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Preparation method of cyanate ester based wear-resistant self-lubricating swash plate

A cyanate ester, self-lubricating technology, used in mechanical equipment, devices for coating liquid on surfaces, special surfaces, etc., can solve problems such as increasing the difficulty of preparation, harmful to the social environment, and increasing social energy consumption, and achieves easy spray thickness. , the composition is reasonable, the effect of improving mechanical properties and heat resistance

Inactive Publication Date: 2019-09-27
浙江儒商科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] The existing base resin used for swash plate preparation is generally polyimide or polyamide-imide, which can improve the self-lubricating performance of the swash plate to a certain extent, but the friction of the wear-resistant coating thus formed, In particular, the dry friction performance and adhesion need to be improved; there are also some reports on the use of polyetherketone, polyethersulfone or polyethersulfoneketone materials for swashplates, such materials have certain heat resistance, However, the adhesion is poor and the compatibility with other materials is poor; and the existing base resins cannot be dissolved in conventional solvents such as acetone, and all need toxic and environmentally friendly solvents to dissolve, which is harmful to the social environment. The curing process of the basic resin is very harsh, and it needs to exceed 300°C, and the time is several hours, which not only increases the difficulty of preparation, but also increases the energy consumption of the society
Existing swash plates have certain deficiencies in self-lubrication, heat resistance, wear resistance and adhesion

Method used

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  • Preparation method of cyanate ester based wear-resistant self-lubricating swash plate
  • Preparation method of cyanate ester based wear-resistant self-lubricating swash plate

Examples

Experimental program
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Effect test

Embodiment 1

[0028] The preparation method of a kind of wear-resistant self-lubricating swash plate based on cyanate ester involved in this embodiment includes the following steps: preparation of accelerator, preparation of graphene oxide / cyanate ester-epoxy resin composite material, wear-resistant Preparation, spraying and curing of self-lubricating coatings.

[0029]Step (1) preparation of accelerator: add methyl tin mercaptide aqueous solution and fatty acid mercaptoethanol ester, slowly and evenly drop ammoniacal liquor or sodium hydroxide aqueous solution to pH value 7.5 under stirring, reaction temperature is 45 ℃, and reaction time is After 3 hours, stand still and separate layers, separate the upper layer ammonium chloride aqueous solution or sodium chloride aqueous solution, and the lower oil phase is washed with water to obtain the fatty acid mercaptoethanol ester methyl tin liquid product. The mercaptan methyl tin used is one of the three major organotin varieties. It is a trans...

Embodiment 2

[0042] The preparation method of a kind of wear-resistant self-lubricating swash plate based on cyanate ester involved in this embodiment includes the following steps: preparation of accelerator, preparation of graphene oxide / cyanate ester-epoxy resin composite material, wear-resistant Preparation, spraying and curing of self-lubricating coatings.

[0043] Step (1) preparation of accelerator: add methyl tin mercaptide aqueous solution and fatty acid mercaptoethanol ester, slowly and evenly drop ammoniacal liquor or sodium hydroxide aqueous solution to pH value 7.7 under stirring, reaction temperature is 48 ℃, and reaction time is After 2.5 hours, static layering, the upper layer of ammonium chloride aqueous solution or sodium chloride aqueous solution was separated, and the lower oil phase was washed with water to obtain the fatty acid mercaptoethanol ester methyl tin liquid product. The mercaptan methyl tin used is one of the three major organotin varieties. It is a transpare...

Embodiment 3

[0056] The preparation method of a kind of wear-resistant self-lubricating swash plate based on cyanate ester involved in this embodiment includes the following steps: preparation of accelerator, preparation of graphene oxide / cyanate ester-epoxy resin composite material, wear-resistant Preparation, spraying and curing of self-lubricating coatings.

[0057] Step (1) Preparation of accelerator: add methyl tin mercaptide aqueous solution and fatty acid mercaptoethanol ester, slowly and uniformly drop ammoniacal liquor or sodium hydroxide aqueous solution to pH value 8 under stirring, reaction temperature is 50 ℃, reaction time is After 3 hours, stand still and separate layers, separate the upper layer ammonium chloride aqueous solution or sodium chloride aqueous solution, and the lower oil phase is washed with water to obtain the fatty acid mercaptoethanol ester methyl tin liquid product. The mercaptan methyl tin used is one of the three major organotin varieties. It is a transpa...

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Abstract

The invention discloses a preparation method of a cyanate ester based wear-resistant self-lubricating swash plate. The preparation method comprises following steps: preparation of a promoter; preparation of an oxidized graphene / cyanate ester-epoxy resin composite material; preparation of a wear-resistant self-lubricating coating layer; spraying; and curing; wherein the oxidized graphene / cyanate ester-epoxy resin composite material is dissolved in acetone so as to obtain a composite material acetone solution with a mass concentration of 40%; 30 mass parts of a solid lubricating agent is added into 100 mass parts of the composite material acetone solution for uniform mixing so as to obtain a wear-resistant coating layer solution. The wear-resistant coating is reasonable in composition, and excellent in heat resistance and bonding performance, so that the swash plate prepared based on the wear-resistant coating possesses excellent wear resistance, wet state friction performance and oil state friction state are both much better than that of conventional resin swash plates, and the requirements of automobile air-conditioning compressor can be satisfied.

Description

technical field [0001] The invention relates to the preparation of a swash plate of an automobile air-conditioning compressor, in particular to a preparation method of a wear-resistant self-lubricating swash plate based on cyanate ester. Background technique [0002] Automobile air-conditioning compressor is the key component of automobile air-conditioning system, among them, the swash-plate air-conditioning compressor has the advantages of simple structure, reliable adjustment, good balance performance of the machine, and high speed, etc. The most common compressor accounts for about 80% of the passenger car market, and it has a tendency to expand further. [0003] In the swash plate air conditioner compressor, the swash plate rotates at the same speed as the main shaft passing through the swash plate, and the swash plate drives the piston to reciprocate through the connection between the sliding shoe and the piston, and then completes the gas compression through the one-wa...

Claims

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Application Information

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IPC IPC(8): C09D179/04C09D163/00C09D127/18C09D7/61C09D7/62C09D7/63F04B39/00F04B27/08F04B27/10B05D3/02B05D5/08B05D7/14B05D7/24
CPCB05D3/0254B05D5/083B05D7/14B05D7/24C08K2003/2227C08K2003/2251C08K2003/2289C08K2003/3009C08K2201/011C08L2201/08C08L2205/03C09D7/61C09D7/62C09D7/63C09D7/69C09D179/04F04B27/086F04B27/1054F05C2251/14F05C2253/12C08L63/00C08L27/18C08K13/06C08K3/042C08K3/04C08K3/30C08K3/045C08K3/08C08K3/22C08K5/58
Inventor 布占印
Owner 浙江儒商科技有限公司
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