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A carbon fiber for a polysulfone resin-based composite material and a preparation method thereof

A polysulfone resin and composite material technology, applied in the direction of carbon fiber, fiber treatment, fiber chemical characteristics, etc., can solve the problems of fiber aging and hardening, polysulfone matrix resin impregnation, etc. , The effect of simple process

Active Publication Date: 2019-05-07
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In the sizing process, the present invention introduces a new type of suspension-like carbon fiber sizing agent prepared by a physical stirring and mixing method with polysulfone resin powder as the main body, sodium polyacrylate as the main dispersant, polyvinyl alcohol as a stabilizing aid, and a physical mixing method to solve the problem. Solved the problems of poor impregnation of polysulfone matrix resin and aging and hardening of fibers
In the sizing process, the infrared radiation heating process before sizing is introduced, and the horizontal hot air drying oven drying process is introduced in the drying process after sizing, which solves the problem of uniformity of polysulfone resin suspension sizing agent spreading on the carbon fiber surface and fiber drying, etc. question

Method used

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  • A carbon fiber for a polysulfone resin-based composite material and a preparation method thereof
  • A carbon fiber for a polysulfone resin-based composite material and a preparation method thereof
  • A carbon fiber for a polysulfone resin-based composite material and a preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1~4

[0048] Examples 1 to 4 are a manufacturing method of 48K carbon fibers suitable for polysulfone resin-based composite materials, including polymerization, spinning, pre-oxidation, low-temperature carbonization, high-temperature carbonization, surface treatment, water washing, drying before sizing, sizing, Drying after sizing, winding and winding production process. The specific process is as follows:

[0049] Step 1: Aggregation.

[0050] Adopt sodium thiocyanate aqueous solution as solvent to carry out solution polymerization, take acrylonitrile, methyl methacrylate, sodium itaconate as polymerization monomer, the weight ratio of acrylonitrile, methyl methacrylate, sodium itaconate is 92.0: 6.8:1.2, the feed concentration of the total polymerized monomers is 25.8wt%, and the initiator azobisisobutyronitrile is added simultaneously, and the amount of the initiator is 0.65wt% based on the total amount of all polymerized monomers, and the polymerization reaction temperature is ...

Embodiment 5~8

[0068] Examples 5-8 are a method for manufacturing 50K carbon fibers suitable for polysulfone resin-based composite materials. The specific process includes polymerization, spinning, pre-oxidation, low-temperature carbonization, high-temperature carbonization, surface treatment, water washing, drying before sizing, Production process of sizing, drying after sizing, and winding. The specific process of this embodiment is the same as that of Examples 1-4, wherein the parameters of spinning, pre-oxidation, low-temperature carbonization, high-temperature carbonization, and sizing are different.

[0069]Step 1: Aggregation. Described polymerization production procedure is identical with the method described in embodiment 1~4 step 1, adopts sodium thiocyanate aqueous solution to carry out solution polymerization as solvent, wherein the parameter that polymerization production procedure changes is that the comonomer proportioning of solution polymerization reaction is different, The...

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Abstract

The invention discloses a carbon fiber for a polysulfone resin-based composite material and a preparation method of the carbon fiber. The preparation process of the carbon fiber for the polysulfone resin-based composite material sequentially comprises the production processes of polymerization, spinning, pre-oxidation, low-temperature carbonization, high-temperature carbonization, surface treatment, water washing, drying before sizing, sizing, drying after sizing, and winding, wherein a polysulfone resin-based suspension sizing agent is adopted during sizing; the polysulfone resin-based suspension sizing agent is prepared from polysulfone resin powder, sodium polyacrylate, polyvinyl alcohol and deionized water; the total mass of the solid components is 100%, the polysulfone resin powder accounts for 65-75wt%, the sodium polyacrylate accounts for 10-15wt%, and the polyvinyl alcohol accounts for 15-20wt%. The prepared carbon fiber is suitable for preparing a polysulfone resin-based composite material, and the prepared composite material is high in heat resistance and excellent in interface mechanical property.

Description

technical field [0001] The invention belongs to the technical field of carbon fiber preparation, in particular to a carbon fiber for polysulfone resin-based composite materials and a preparation method thereof. Background technique [0002] Composite materials are an important development direction in the field of materials in recent years. Resin-based composite materials prepared with carbon fiber as a reinforcing phase and high-performance thermosetting or thermoplastic resin as a matrix have broad application prospects in aerospace, automotive, wind power and many other fields. At present, most commonly used matrix resins are thermosetting resins, which have disadvantages such as poor toughness, high water absorption, and poor stability under hot and humid conditions. Therefore, high-performance thermoplastic resins have attracted more and more attention. Among them, polysulfone resin has excellent mechanical properties, high temperature resistance, good dimensional stabi...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): D06M15/63D06M15/333D06M15/263D06M10/00D01F9/22D06M101/40
Inventor 季春晓黄翔宇曹阿民刘瑞超袁玉红吴嵩义许璐璐田晓婧
Owner CHINA PETROLEUM & CHEM CORP
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