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Flame-retardant epoxy resin

An epoxy resin, flame retardant technology, applied in the field of flame retardant epoxy resin, can solve the problems of poor thermal performance of epoxy resin, poor flame retardancy, human injury, etc., achieve low volatility, good electrical insulation, The effect of improving flame retardancy

Pending Publication Date: 2019-08-06
ANHUI MEIJIA NEW MATERIAL
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Due to the active epoxy groups in the molecular structure, they can cross-link with various types of curing agents to form an insoluble polymer epoxy resin with a three-way network structure, which has excellent electrical and mechanical properties. Performance and chemical corrosion resistance are widely used in coatings, civil engineering, and electronics, but due to the poor thermal properties of epoxy resins, its application range is limited. Therefore, it is necessary to prepare epoxy resins with excellent thermal properties and high flame retardant properties. Resin becomes the focus of research
[0003] Existing epoxy resins use halogens to flame-retardant, but halogens will produce toxic gases during combustion, causing harm to the human body, and the flame retardancy is poor

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0034] a. Reserve raw materials, the epoxy resin raw materials include by weight: 10-20 parts of cyclic hydrocarbon compounds, 10-15 parts of flame retardant and curing compounds, 60-65 parts of epoxy resin monomers, flame retardant micro Capsule 10-15 parts, modified phenolic resin 8-10 parts, expanded graphite 0.5-1 part, curing agent 3-5 parts, talcum powder 1.5-4.5 parts, quartz sand 2-5 parts, defoamer 0.5-1 part , 0.2-1.5 copies of leveling agent;

[0035] b, with 60-65 parts by weight of epoxy resin monomer, 10-15 parts by weight of flame-retardant microcapsules, 0.5-1 parts by weight of expanded graphite and 8-10 parts by weight of modified phenolic resin, mechanically After stirring for 45-60min, then 30-70kHz ultrasonic dispersion for 30-45min;

[0036] c. After ultrasonically dispersing the mixed system obtained in step b to remove the dispersion medium, add 10-15 parts of flame retardant and curing compound; raise the temperature of the added flame retardant and c...

Embodiment 2

[0041] No flame retardant microcapsules added:

[0042] a. Reserve raw materials, the epoxy resin raw materials include by weight: 10-20 parts of cyclic hydrocarbon compound, 10-15 parts of flame retardant and curing compound, 60-65 parts of epoxy resin monomer, modified phenolic resin 8-10 parts, 0.5-1 part of expanded graphite, 3-5 parts of curing agent, 1.5-4.5 parts of talcum powder, 2-5 parts of quartz sand, 0.5-1 part of defoamer, 0.2-1.5 parts of leveling agent;

[0043] b. 60-65 parts by weight of epoxy resin monomer, 0.5-1 parts by weight of expanded graphite and 8-10 parts by weight of modified phenolic resin are mechanically stirred at 400-600rpm for 45-60min, and then stirred at 30-70 kilohertz Ultrasonic dispersion for 30-45min;

[0044]c. After ultrasonically dispersing the mixed system obtained in step b to remove the dispersion medium, add 10-15 parts of flame retardant and curing compound; raise the temperature of the added flame retardant and curing compound...

Embodiment 3

[0049] No flame retardant microcapsules and expanded graphite:

[0050] a. Reserve raw materials, the epoxy resin raw materials include by weight: 10-20 parts of cyclic hydrocarbon compound, 10-15 parts of flame retardant and curing compound, 60-65 parts of epoxy resin monomer, modified phenolic resin 8-10 parts, 3-5 parts of curing agent, 1.5-4.5 parts of talcum powder, 2-5 parts of quartz sand, 0.5-1 part of defoamer, 0.2-1.5 parts of leveling agent;

[0051] b. 60-65 parts by weight of epoxy resin monomer and 8-10 parts by weight of modified phenolic resin are mechanically stirred at 400-600 rpm for 45-60 minutes, and then ultrasonically dispersed at 30-70 kilohertz for 30-45 minutes;

[0052] c. After ultrasonically dispersing the mixed system obtained in step b to remove the dispersion medium, add 10-15 parts of flame retardant and curing compound; raise the temperature of the added flame retardant and curing compound to 100-120 ° C, and use 300- 500rpm for mechanical st...

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PUM

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Abstract

The invention discloses flame retardant epoxy resin. The epoxy resin comprises the following raw material components in parts by weight: 10-20 parts of a cyclic hydrocarbon compound, 10-15 parts of aflame retardant and curing compound, 60-65 parts of an epoxy resin monomer, 10-15 parts of a flame retardant microcapsule, 8-10 parts of modified phenolic resin, 0.5-1 part of expanded graphite, 3-5 parts of a curing agent, 1.5-4.5 parts of talcum powder, 2-5 parts of quartz sand, 0.5-1 part of a defoaming agent and 0.2-1.5 parts of a leveling agent. The flame retardant microcapsule contains a halogen-free flame retardant, the halogen-free flame retardant is an inorganic flame retardant, and the halogen-free flame retardant contains more than 40% of aluminum hydroxide Al (OH) 3, has flame retardant, smoke abatement and filling three functions, and can generate synergistic flame retardant effect with various substances. The flame retardant microcapsule is a pollution-free inorganic flame retardant, the epoxy resin contains flame retardant and curing compounds, the flame retardant and curing compounds contain the phenolic resin, and an important application of the phenolic resin is as abinder. The phenolic resin can be used as abrasive tools and refractory materials, can provide required mechanical strength, heat resistance and electrical properties for the epoxy resin after crosslinking.

Description

technical field [0001] The invention relates to a flame-retardant epoxy resin, in particular to a flame-retardant epoxy resin. Background technique [0002] Epoxy resins generally refer to organic compounds containing two or more epoxy groups in their molecules. All polymer compounds containing epoxy groups in their molecular structures are collectively referred to as epoxy resins. Except for a few, their relative molecules The quality is not high. The molecular structure of epoxy resin is characterized by active epoxy groups in the molecular chain. The epoxy groups can be located at the end, middle or ring structure of the molecular chain. Due to the active epoxy groups in the molecular structure, they can cross-link with various types of curing agents to form an insoluble polymer epoxy resin with a three-way network structure, which has excellent electrical and mechanical properties. Performance and chemical corrosion resistance are widely used in coatings, civil engineer...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L63/00C08L61/14C08L61/34C08L91/06C08K9/10C08K3/22C08K3/34C08K3/36C08K7/24
CPCC08L63/00C08L2201/02C08L2205/035C08K2003/2227C08L61/14C08L61/34C08L91/06C08K9/10C08K3/22C08K3/34C08K3/36C08K7/24
Inventor 王方银张雪梅王峰范宽政
Owner ANHUI MEIJIA NEW MATERIAL
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