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Reforming hydrogen production reactor and its reformer and method for reforming hydrogen production reaction

A reforming hydrogen production and reactor technology, applied in chemical instruments and methods, hydrogen, inorganic chemistry, etc., can solve the problems of increasing the energy consumption of the raw gas compressor, increasing the number of catalyst active centers, and the catalyst being prone to carbon deposition and deactivation. , to achieve the effect of long service life, improved conversion efficiency, and not easy carbon deposition and inactivation

Active Publication Date: 2021-03-02
SINOPEC ENG +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0008] The existing hydrogen production conversion furnace is filled with a nickel-based catalyst of a certain particle size and shape in the furnace tube, which often causes uneven loading, causing the raw material gas to drift, resulting in a low conversion rate of the raw material, and the catalyst is prone to carbon deposition and deactivation. operating cycle
In addition, the catalyst with smaller particle size is loaded in the furnace tube, although it can increase the loading amount of the catalyst, increase the number of catalyst active centers, and improve the processing capacity and conversion rate of raw materials to a certain extent, the disadvantage is that the smaller the catalyst size, the furnace The larger the pipe pressure drop, the higher the energy consumption of the feed gas compressor

Method used

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  • Reforming hydrogen production reactor and its reformer and method for reforming hydrogen production reaction
  • Reforming hydrogen production reactor and its reformer and method for reforming hydrogen production reaction
  • Reforming hydrogen production reactor and its reformer and method for reforming hydrogen production reaction

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Embodiment 1

[0079] Such as figure 1 , figure 2 As shown, the reforming hydrogen production reactor adopted in this embodiment includes a pressure-bearing shell 12 with a first straight pipe 16 at the upper end and a second straight pipe 17 at the lower end. In the catalytic reaction unit 13 , the upper part of the first straight pipe 16 is provided with an air inlet 1 , and the lower part of the second straight pipe 17 is provided with an air outlet 2 . The catalytic reaction unit 13 is composed of upper micro-catalytic reaction plates 10 and lower micro-catalytic reaction plates 11 which are sleeved alternately in a cylindrical shape, and the upper micro-catalytic reaction plates 10, the lower micro-catalytic reaction plates 11 and the housing 12 and the center pipe 6 are in the form of Arranged coaxially; the upper micro-catalytic reaction plate 10 is sealed and fixed with the top sealing plate 5, and the lower micro-catalytic reaction plate 11 is sealed and fixed with the bottom seal...

Embodiment 2

[0091] Such as figure 1 , image 3 , Figure 12 As shown, the reforming hydrogen production reactor and the reformer of the present embodiment are compared with the reactor size, the height of the catalytic reaction unit, the distance between the opening at the bottom of the central tube and the sealing plate 8 at the bottom of the catalytic reaction unit of the embodiment 1, and the upper micro-catalytic reaction The distance between the bottom of the plate 10 and the bottom sealing plate 8, the distance between the bottom of the lower micro-catalytic reaction plate 11 and the top sealing plate 5, the distance between two adjacent catalytic reaction plates, the distance between the outermost micro-catalytic reaction plate and the inner wall of the housing, The substrate material of the micro-reaction plate is the same as the NiO loading parameter of the active component per unit area. The difference from Example 1 is that the micro-catalytic reaction plate in this example i...

Embodiment 3

[0097] Such as figure 1 , Figure 4 , Figure 10As shown, the reforming hydrogen production reactor and reforming furnace of the present embodiment are compared with the reactor size, the height of the catalytic reaction unit, the distance from the opening at the bottom of the central tube to the bottom sealing plate 8 of the catalytic reaction unit, and the upper micro-catalytic reaction of the embodiment 2. The distance between the bottom of the plate 10 and the sealing plate 8 at the bottom of the catalytic reaction unit, the distance between the bottom of the lower micro-catalytic reaction plate 11 and the top sealing plate 5, the distance between two adjacent catalytic reaction plates, the ring between the outermost micro-catalytic reaction plate and the inner wall of the housing The gap distance, the substrate material of the micro-reaction plate and the loading amount of active component NiO per unit area are the same. The difference from Example 2 is that the micro-c...

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Abstract

The present disclosure relates to a reforming hydrogen production reactor and its reformer, and a method for reforming hydrogen production. The amount of catalytically active metal is reduced, the catalyst is not easy to be deactivated by carbon deposition, the distance from the reaction gas to the catalytic active center is shortened, the mass transfer resistance and the pressure drop of the reactor are reduced, and the conversion rate of the hydrogen production reaction is improved; It flows from the center to the outside, the flow channel area gradually increases, and the temperature of the reaction plate gradually increases, which is beneficial to the improvement of the conversion rate of the hydrogen production reaction as a volume increase and an endothermic reaction; the reforming hydrogen production reactor has a wide range of applications. As the furnace tube of the hydrogen reformer, it can be applied to different types of reformers. The hydrogen production method using the reforming hydrogen production reformer reduces the furnace tube pressure, the product space-time yield per unit volume of the catalyst in the furnace tube is high, and the raw gas processing capacity can be converted, and the hydrogen production reaction requirements can be met.

Description

technical field [0001] The present disclosure relates to the field of reforming hydrogen production, in particular, to a reforming hydrogen production reactor and its reformer, and a method for reforming hydrogen production reaction. Background technique [0002] Hydrogen is not only an important chemical raw material, but also a clean fuel. Hydrogen plays an increasingly important role in modern industry, especially petrochemical industry, fuel cell and other national economies. Under the multiple pressures of increasing crude oil quality and inferior quality in the world, increasing demand for clean oil products, continuously improving quality standards, and increasingly stringent environmental regulations, the demand for hydrogen is also increasing, and the demand for hydrogen production is also increasing. Devices also put forward higher requirements. [0003] Hydrogen production processes mainly include water electrolysis, light hydrocarbon steam reforming, partial ox...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01J8/02B01J8/04C01B3/38C01B3/40
CPCB01J8/0257B01J8/0465B01J2208/022C01B3/38C01B3/40Y02P20/52
Inventor 张旭戴文松
Owner SINOPEC ENG
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