Looking for breakthrough ideas for innovation challenges? Try Patsnap Eureka!

Graphene doped Cu/Cu2O nano photocatalytic coating and preparation method thereof

A catalytic coating, graphene technology, applied in metal/metal oxide/metal hydroxide catalysts, chemical instruments and methods, physical/chemical process catalysts, etc., can solve the problem that photolysis research is rarely reported, etc. The effect of strong visible light response, enhanced light absorption, good degradation effect

Active Publication Date: 2019-11-29
FUJIAN UNIV OF TECH
View PDF5 Cites 4 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Photolysis is the main pathway for the degradation of methyl orange and phenol in aqueous environments, but there are few reports on the photolysis of methyl orange and phenol by graphene-doped Cu / Cu2O nanophotocatalytic coatings.

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Examples

Experimental program
Comparison scheme
Effect test

preparation example Construction

[0022] A graphene-doped Cu / Cu 2 The preparation method of O nano photocatalytic coating, comprises the following steps:

[0023] 1) Pre-treat the workpiece to clean off the dust, grease and rust on the surface of the workpiece;

[0024] 2) Preparation of graphene-doped Cu / Cu 2 O composite slurry: (1) take Cu 2 O powder is dispersed in alcohol aqueous solution, and ultrasonic treatment is carried out under the condition of magnetic stirring; (2) after the ultrasonic is finished, add adhesive solution and Cu powder, continue to stir evenly; (3) dropwise add graphene oxide powder, the solution continues Magnetically stirred evenly to obtain graphene-doped Cu / Cu 2 O composite slurry;

[0025] Among them, Cu 2 The mass ratio of O powder, Cu powder, graphene oxide powder is 75:20:5, and binder solution is the polyvinyl alcohol aqueous solution or the epoxy polyester powder coating that mass percent is 3-5%;

[0026] 3) The above-mentioned slurry is pressed on the surface of th...

Embodiment 1

[0030] A graphene-doped Cu / Cu 2 The preparation method of O nano photocatalytic coating, comprises the following steps:

[0031] 1) Pre-treat the workpiece to clean off the dust, grease and rust on the surface of the workpiece;

[0032] 2) Preparation of graphene-doped Cu / Cu 2 O composite slurry: (1) take Cu 2 O powder is dispersed in alcohol aqueous solution, and ultrasonic treatment is carried out under the condition of magnetic stirring; (2) after the ultrasonic is finished, add adhesive solution and Cu powder, continue to stir evenly; (3) dropwise add graphene oxide powder, the solution continues Magnetically stirred evenly to obtain graphene-doped Cu / Cu 2 O composite slurry;

[0033] Among them, Cu 2 The mass ratio of O powder, Cu powder, graphene oxide powder is 75:20:5, and binder solution is the polyvinyl alcohol aqueous solution that mass percentage is 3%;

[0034] 3) The above-mentioned slurry is pressed on the surface of the pretreated workpiece by a mechanica...

Embodiment 2

[0038] A graphene-doped Cu / Cu 2 The preparation method of O nano photocatalytic coating, comprises the following steps:

[0039] 1) Pre-treat the workpiece to clean off the dust, grease and rust on the surface of the workpiece;

[0040] 2) Preparation of graphene-doped Cu / Cu 2 O composite slurry: (1) take Cu 2 O powder is dispersed in alcohol aqueous solution, and ultrasonic treatment is carried out under the condition of magnetic stirring; (2) after the ultrasonic is finished, add adhesive solution and Cu powder, continue to stir evenly; (3) dropwise add graphene oxide powder, the solution continues Magnetically stirred evenly to obtain graphene-doped Cu / Cu 2 O composite slurry;

[0041] Among them, Cu 2 The mass ratio of O powder, Cu powder, graphene oxide powder is 75:20:5, and binder solution is the polyvinyl alcohol aqueous solution that mass percentage is 5%;

[0042] 3) The above-mentioned slurry is pressed on the surface of the pretreated workpiece by a mechanica...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

No PUM Login to View More

Abstract

The invention discloses a graphene doped Cu / Cu2O nano photocatalytic coating and a preparation method thereof. The method includes: 1) pretreating a workpiece to remove dust, oil dirt and rust on thesurface of the workpiece; 2) preparing a graphene doped Cu / Cu2O composite slurry; 3) pressing the slurry on the surface of the pretreated workpiece through a mechanical roller to form a base layer; 4)adopting a vacuum induction sintering method, placing the workpiece with the formed base layer in a graphite integrated forming sintering mold, maintaining the pressure after the density of a pressedblank does not change any more, and starting sintering to form a preset layer on the surface of the workpiece; and 5) carrying out electron beam welding on the preset layer to obtain the graphene doped Cu / Cu2O nano photocatalytic coating. The method provided by the invention puts forward solar irradiation of the graphene doped Cu / Cu2O nano photocatalytic coating by a solar concentrating device, can solve the problem of shortening the forbidden bandwidth of a catalyst to expand an absorption spectrum to visible light so as to improve the solar energy utilization rate.

Description

technical field [0001] The invention relates to the field of photocatalytic coatings, in particular to a graphene-doped Cu / Cu 2 O nano photocatalytic coating and its preparation method. Background technique [0002] With the continuous advancement of the global industrialization process, the problem of environmental pollution has become increasingly prominent, which has seriously affected people's daily production and life. In particular, water pollution has become a common concern all over the world, which has greatly threatened people's living water sources. In order to effectively solve the water pollution in the natural environment, experts and scholars from various countries are actively developing new sewage treatment technologies and methods. Traditional sewage treatment methods mainly include physical separation (such as sedimentation, adsorption, filtration, flocculation, etc.), biodegradation and chemical decomposition. Defects such as secondary pollution. . T...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
IPC IPC(8): B01J23/72C02F1/30C02F101/30C02F101/34C02F101/38C02F101/32
CPCB01J23/72C02F1/30C02F2101/306C02F2101/308C02F2101/345C02F2101/38C02F2101/40C02F2101/30C02F2101/32C02F2305/10B01J35/39Y02W10/37
Inventor 简明德刘成武黄卫东许明三黄旭
Owner FUJIAN UNIV OF TECH
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Patsnap Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Patsnap Eureka Blog
Learn More
PatSnap group products