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Preparation method of conductive reinforced alginate fiber

A conductivity-enhancing, seaweed fiber technology, applied in the manufacture of conductive/antistatic filaments, fiber chemical characteristics, alginate artificial filaments, etc., can solve the problem of affecting fiber performance, difficult to apply to textiles, conductive substances Easy peeling and other problems, to achieve good biocompatibility and degradation absorption, good high ion adsorption, and improve the effect of electrochemical performance

Inactive Publication Date: 2019-07-23
珠海阿尔吉科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Due to the unique molecular structure and wide molecular weight distribution of natural polymers, the mechanical strength of seaweed fibers is low, and the conductivity of fibers is low (the mass specific resistance of pure seaweed fibers is 4.48×10 8 Ω·g / cm 2 ), the field of application is limited
[0003] The conjugated structure in the polymer main chain of some conductive fibers is a stiff molecular chain, which is difficult to dissolve and melt, which causes difficulties in spinning; others use ordinary synthetic fibers as the matrix, and some conductive substances are passed through physical, mechanical, It is made by coating the surface of the fiber by means of chemical and other means. Since the conductive component of this type of conductive fiber only covers the surface of the matrix fiber, the conductive substance is easy to peel off after friction and washing, and the abrasion resistance and washing resistance are poor, which affects the fiber. Performance; there are also some composite or blended conductive materials with many chemical substances, which have a certain impact on environmental pollution
The above-mentioned conductive fibers are difficult to be applied to textiles by direct spinning of conductive polymers.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0024] A preparation method of seaweed fiber with enhanced conductivity, comprising the following steps:

[0025] (1) Dissolve 30 g of sodium alginate in 0.7 kg of deionized water to obtain a sodium alginate solution with a concentration of 4.1% by mass.

[0026] (2) Add 6 g of nano-polymer material, that is, polyaniline nanoparticles, to the prepared sodium alginate solution, first mechanically stir for one hour, then ultrasonically treat for 30 minutes, and disperse to obtain a uniformly dispersed mixed solution.

[0027] (3) Add a small amount of sodium hypochlorite as a viscosity modifier to the prepared mixed solution to adjust the viscosity of the mixed solution to 1500mPa·S.

[0028] (4) The mixed solution is then filtered and vacuum defoamed for ten hours to obtain a composite spinning solution.

[0029] (5) The extrusion spinning solution is solidified into filaments through a 3.8% calcium chloride coagulation bath, and the temperature of the coagulation bath is kept...

Embodiment 2

[0033] It is basically the same as Example 1, except that the amount of polyaniline nanoparticles added in step 2) is 3.75 g.

[0034] Adopt YG321 type fiber specific resistance meter to test and test seaweed fiber mass specific resistance, the resistivity of the seaweed fiber of the present embodiment is 6.75×10 6 Ω·g / cm 2 .

Embodiment 3

[0036] It is basically the same as Example 1, except that the amount of polyacetylene nanoparticles added in step 2) is 3 g.

[0037] Adopt YG321 type fiber specific resistance meter to test and test the mass specific resistance of seaweed fiber, the resistivity of the seaweed fiber of the present embodiment is 9.45×10 6 Ω·g / cm 2 .

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PUM

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Abstract

The invention provides a preparation method of conductive reinforced alginate fiber. The preparation method comprises the following steps that 1, sodium alginate is dissolved in water to prepare a sodium alginate solution; 2, a conductive nano polymer material is added into the sodium alginate solution obtained in step 1 and evenly stirred for ultrasonic dispersion, and a uniformly dispersed mixedsolution is obtained; 3, the mixed solution obtained in step 2 is filtered and subjected to vacuum defoaming, and a spinning solution is obtained; 4, the spinning solution obtained in step 3 is extruded and then solidified into yarn through a coagulating bath, and then washing, rolling and drying are carried out, wherein the conductive nano polymer material is selected from one or more of polyaniline nano particles, polyacetylene nano particles, polypyrrole nano particles and polythiophene nano particles. According to the method, the original advantages of the alginate fiber are guaranteed, the conductivity is also improved, and the method can be applied to the field of textiles.

Description

technical field [0001] The invention belongs to the technical field of preparing marine biological composite fibers, and in particular relates to a method for preparing seaweed fibers with enhanced electrical conductivity. Background technique [0002] Seaweed fiber uses sodium alginate extracted from brown algae (such as kelp and macroalgae) as raw material to produce new fiber materials with special properties and functions that can be used in textile health care, military industry and medical treatment by using proprietary spinning technology and equipment. Seaweed fiber has the following excellent properties: super flame retardant properties; excellent hemostatic and antibacterial effects; green production process. Due to the unique molecular structure and wide molecular weight distribution of natural polymers, the mechanical strength of seaweed fibers is low, and the conductivity of fibers is low (the mass specific resistance of pure seaweed fibers is 4.48×10 8 Ω·g / cm ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): D01F8/18D01F8/16D01F8/10D01F9/04D01F1/09D01F1/10
CPCD01F1/09D01F1/10D01F8/10D01F8/16D01F8/18D01F9/04
Inventor 王晓莹吉冈诚王磊矫庆泽
Owner 珠海阿尔吉科技有限公司
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