A flexible wax oil hydrotreating process

A technology for hydrotreating and wax oil hydrogenation, which is applied in the directions of hydrotreating process, hydrocarbon oil treatment products, and hydrocarbon oil treatment, etc., can solve the problem that the quality of catalytically cracked gasoline does not reach the best, is not conducive to the effective control of high-quality gasoline, and has no reaction. Material combination processing technology and other issues to achieve the effect of improving octane number

Active Publication Date: 2021-07-09
CHINA PETROLEUM & CHEM CORP +1
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  • Abstract
  • Description
  • Claims
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Problems solved by technology

However, since wax oil is directly hydrogenated after mixing with LCO, the hydrogenation depth of LCO cannot be effectively controlled, and the sulfur content or nitrogen content of the mixed hydrogenation product (catalytic cracking raw material) can only be used as the control target, which is not conducive to the production of high-quality gasoline with LCO effective control of
[0004] In summary, compared with the existing LCO hydrogenation technology and wax oil hydrotreating technology, LCO is usually blended directly into the wax oil hydrotreating unit for hydrogenation, and the hydrogenated wax oil obtained after mixing hydrogenation Together with hydrogenated LCO as the raw material of the catalytic cracking unit, that is, LCO is hydrogenated and then returned to the catalytic cracking unit. Since the hydrogenation depth of LCO is not deliberately controlled, the quality of catalytic cracked gasoline has not reached the best, and there is no reaction material coupling Combined processing technology

Method used

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  • A flexible wax oil hydrotreating process
  • A flexible wax oil hydrotreating process
  • A flexible wax oil hydrotreating process

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Experimental program
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Effect test

Embodiment 1-4

[0046] Protective agents FZC-100, FZC-105 and FZC106 are hydrogenation protective agents developed and produced by Sinopec Fushun Petrochemical Research Institute; catalyst FF-24 is developed and produced by Sinopec Fushun Petrochemical Research Institute Hydrotreating catalysts.

[0047] Table 1 Main properties of wax oil feedstock

[0048] wax oil 1 wax oil 2 LCO Density, g / cm 3

0.904 0.937 0.935 Distillation range, ℃ 325~550 345~620 156~380 Sulfur content, wt% 2.2 1.5 1.1 Nitrogen content, wt% 0.103 0.245 0.08 Aromatic content, wt% — — 91.6

[0049] Table 2 Process conditions

[0050]

[0051] Continued Table 2 Process Conditions

[0052]

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Abstract

The invention discloses a flexible wax oil hydrogenation treatment process. The wax oil raw material is mixed with hydrogen and enters the first hydrotreating reactor, and the material passing through the upper hydrotreating catalyst bed is divided into two streams; one stream of material is extracted from the first hydrotreating reactor through the middle of the bed, and mixed with LCO mixed into the second hydrotreating reactor for hydrogenation reaction; another stream of material continues to flow down through the lower hydrotreating catalyst bed, and the obtained first hydrotreating reaction material and second hydrotreating reaction material undergo gas-liquid Separation and fractionation to obtain naphtha, diesel and hydrogenated heavy fractions. The invention provides a flexible hydrogenation treatment process for flexibly processing different raw material oils on a hydrogenation device to produce high-quality catalytic cracking raw materials, which can make full use of the heat carried by part of the first hydrogenation treatment materials to realize the first hydrogenation Coupling operation of the hydrotreating reactor and the second hydrotreating reactor.

Description

technical field [0001] The invention belongs to the field of petroleum refining, and in particular relates to a flexible hydroprocessing process for flexibly producing high-quality catalytic cracking raw materials using wax oil and LCO as raw material oils. Background technique [0002] Fluid Catalytic Cracking (FCC) is one of the important means of lightening heavy oil, but with the deterioration and heavyness of catalytic cracking raw materials, its operating conditions are becoming more and more stringent, and the yield of light products and products However, the hydroprocessing technology of catalytic cracking raw materials can not only remove the content of impurities such as sulfur, nitrogen, and metals, but also improve the cracking performance of the feed, reduce the severity of FCC operation, improve product distribution, and increase the selectivity of target products. Reduce the yield of dry gas and coke, improve the economics of FCC unit, reduce the sulfur conten...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C10G67/00
CPCC10G67/00C10G2300/1037C10G2400/04
Inventor 刘涛李宝忠张学辉彭绍忠崔哲乔凯
Owner CHINA PETROLEUM & CHEM CORP
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