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Tundish magnesium calcium ladle cover casting materials and preparation method thereof

A magnesia-calcium, tundish technology, applied in the field of refractory materials for tundish, can solve problems such as poor thermal shock resistance, peeling, and steel structure burning, achieve good thermal insulation performance and thermal shock resistance, and improve thermal shock stability The effect of improving the strength at medium temperature

Active Publication Date: 2018-12-28
阳泉市庚光高温材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Research and analysis found that the integrally welded steel structure undergoes large deformation with drastic temperature changes, and the difference in expansion coefficient between the steel structure and the refractory material prevents the refractory material from being in close contact with the steel structure for a long time, and the refractory material is easy to crack and peel off, resulting in steel The structure was burned, eventually leading to complete failure of the cladding
It can be seen that the poor service thermal shock resistance of the cover refractory is the main reason for the damage of the tundish cover, and a tundish cover castable and its preparation method (ZL201410242492.5) invented in the early stage can better solve the problem of thermal shock stability. However, the introduction of carbon can easily cause contamination of molten steel and the thermal conductivity is still relatively high, which needs to be solved urgently

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0036] A tundish magnesium-calcium overcasting material, comprising the following components in weight percent:

[0037] Magnesia particles 20wt%, particle size 0.088-10mm; magnesia-calcium sand particles 20wt%, particle size 0.088-10mm; quicklime particles 5wt%, particle size 0.088-8mm; magnesia fine powder 10wt%, particle size less than 0.088mm; organic magnesium compound 0.5wt%, particle size less than 0.088mm; organic calcium 1wt%, particle size less than 0.088mm; thermoplastic micropowder 2wt%, particle size less than 0.045mm; magnesium oxide powder 2wt%, particle size less than 0.01mm Water reducing agent 0.1wt%.

[0038] Wherein, in this embodiment, the MgO content in the magnesia particles is greater than 99wt%. The CaO of the magnesia-calcium sand particles is more than or equal to 20wt%. The CaO content of the quicklime particles is greater than 95% by weight. The MgO content of the magnesia fine powder is greater than 99wt%. The organomagnesium compound is a mix...

Embodiment 2

[0045] A tundish magnesium-calcium overcasting material, comprising the following components in weight percent:

[0046] Magnesia particles 30wt%, particle size 0.088-10mm; magnesia-calcium sand particles 30wt%, particle size 0.088-10mm; quicklime particles 10wt%, particle size 0.088-8mm; magnesia fine powder 15wt%, particle size less than 0.088mm; organic magnesium compound 2wt%, particle diameter less than 0.088mm; organic calcium 4wt%, particle diameter less than 0.088mm; thermoplastic micropowder 4wt%, particle diameter less than 0.045mm; Aqua 0.15wt%.

[0047] Wherein, in this embodiment, the MgO content in the magnesia particles is greater than 99wt%. The CaO of the magnesia-calcium sand particles is more than or equal to 20wt%. The CaO content of the quicklime particles is greater than 95% by weight. The MgO content of the magnesia fine powder is greater than 99wt%. The organomagnesium compound is a mixture of dicyclopentadiene magnesium and dimethylcyclopentadienyl...

Embodiment 3

[0054] A tundish magnesium-calcium overcasting material, comprising the following components in weight percent:

[0055] Magnesia particles 40wt%, particle size is 0.088 ~ 10mm; magnesia calcium sand particles 40wt%, particle size is 0.088 ~ 10mm; quicklime particles 15wt%, particle size is 0.088 ~ 8mm; magnesia fine powder 20wt%, particle size is less than 0.088mm; organic magnesium compound 3wt%, particle diameter less than 0.088mm; organic calcium 6wt%, particle diameter less than 0.088mm; thermoplastic micropowder 6wt%, particle diameter less than 0.045mm; Aqua 0.2wt%.

[0056] Wherein, in this embodiment, the MgO content in the magnesia particles is greater than 99wt%. The CaO of the magnesia-calcium sand particles is more than or equal to 20wt%. The CaO content of the quicklime particles is greater than 95% by weight. The MgO content of the magnesia fine powder is greater than 99wt%. The organomagnesium compound is a mixture of dicyclopentadiene magnesium and dimethy...

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PUM

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Abstract

The invention relates to tundish magnesium calcium ladle cover casting materials. The tundish magnesium calcium ladle cover casting materials comprise the following components in percentage by weight:20-40wt% of magnesium sand granules, 20-40wt% of magnesium calcium sand granules, 5-15wt% of quick lime granules, 10-20wt% of a magnesium sand fine powder, 0.5-3wt% of an organic magnesium compound,1-6wt% of organic calcium, 2-6wt% of a thermoplastic micro powder, 2-8wt% of a magnesium oxide micro powder and 0.1-0.2wt% of a water reducing agent. The invention further relates to a method for preparing the tundish magnesium calcium ladle cover casting materials. According to the tundish magnesium calcium ladle cover casting materials and the preparation method thereof disclosed by the invention, the heat shock stability of fireproof materials is improved, besides, dissipation of heat quantity is effectively reduced, and favorable heat preservation properties and favorable thermal shock resistance of the materials are guaranteed; and when the tundish magnesium calcium ladle cover casting materials are applied to high-quality steel continuous casting tundishes, the temperature of a housing of a tundish ladle cover can be reduced by 10% or above averagely, and the average service life reaches 15 times or above.

Description

technical field [0001] The invention belongs to the technical field of refractory materials for tundishes, and in particular relates to a tundish magnesium-calcium covering castable with excellent thermal shock resistance and heat preservation performance and purified molten steel and a preparation method thereof. Background technique [0002] In recent years, with the enhancement of the metallurgical function of the tundish and the demand for energy saving and consumption reduction, the role of the cover of the continuous casting tundish has become more and more prominent. The quality of its use directly affects the output and quality of continuous casting steel. The function of the cover is mainly reflected in: it plays the role of heat preservation and heat insulation during the baking and pouring process of the tundish, improves the baking efficiency of the tundish and reduces the heat dissipation of the molten steel; thus protects the ladle slide mechanism from the direc...

Claims

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Application Information

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IPC IPC(8): C04B35/043
CPCC04B35/043C04B2235/3208C04B2235/447C04B2235/48
Inventor 白华蓉李斌
Owner 阳泉市庚光高温材料有限公司
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