretched polyester film is an ABA type three-layer structure, the B layer is a colored layer, the A layer is located on both sides of the B layer, and the A layer is transparent layer, the raw materials of the B layer include: 0.2% to 15% of purple masterbatch and 85% to 99.8% of optical grade PET slices by mass percentage; the raw materials of the A layer include: 1% to 50% by weight Open masterbatch and 50% to 99% optical grade PET chips.

[0033] The scheme makes the purple double-stretched polyester film have good performance, widens the application range of the purple double-stretched polyester film, and reduces the use cost of the purple double-stretched polyester film.

no. 2 example

[0035] The total thickness of the A layer accounts for 20% to 50% of the total thickness of the purple biaxially stretched polyester film, and the thickness of the B layer accounts for 50% to 80% of the purple biaxially stretched polyester film.

[0036] The purple masterbatch comprises 3% to 14% of purple toner, 0.5% to 2% of dispersant and 80% to 95% of optical grade PET in the weight portion of the purple masterbatch.

[0037] The opening masterbatch comprises: 5% to 15% of calcium carbonate, 1% to 4% of silane coupling agent and 81% to 94% of optical grade PET in the weight of the opening masterbatch.

[0038] The calcium carbonate used is in a regular spherical shape, and the particle size of the calcium carbonate used is 0.5um to 1.6um.

[0039] The particle size of calcium carbonate is not specifically limited, and those skilled in the art can reasonably select it according to needs.

[0040] The total thickness of the purple biaxially stretched polyester film is 12um ...

no. 3 example

[0043] A preparation method for a purple double-stretched polyester film, comprising the following steps:

[0044] Grind optical-grade PET chips into polyester powder with a particle size of 0.5um to 0.8um, then mix polyester powder, quality purple toner and dispersant at a speed of 3500r / min to 4000r / min for 5min to 10min, Then adjust the rotation speed to 100r / min to 150r / min and mix for 2min to 3min. Finally, melt and knead the mixed raw materials at 265°C to 275°C, extrude and pelletize to obtain purple masterbatch;

[0045] Grind optical-grade PET slices into polyester powder with a particle size of 0.5um to 0.8um, then mix polyester powder, calcium carbonate, and silane coupling agent at a speed of 4000r / min to 5000r / min for 10min to 15min, Then adjust the rotation speed to 150r / min to 200r / min and mix for 3min to 5min. Finally, melt and knead the mixed raw materials at 265°C to 275°C, extrude and pelletize to obtain open masterbatch;

[0046]The prepared purple masterb...

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Abstract

The invention provides a purple biaxial-stretching polyester film. The purple biaxial-stretching polyester film is of an ABA-type three-layer structure, wherein an A layer is a transparent layer, a Blayer is a colored layer, and a C layer includes purple masterbatch and optical-grade PET slice; and the A layer includes open-end masterbatch and optical-grade PET slice. When the preparation methodis compared with the prior art, the purple biaxial-stretching polyester film has the advantages of no color migration, no color fading, low haze and high gloss through selection of reasonable composition matching and a reasonable structure, and the performance of the purple biaxial-stretching polyester film is optimized. According to a preparation method of the purple biaxial-stretching polyesterfilm, related temperature parameters and mixing time are controlled reasonably, so that the performance of the purple biaxial-stretching polyester film is optimized, and the manufacture cost the purple biaxial-stretching polyester film is reduced.

Description

technical field [0001] The invention relates to the field of polyester films, in particular to a purple biaxially stretched polyester film and a preparation method thereof. Background technique [0002] Biaxially oriented polyester film has excellent physical and chemical properties, dimensional stability, and transparency, and can be widely used in packaging, printing, photosensitive materials, electrical, electronic industries and other fields. Among them, colored biaxially oriented polyester film is used in such fields as mobile phones , Digital cameras, LCD, LED and other electronic products have been widely used as an auxiliary material in the production process. With the continuous development of consumer electronics, the requirements for related materials are getting higher and higher, requiring colored polyester film During the processing, there should be no color migration, color fading and certain temperature resistance. At the same time, the polyester film is requ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B32B27/06B32B27/36B32B27/18B29C48/08B29C48/18B29C55/14C08L67/02C08K3/26C08J5/18
CPCB29C55/143B32B27/08B32B27/18B32B27/36B32B2250/03B32B2250/40B32B2307/4026B32B2307/406B32B2307/54B29C48/08B29C48/18C08J5/18C08J2367/02C08K2003/265
Inventor 范和强陈正坚陆宇赵言松
Owner ZHEJIANG HESHUN NEW MATERIAL CO LTD
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