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Bio-filler for absorbing and degrading hydrophobic organic waste gases, and preparation method of bio-filler

A technology of organic waste gas and biological fillers, applied in separation methods, chemical instruments and methods, gas treatment, etc., can solve the problems of reducing treatment efficiency, dry shrinkage, and no VOCs, so as to promote oxidation-reduction reactions, improve adhesion and Humidity, promotes the effect of absorbing pollutants

Active Publication Date: 2018-12-21
广东省南方环保生物科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

For example, the Chinese patent application whose publication number is CN 104524965 A utilizes ceramsite, nutrients and other materials to form regular shape biological fillers. A large amount of nutrients are beneficial to the growth of microorganisms, and the fillers shrink during the molding process. No effective buffs, limited strength stability
The Chinese patent application with the publication number CN 105597696 A uses the bamboo charcoal powder on the surface of the filler to adsorb pollutants in the water phase, and then absorbs and purifies them through microorganisms. However, the composition of VOCs is complex and most of them are hydrophobic. The effective adsorption capacity of pollutants is not significant, which increases the difficulty of obligate microorganisms in the treatment of pollutants and reduces the treatment efficiency
[0005] For the development of biological fillers, the domestic technology is uneven, and the development and production of biological fillers with unique properties are still in the preliminary stage. When dealing with hydrophobic components, the limitations are more obvious. Enterprises that really invest a lot of manpower and material resources in the research and development of biological fillers There are only a handful of them, so that the country has not found a method that can simply and effectively absorb and degrade VOCs with complex components

Method used

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  • Bio-filler for absorbing and degrading hydrophobic organic waste gases, and preparation method of bio-filler
  • Bio-filler for absorbing and degrading hydrophobic organic waste gases, and preparation method of bio-filler
  • Bio-filler for absorbing and degrading hydrophobic organic waste gases, and preparation method of bio-filler

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0034] 1. Preparation of biofiller for adsorption and degradation of hydrophobic organic waste gas

[0035] The biological filler for adsorbing and degrading hydrophobic organic waste gas includes the following raw materials in percentage by weight: 5% of modified iron-based β-cyclodextrin, 5% of diatomaceous earth, 15% of biochar (powder), 35% of ceramsite, oxidation Calcium 5%, silicate inorganic gel (P.Ⅱ42.5R Portland cement) 20% and water 15%.

[0036] Preparation:

[0037] (1) Add the modified iron-based β-cyclodextrin into water, stir until completely dissolved, then add calcium oxide, and continue stirring until completely dissolved to obtain Sol A;

[0038] (2) Mix diatomite, biochar and silicate inorganic gel evenly to obtain powder B;

[0039](3) Soak the ceramsite in sol A for 5 minutes and place it in the granulator, keep rotating at a constant speed, control the speed at 25r / min, and control the angle of the turntable at 45°; then divide the powder B into 8 time...

Embodiment 2

[0049] 1. Preparation of biofiller for adsorption and degradation of hydrophobic organic waste gas

[0050] The biological filler for adsorbing and degrading hydrophobic organic waste gas includes the following raw materials in percentage by weight: 10% of modified iron-based β-cyclodextrin, 5% of diatomaceous earth, 20% of biochar (powder), 25% of ceramsite, oxidation Calcium 5%, silicate inorganic gel (P.Ⅱ42.5R Portland cement) 20% and water 15%.

[0051] Preparation:

[0052] (1) Add the modified iron-based β-cyclodextrin into water, stir until completely dissolved, then add calcium oxide, and continue stirring until completely dissolved to obtain Sol A;

[0053] (2) Mix diatomite, biochar and silicate inorganic gel evenly to obtain powder B;

[0054] (3) Soak the ceramsite in sol A for 5 minutes and place it in the granulator, keep rotating at a constant speed, the speed is controlled at 20r / min, and the angle of the turntable is controlled at 45°; then the powder B is d...

Embodiment 3

[0060] 1. Preparation of biofiller for adsorption and degradation of hydrophobic organic waste gas

[0061] The biological filler for adsorbing and degrading hydrophobic organic waste gas includes the following raw materials in percentage by weight: 17% of modified iron-based β-cyclodextrin, 5% of diatomaceous earth, 15% of biochar (powder), 20% of ceramsite, oxidation Calcium 3%, silicate inorganic gel (P.Ⅱ42.5R Portland cement) 20% and water 20%.

[0062] Preparation:

[0063] (1) Add the modified iron-based β-cyclodextrin into water, stir until completely dissolved, then add calcium oxide, and continue stirring until completely dissolved to obtain Sol A;

[0064] (2) Mix diatomite, biochar and silicate inorganic gel evenly to obtain powder B;

[0065] (3) Soak the ceramsite in sol A for 5 minutes and place it in the granulator, keep rotating at a constant speed, the speed is controlled at 20r / min, and the angle of the turntable is controlled at 45°; then the powder B is d...

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Abstract

The invention discloses bio-filler for absorbing and degrading hydrophobic organic waste gases, and a preparation method of the bio-filler. The bio-filler is prepared from the following raw materials:modified iron-based beta-cyclodextrin, diatomaceous earth, biochar, ceramsite, calcium oxide, silicate inorganic gel and water. The preparation method of the bio-filler comprises the following steps:dissolving the modified iron-based beta-cyclodextrin and the calcium oxide to obtain sol A; evenly mixing the diatomaceous earth, the biochar and the silicate inorganic gel to obtain powder B; dipping the ceramsite into the sol A for 5min, then placing the product in a drum granulator for granulating together with the powder B, spraying the sol A in the granulation process so as to obtain preliminarily-cured gel granules, and curing to obtain the bio-filler for absorbing and degrading the hydrophobic organic waste gases. The bio-filler prepared by the method can be widely applied to various types of organic waste gas biological purification systems, and enables the hydrophobic organic waste gases to more easily penetrate a wet water film on the surface of the filler and be in contact withmicroorganisms so as to enable the hydrophobic organic waste gases to be subjected to efficient catalytic degradation.

Description

technical field [0001] The invention belongs to the technical field of material chemistry and environmental protection, and in particular relates to a biological filler for adsorbing and degrading hydrophobic organic waste gas and a preparation method thereof. Background technique [0002] At present, it is the general trend for the country to tighten the emission limits of organic pollutants. How to ensure that the concentration of organic pollutants reaches the standard in the future, it is urgent to upgrade the existing organic pollution control technology to adapt to the new emission standards. As my country pays more and more attention to volatile organic pollutants (VOCs) and environmental protection regulations continue to strictly control the emission of VOCs, VOCs treatment technology is gradually improving and perfecting. The main reason why VOCs are difficult to deal with is because of their wide variety and wide sources. The complex organic pollution waste gas i...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01D53/85B01D53/44
CPCB01D53/44B01D53/85B01D2251/95B01D2257/708Y02A50/20
Inventor 郑理慎占金华陈锐东陈志平宋旭祝雅杰卢咏
Owner 广东省南方环保生物科技有限公司
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