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Composite fire extinguishing agent for lithium battery

A fire extinguishing agent and lithium battery technology, applied in fire prevention equipment, fire rescue, etc., can solve the problems of interrupting combustion, difficulty in extinguishing fire, and high risk of re-ignition

Inactive Publication Date: 2019-11-22
ZHEJIANG NARADA POWER SOURCE CO LTD +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Existing fire extinguishing agents can extinguish the open flames caused by lithium-ion battery fires in a short period of time, but because the thermal runaway reaction of lithium-ion batteries can continuously generate combustible gases, oxygen and heat, traditional fire extinguishing agents cannot interrupt the combustion from the source, and the risk of re-ignition high
In addition, the chemical properties of lithium are very active. Once this type of metal burns, it will be particularly violent, and it can react with water, carbon dioxide, foam, and ordinary dry powder fire extinguishing agents, which will further aggravate the spread of the fire and make it extremely difficult to extinguish the fire.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0031] This embodiment provides a composite fire extinguishing agent for lithium batteries, including perfluorohexanone, organophosphorus inhibitors and argon, the proportion of perfluorohexanone is 50%, the proportion of organophosphorus inhibitors is 30%, and argon The mass proportion of gas is 20%, and all proportions are weight ratios.

[0032] Spray the composite fire extinguishing agent for lithium batteries in Example 1 onto the burning lithium-ion battery, perfluorohexanone can hit the open flame within 10 seconds, and the organophosphorus-based inhibitory additive enters the interior of the battery by virtue of the volatility of perfluorohexanone, absorbing The phosphorus-containing free radicals produced by thermal decomposition can combine with free radicals such as hydrogen free radicals to form non-combustible substances, block the combustion reaction, thereby preventing the thermal runaway reaction from proceeding, thereby preventing combustion and explosion, and ...

Embodiment 2

[0034] This embodiment provides a composite fire extinguishing agent for lithium batteries, including perfluorohexanone, organophosphorus inhibitory additives and argon gas, the proportion of perfluorohexanone is 70%, the proportion of organophosphorus inhibitory additives is 10%, and argon The mass proportion of gas is 20%, and all proportions are weight ratios.

[0035] Spray the composite fire extinguishing agent of Example 2 onto the burning lithium-ion battery, and perfluorohexanone can blow open flames within 5 seconds, and the organophosphorus-based inhibitory additive enters the interior of the battery by virtue of the volatility of perfluorohexanone, and decomposes by endothermic The generated phosphorus-containing free radicals can combine with hydrogen free radicals and other free radicals to form non-combustible substances, block the combustion reaction, thereby preventing the thermal runaway reaction from proceeding, thereby preventing combustion and explosion, and...

Embodiment 3

[0037] A composite fire extinguishing agent for lithium batteries provided in Example 3 of the present invention includes perfluorohexanone, organophosphorus-based inhibitory additives and argon gas, the proportion of perfluorohexanone is 80%, and the proportion of organophosphorus-based inhibitory additives is 5%. %, the mass proportion of argon is 15%, and all proportions are weight ratios.

[0038] Spray the composite fire extinguishing agent of Example 3 onto the burning lithium-ion battery, and perfluorohexanone can blow open flames within 8 seconds, and the organophosphorus-based inhibitory additive enters the interior of the battery by virtue of the volatility of perfluorohexanone, and decomposes by endothermic The generated phosphorus-containing free radicals can combine with free radicals such as hydrogen free radicals to form non-combustible substances, block the combustion reaction, thereby preventing the thermal runaway reaction from proceeding, thereby preventing c...

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PUM

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Abstract

The invention provides a composite fire extinguishing agent for a lithium battery. The composite fire extinguishing agent comprises the following components in percentage by weight: 50-90% of a fire extinguishing agent; 5%-50% of an inhibition additive; 0%-45% of a driving gas; wherein the inhibition additive is provided with free radicals which are generated by decomposition after heat absorptionand can block combustion. Fire extinguishing agent components in the composite fire extinguishing agent for the lithium battery can quickly extinguish open fire in a combustion area; the inhibition additive can quickly enter the lithium ion battery by virtue of the fire extinguishing agent to inhibit a thermal runaway reaction and block a combustion reaction; the driving gas provides a power source, which is helpful for extinguishing agents and inhibiting diffusion of additives. The purposes of quickly extinguishing open fire and effectively inhibiting the thermal runaway reaction of the lithium ion battery so as to reduce the after-combustion risk are achieved.

Description

technical field [0001] The invention relates to the technical field of lithium ion batteries, in particular to a composite fire extinguishing agent for lithium batteries. Background technique [0002] Lithium-ion batteries contain high-energy materials and flammable electrolytes. If used improperly, it is easy to cause accidents such as smoke, fire, and explosion. In recent years, with the widespread application of lithium-ion batteries in electric bicycles, energy storage and electric vehicles, related fires and explosions have occurred frequently. [0003] The fire extinguishing mechanism of the fire extinguishing agent is related to the four factors of burning fuel, oxygen, heat and combustion chain reaction. These four factors need to be combined correctly to ignite the fire and continue to burn. To extinguish a fire requires breaking one or more of the links between these factors, or changing the balance between them. Therefore, there are four main fire extinguishing ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): A62D1/00A62D1/06A62C3/16
CPCA62C3/16A62D1/00A62D1/0092A62D1/06
Inventor 王羽平党志敏陈冬相佳媛陈建
Owner ZHEJIANG NARADA POWER SOURCE CO LTD
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