Colored-light waterborne functional paint applicable to indoor entertainment as well as preparation method and application thereof
A functional paint, water-based technology, applied in the field of paint, to achieve the effects of good water dispersibility, strong color light effect and high fluorescence quantum efficiency
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Embodiment 1
[0035] The first step is the preparation of quantum dot colloidal water dispersion
[0036] (1) Preparation of oil-soluble fluorescent quantum dots
[0037] a. Preparation of anionic precursor complex: add selenium powder and sulfur powder to 2ml of trioctyl phosphine oxide, stir and dissolve at 25°C to obtain an anionic precursor complex mixture;
[0038] b. Preparation of cationic precursor complex: add cadmium oxide and zinc acetate to 10ml of ODE, then add 3ml of oleic acid, then put the system under inert gas, then heat to 160℃, keep heating for 40 min Until the color of the solution is light yellow, the temperature is reduced to 80°C and the system is vacuumed for 30 to remove the water in the system;
[0039] c. Heat the obtained cationic precursor complex to the reaction temperature of 320 ℃, and when the temperature reaches the preset temperature, quickly inject the body mixture of the anion obtained in step 1) with a syringe, and then adjust the temperature to 310 ℃ to keep ...
Embodiment 2
[0050] The first step is the preparation of quantum dot colloidal water dispersion
[0051] (1) The preparation of oil-soluble fluorescent quantum dots is the same as in Example 1;
[0052] (2) The modification of the oil-soluble fluorescent quantum dot aqueous solution is the same as in Example 1;
[0053] (3) Preparation of quantum dot colloidal water dispersion
[0054] Three different colors of fluorescent quantum dot powders are prepared with a mass ratio of 1:1:1 to prepare a colloidal aqueous dispersion of quantum dots with a colloidal concentration of 20mg / ml;
[0055] In the second step, the preparation of the color light water-based functional coating is the same as in Example 1.
[0056] The obtained color light water-based functional paint is applied to the walls of schools and home entertainment rooms. Under dark conditions, irradiation with a 400-nanometer wavelength laser can make the walls show sporadic red, yellow, and green point color light effects. It has a similar e...
Embodiment 3
[0058] The first step is the preparation of quantum dot colloidal water dispersion
[0059] (1) The preparation of oil-soluble fluorescent quantum dots is the same as in Example 1;
[0060] (2) The modification of the oil-soluble fluorescent quantum dot aqueous solution is the same as in Example 1;
[0061] (3) The preparation of the quantum dot colloidal aqueous dispersion is the same as in Example 2;
[0062] The second step is the preparation of color light water-based functional coatings
[0063] Raw material ratio: 48ml aqueous acrylic emulsion, 50ml quantum dot colloidal water dispersion, 1.58g OK520 matting powder, 2.8g B-3500 glass powder, 1.6g tripropylene glycol butyl ether film former, 0.52g hydroxyethyl cellulose Leveling agent, 0.54g JLJ-6 defoamer, 1.12g HF206 thickener, 0.09g Huake-981 anti-mold agent and 20ml deionized water.
[0064] The preparation method is the same as in Example 1.
[0065] In this embodiment, the mass ratio of fluorescent quantum dots has been improv...
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