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Bionic microcapsule containing molybdenum disulfide and preparing method and application of microcapsule

A technology of molybdenum disulfide and microcapsules, which is applied in the direction of microcapsule preparation and microsphere preparation, can solve the problems of low synthesis efficiency and general stability of microcapsule structure, and achieve the effect of reducing friction and wear

Inactive Publication Date: 2018-08-31
WUHAN UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

It synthesizes microcapsules by phase separation, and the core material of microcapsules is guaiac resin. However, the synthesis method of phase separation has low synthesis efficiency, and the structural stability of the synthesized microcapsules is average.

Method used

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  • Bionic microcapsule containing molybdenum disulfide and preparing method and application of microcapsule
  • Bionic microcapsule containing molybdenum disulfide and preparing method and application of microcapsule

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Embodiment Construction

[0036] The following examples further illustrate the technical solutions of the present invention, but are not intended to limit the protection scope of the present invention.

[0037] The preparation process of the biomimetic microcapsule containing molybdenum disulfide of the present invention is as follows:

[0038] 1) Preparation of wall material: Mix formaldehyde, urea and deionized water, the amount of formaldehyde and urea is 70%-80% formaldehyde and 20%-30% urea in terms of mass percentage, heat and stir to obtain urea-formaldehyde resin prepolymer , the reaction temperature is 70°C;

[0039] 2) Preparation of the core material suspension: adding molybdenum disulfide to a solution with an emulsifier (sodium lauryl sulfate) content of 2 wt%, and ultrasonically dispersing to obtain a molybdenum disulfide suspension;

[0040] 3) Using toluene as a solvent, the urea-formaldehyde resin prepolymer and molybdenum disulfide suspension are slowly added to the external water ph...

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Abstract

The invention discloses a bionic microcapsule containing molybdenum disulfide and a preparing method and application of the microcapsule. The bionic microcapsule comprises a core material and a wall material. The core material is wrapped in the wall material through an emulsion reaction of molybdenum disulfide. Urea resin is adopted as the wall material. Methylbenzene is used as an external waterphase, a urea resin prepolymer and a molybdenum disulfide suspension are slowly added to the external water phase for an emulsion reaction, and pH is controlled to be 3-3.8; after the reaction ends, centrifugal separation, cleaning and drying are conducted to obtain the bionic microcapsule. The invention further discloses a water lubricated bearing bionic material which is prepared by mixing the bionic microcapsule containing molybdenum disulfide with a high polymer substrate material. The obtained water lubricated bearing bionic material has wear resistance to a certain extent; meanwhile, itis avoided that when a composite is prepared, the compatibility difference of different materials is quite large, the composite is prone to cracks, additives are prone to leakage and filling lubricants can hardly have lubricating and wear reduction functions under the extreme conditions.

Description

technical field [0001] The invention belongs to the technical field of composite polymer materials, and mainly relates to a bionic microcapsule and a preparation method thereof. Background technique [0002] Water-lubricated stern bearings have been used on ships since the middle of the 19th century. At the beginning, metals were used to make water-lubricated stern bearings. However, due to the corrosiveness of water media, especially seawater, and the electrochemical Corrosion makes the metal corrosion of the stern bearing very serious and accompanied by greater wear. [0003] Iron plow wood materials have been used in ship stern bearings since the middle of the 19th century. Through research, it has been found that resin, resin essence, hard resin and bitter essence, the self-lubricating properties of iron plow wood materials and the transformation of resin and essence Closely related, on the one hand, the resin stored in the gap is squeezed out of the gap under the actio...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08K9/10C08K3/30C08L23/06B01J13/14
CPCC08K9/10B01J13/14C08K3/30C08K2003/3009C08L23/06C08L2207/062C08L61/24
Inventor 郭智威杨宗榕袁成清白秀琴
Owner WUHAN UNIV OF TECH
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