A kind of concrete viscosity reducer and preparation method thereof

A technology for viscosity reducing agent and concrete, applied in the field of concrete viscosity reducing agent, can solve the problems of reducing the fluidity of concrete, adverse effects on the later strength of concrete, difficult mass production and application, etc., achieves good compatibility and stability, and improves pump performance. The effect of delivering construction performance and easy mass production

Active Publication Date: 2020-07-10
GUIZHOU DR SHI TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

But at present, most of the viscosity reducers on the market have the following problems: incompatibility with polycarboxylate superplasticizers, delamination or flocculation, and even reduce the fluidity of concrete, and adversely affect the strength of concrete in the later stage; The preparation process is complicated, the reaction conditions are harsh, and it is difficult to realize mass production and application; the raw materials of large monomers are not easy to obtain; the synthesis cost is high

Method used

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  • A kind of concrete viscosity reducer and preparation method thereof
  • A kind of concrete viscosity reducer and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0027] Embodiment one: a kind of preparation method of concrete viscosity reducer, comprises the following steps:

[0028] S1) Synthesis of maleic anhydride polyethylene glycol ester (MAH-PEG600) solution: Add 500.0 parts of polyethylene glycol (PEG600) into a four-neck flask, heat up to 50°C, start stirring, and put in maleic anhydride (MAH) 86.0 part, then add 0.1 part of hydroquinone and 0.9 part of catalyst in sequence, heat up to 70-80°C, and react for 3-4 hours under constant stirring, the esterification reaction stops, and the yellow or red liquid is polyethylene glycol maleate Ester (MAH-PEG600) solution;

[0029] S2) Synthesis of bottom liquid: 200.0 parts of water, 200.0 parts of maleic anhydride polyethylene glycol ester (MAH-PEG600), and 3.5 parts of chain transfer agent were put into a four-necked flask and stirred and mixed;

[0030] S3) Synthesis of liquid A: Add 50.0 parts of water, 35.0 parts of acrylic acid (AA), 12.0 parts of isooctyl acrylate (2-EAH), and ...

Embodiment 2

[0038] Embodiment two: a kind of preparation method of concrete viscosity reducer, comprises the following steps:

[0039] S1) Synthesis of maleic anhydride polyethylene glycol ester (MAH-PEG800) solution: Add 500.0 parts of polyethylene glycol (PEG800) into a four-necked flask, heat up to 50°C, start stirring, and put in maleic anhydride (MAH) 65.0 Then add 0.07 parts of hydroquinone and 0.7 parts of catalyst in sequence, heat up to 70-80°C, and react for 3-4 hours under constant stirring, the esterification reaction stops, and the yellow or red liquid is polyethylene glycol maleate Ester (MAH-PEG800) solution;

[0040] S2) Synthesis of bottom liquid: 200.0 parts of water, 200.0 parts of maleic anhydride polyethylene glycol ester (MAH-PEG800) and 3.5 parts of chain transfer agent were put into a four-necked flask and stirred;

[0041] S3) Synthesis of liquid A: Add 50.0 parts of water, 35.0 parts of acrylic acid (AA), 12.0 parts of isooctyl acrylate (2-EAH), and 0.2 parts of...

Embodiment 3

[0049] Embodiment three: a kind of preparation method of concrete viscosity reducer, comprises the following steps:

[0050] S1) Synthesis of maleic anhydride polyethylene glycol ester (MAH-PEG1000) solution: Add 500.0 parts of polyethylene glycol (PEG1000) into a four-neck flask, heat up to 50°C, start stirring, and put in maleic anhydride (MAH) 52.0 Then add 0.05 parts of hydroquinone and 0.5 parts of catalyst in sequence, heat up to 70-80°C, and react for 3-4 hours under constant stirring, the esterification reaction stops, and the yellow or red liquid is polyethylene glycol maleate Ester (MAH-PEG1000) solution;

[0051] S2) Synthesis of bottom liquid: put 200.0 parts of water, 200.0 parts of maleic anhydride polyethylene glycol ester (MAH-PEG1000), and 3.5 parts of chain transfer agent into a four-necked flask and stir and mix;

[0052] S3) Synthesis of liquid A: Add 50.0 parts of water, 35.0 parts of acrylic acid (AA), 12.0 parts of isooctyl acrylate (2-EAH), and 0.2 par...

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Abstract

The invention provides a concrete viscosity reducer. A method comprises steps as follows: an MAH-PEG (maleic anhydride-polyethylene glycol) solution is synthesized; 500.0 parts of PEG are added to a four-neck flask, heated to 50 DEG C and started to be stirred, 86.0 parts of MAH are added, 0.1 parts of hydroquinone and 0.9 parts of a catalyst are sequentially added, the mixture is heated to 70-80DEG C and constantly stirred to react for 3-4 h, and a yellow or red solution, namely, the MAH-PEG solution is obtained after the esterification reaction. The concrete viscosity reducer has certain water reduction performance and good viscosity reduction effects and can be blended into concrete at a low water-binder ratio to notably reduce the viscosity of the concrete without affecting the flowability of concrete, and the pumping construction performance is improved; the concrete viscosity reducer is low in doping amount, has higher cost performance than a silica fume admixture, and no negative influence is caused to the strength of concrete; the concrete viscosity reducer is compounded with concrete admixtures such as ordinary polycarboxylate superplasticizer products and the like, has good compatibility and stability and cannot have layering or flocculation phenomenon.

Description

technical field [0001] The invention relates to the technical field of concrete viscosity reducer, in particular to a concrete viscosity reducer and a preparation method thereof. Background technique [0002] With the rapid development of the construction industry and the increase of our country's infrastructure, the scale of civil engineering has expanded unduly, the amount of concrete has also continued to increase, and the requirements for concrete have also increased. The continuous emergence of some high-rise, long-span, and important buildings with special functional requirements, such as skyscrapers, super-long-span bridges, and giant water conservancy projects, requires concrete to have higher strength, better durability, and better Stability, these requirements have led to the gradual development of concrete from ordinary to high performance and even ultra-high performance. However, the improvement of concrete strength is mainly achieved by increasing the amount of...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08F283/06C08F220/06C08F220/18C04B24/26
CPCC04B24/2694C08F283/065C08F220/1808
Inventor 陈杰邓妮田应兵方世昌皮永奇
Owner GUIZHOU DR SHI TECH
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