A kind of preparation method of lithium battery hard carbon negative electrode material
A negative electrode material, lithium battery technology, applied in battery electrodes, nanotechnology for materials and surface science, secondary batteries, etc. High capacity, increased specific surface area, good rate performance
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Embodiment 1
[0015] 1) Weigh 50 parts by weight of waste car brake pads and fill them into a porcelain ark, place the ark in a quartz tube furnace, fill with excess nitrogen, heat up to 400°C, keep it for 2 hours, then raise it to 1200°C, and keep it for 2 hours After naturally cooling to room temperature, the sample obtained was ball milled for 30 minutes, passed through a 200-mesh sieve, pickled 3 times with 150 parts by weight of HCl with a mass concentration of 65%, filtered by ultrasonic dispersion for 30 minutes, and then washed with 150 parts by weight of HCl Alkaline washing with 30% LiOH solution for 3 times, ultrasonic dispersion for 30 minutes, suction filtration, and 150 parts by weight deionized water washing for 3 times until the filtrate was neutral, and the filtered sample was dried in an oven at 100°C for 24 hours , grind and pass through a 200-mesh sieve to obtain phenolic resin pyrolytic carbon, for subsequent use;
[0016] 2) Transfer the above-mentioned phenolic resin ...
Embodiment 2
[0020] It is exactly the same as Example 1, except that 60 parts by weight of waste automobile brake pads and 2 parts by weight of PbO / CNTs composite nanomaterials are added.
Embodiment 3
[0022] It is exactly the same as Example 1, except that 55 parts by weight of waste automobile brake pads and 5 parts by weight of PbO / CNTs composite nanomaterials are added.
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