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Preparation method of nuclear-grade zirconium alloy return scrap cast ingots

A zirconium alloy and return material technology is applied in the field of preparation of nuclear grade zirconium alloy return material ingots, which can solve problems such as low yield and achieve the effect of improving the recovery range.

Active Publication Date: 2019-03-01
西安西部新锆科技股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the finished product rate of nuclear-grade zirconium alloy processing is low, and a large amount of zirconium alloy return materials are produced during the production process. Usually, the zirconium alloy return materials generated during the processing of nuclear-grade zirconium alloys account for about 20% to 60% of the input amount of raw materials; in addition , the industry's internal demand to reduce costs and participate in international competition and the external pressure of environmental protection make the recycling of nuclear-grade zirconium alloy return materials an urgent problem to be solved in the nuclear-grade zirconium alloy production industry

Method used

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  • Preparation method of nuclear-grade zirconium alloy return scrap cast ingots
  • Preparation method of nuclear-grade zirconium alloy return scrap cast ingots
  • Preparation method of nuclear-grade zirconium alloy return scrap cast ingots

Examples

Experimental program
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Effect test

Embodiment 1

[0046] This embodiment includes the following steps:

[0047] Step 1, using a hand-held X-ray fluorescence spectrometer to quickly identify and classify the grades of the zirconium alloy returned materials;

[0048] Step 2. Select zirconium alloy return material with the same grade as Zr-4 alloy or similar chemical composition to carry out pretreatment; the zirconium alloy return material is scrap zirconium alloy return material or block zirconium alloy return material; the scrap zirconium alloy return material Alloy return materials include all kinds of chips generated during the processing of zirconium materials; the block zirconium alloy return materials include tubular rod-shaped zirconium alloy return materials and non-tube rod-shaped zirconium alloy return materials generated in the processing of zirconium materials; The pretreatment of zirconium alloy return material includes the following steps:

[0049] Step 201. Cutting: classify scrap zirconium alloy return materia...

Embodiment 2

[0071] This embodiment includes the following steps:

[0072] Step 1, using a hand-held X-ray fluorescence spectrometer to quickly identify and classify the grades of the zirconium alloy returned materials;

[0073] Step 2. Select zirconium alloy return material with the same grade as Zr-4 alloy or similar chemical composition to carry out pretreatment; the zirconium alloy return material is scrap zirconium alloy return material or block zirconium alloy return material; the scrap zirconium alloy return material Alloy return materials include all kinds of chips generated during the processing of zirconium materials; the block zirconium alloy return materials include tubular rod-shaped zirconium alloy return materials and non-tube rod-shaped zirconium alloy return materials generated in the processing of zirconium materials; The pretreatment of zirconium alloy return material includes the following steps:

[0074] Step 201, shearing: classify the chip-like zirconium alloy retur...

Embodiment 3

[0095] This embodiment includes the following steps:

[0096] Step 1, using a hand-held X-ray fluorescence spectrometer to quickly identify and classify the grades of the zirconium alloy returned materials;

[0097] Step 2. Select zirconium alloy return material with the same grade as Zr-4 alloy or similar chemical composition to carry out pretreatment; the zirconium alloy return material is scrap zirconium alloy return material or block zirconium alloy return material; the scrap zirconium alloy return material Alloy return materials include all kinds of chips generated during the processing of zirconium materials; the block zirconium alloy return materials include tubular rod-shaped zirconium alloy return materials and non-tube rod-shaped zirconium alloy return materials generated in the processing of zirconium materials; The pretreatment of zirconium alloy return material includes the following steps:

[0098] Step 201. Cutting: classify scrap zirconium alloy return materia...

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Abstract

The invention discloses a preparation method of nuclear-grade zirconium alloy return scrap cast ingots. The preparation method comprises the steps that 1, nuclear-grade zirconium alloy return scrap isidentified and classified; 2, pretreatment is conducted on the zirconium alloy return scrap same as nuclear-grade zirconium alloy return scrap cast ingots in mark or containing similar chemical component to the cast ingots; 3, the zirconium alloy return scrap subjected to pretreatment is selected and prepared into a consumable electrode and a zirconium block; 4, vacuum consumable smelting is conducted on the consumable electrode and a zirconium block to obtain the nuclear-grade zirconium alloy return scrap cast ingots. According to the mass content of O and N in the nuclear-grade zirconium alloy return scrap cast ingots, the nuclear-grade zirconium alloy return scrap containing different mass contents of O and N is selected, the mass contents of O and N in the nuclear-grade zirconium alloy return scrap cast ingots are accurately controlled, the nuclear-grade zirconium alloy cast ingots containing components conforming to GB / T13747 zirconium and zirconium alloy chemical analysis methodare obtained, effective recovery of zirconium alloy return scrap is achieved, and the recovery rate of the zirconium alloy return scrap is greatly improved.

Description

technical field [0001] The invention belongs to the technical field of nuclear-grade zirconium alloy preparation, and in particular relates to a method for preparing a nuclear-grade zirconium alloy return ingot. Background technique [0002] After entering the 21st century, my country's nuclear power industry has entered a stage of rapid development. The demand for nuclear-grade zirconium alloys as cladding materials for nuclear power has increased significantly, and the localization of nuclear-grade zirconium alloys is also gradually progressing. However, the finished product rate of nuclear-grade zirconium alloy processing is low, and a large amount of zirconium alloy return materials are produced during the production process. Usually, the zirconium alloy return materials generated during the processing of nuclear-grade zirconium alloy account for about 20% to 60% of the input amount of raw materials; in addition , The industry's internal demand to reduce costs to partici...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22C1/03C22C16/00C22B9/20
CPCC22B9/20C22C1/03C22C16/00
Inventor 田锋严宝辉文惠民周军石明华袁波孙玮珑刘蛟
Owner 西安西部新锆科技股份有限公司
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