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Additive with functional group double-terminated structure as well as preparation and application of additive

A functional group, double-end capping technology, applied in the field of additives with functional group double end capping structure and tire functional group double end capping structure, can solve the problems of high hysteresis loss, unsatisfactory effect, and poor anti-aging performance.

Active Publication Date: 2018-07-06
TONGJI UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the results of these two techniques are not ideal
For example, the addition of large amounts of carbon black to rubber compositions generally results in a high degree of hysteresis loss, so the use of such compounds in tires can result in excessive heat build-up and poor tear resistance
As another example, adding large amounts of sulfur to a rubber composition generally results in poor aging resistance of the formulation, and moreover, simply increasing the degree of vulcanization to achieve high modulus is often very impractical

Method used

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  • Additive with functional group double-terminated structure as well as preparation and application of additive
  • Additive with functional group double-terminated structure as well as preparation and application of additive
  • Additive with functional group double-terminated structure as well as preparation and application of additive

Examples

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preparation example Construction

[0048] A preparation method of an additive with a functional group double-capped structure, comprising the following steps:

[0049] (1): take dicarboxylic acid and alkali, or directly take the salt of dicarboxylic acid and place it in a polar solvent, heat until the solution is completely transparent, and obtain solution A of the dicarboxylic acid salt product;

[0050] (2): Take functional group carboxylic acid and alkali, or place the salt of functional group carboxylic acid in a polar solvent, and heat until the solution is completely transparent to obtain solution B of functional group carboxylate product;

[0051] (3): under stirring condition, solution A, solution B are mixed with the metal M salt solution that configures, and react to obtain solid product, filter, wash, dry, promptly obtain the additive of target product functional group double-capping structure;

[0052] For example, the structural formula of the dicarboxylic acid can be: HOOC-R 1 -(A x B y ) m -R...

Embodiment 1

[0075] An additive with a functional group double-capped structure, its chemical structural formula is:

[0076]

[0077] The preparation method of above-mentioned compound, comprises the following steps:

[0078] (1) Add 1 L of distilled water and 16 g of solid sodium hydroxide (purity ≥ 97%, purchased from Aladdin) into a 2 L beaker. After the sodium hydroxide was completely dissolved, 42.05g of 3,3'-dithiodipropionic acid (purity≥99.0% (GC)(T), purchased from TCI) was added. The above mixture was heated to 90°C and stirred vigorously for 1 hour until the solution was completely transparent. (Solution A)

[0079] (2) Add 1 L of distilled water and 8 g of solid sodium hydroxide (purity ≥ 97%, purchased from Aladdin) into a 2 L beaker. After the sodium hydroxide was completely dissolved, 27.62g of 4-hydroxybenzoic acid (purity≥99%, purchased from Aladdin) and 64.09g of sodium ricinoleate (purity>90.0% (T), purchased from TCI) were added. The above mixture was heated to ...

Embodiment 2

[0084] An additive with a functional group double-capped structure, its chemical structural formula is:

[0085]

[0086] The preparation method of above-mentioned compound, comprises the following steps:

[0087] (1) Add 1 L of distilled water and 16 g of solid sodium hydroxide (purity ≥ 97%, purchased from Aladdin) into a 2 L beaker. After the sodium hydroxide was completely dissolved, 42.05g of 3,3'-dithiodipropionic acid (purity≥99.0% (GC)(T), purchased from TCI) was added. The above mixture was heated to 90°C and stirred vigorously for 1 hour until the solution was completely transparent. (Solution A)

[0088] (2) Add 1 L of distilled water and 16 g of solid sodium hydroxide (purity ≥ 97%, purchased from Aladdin) into a 2 L beaker. After the sodium hydroxide is completely dissolved, add 30.82g 3,4-dihydroxybenzoic acid (purity≥97%, purchased from Aladdin) and 60.10g 12-hydroxystearic acid (purity>80% (GC), purchased from TCI). The above mixture was heated to 90°C ...

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Abstract

The invention relates to an additive with a functional group double-terminated structure as well as a preparation and application of the additive. The additive has a chemical structural formula as shown in the specification, wherein n is an oxidation state of metal M and is equal to 2, 3 or 4; A is one of oxygen, sulfur, carbon, nitrogen, phosphorus and silicon, and x is larger than or equal to 0and is smaller than or equal to 10; B is one of oxygen, sulfur, carbon, nitrogen, phosphorus and silicon, and y is larger than or equal to 0 and is smaller than or equal to 10; (AxBy)m shows that atoms are connected by chemical bonds, and x and y are not zero at the same time; m is larger than or equal to 0 and is smaller than or equal to 10; z is smaller than or equal to 50; R1 and R2 are aliphatic chains, alicyclic hydrocarbons or aromatic compounds of which the carbon atom numbers do not exceed 50; and F1 and F2 are organic groups with functional groups and have different structures. The additive prepared by using the preparation method can be introduced to rubber compositions so as to comprehensively improve the hardness, wet skid resistance, dynamic mechanical property and tensile property of rubber, and even, in parts of exemplary embodiments, the rubber compositions containing the additive with the functional group double-terminated structure have improved Shore hardness, elongation at break and wet skid resistance.

Description

technical field [0001] The present invention relates to the field of an additive with a tire functional group double-capped structure, in particular to an additive with a functional group double-capped structure and its preparation and application. Background technique [0002] It is desirable in the tire industry to increase the modulus of compounds used in base tread compositions and tire wire cover compounds. In order to increase the modulus of the above-mentioned compounds, it is common practice to add a large amount of reinforcing fillers, such as carbon black and silica, to these compounds, or to increase the degree of vulcanization of these compounds. However, the results produced by these two techniques are not ideal. For example, the addition of large amounts of carbon black to rubber compositions generally results in a high degree of hysteresis loss, and thus the use of such compounds in tires results in excessive heat build-up and poor tear resistance. As anothe...

Claims

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Application Information

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IPC IPC(8): C08K5/372C08L7/00C09D7/63C09J11/06C09D133/00C09D175/04C09D171/00C09D163/00C08L9/06C08L9/02C08L83/04C08L75/04C08L23/16C07F5/06A61K8/58A61Q19/00A61Q11/00
CPCA61K8/58A61Q11/00A61Q19/00C07F5/069C08K5/0091C08L7/00C08L9/02C08L9/06C08L23/16C08L75/04C08L83/04C09D133/00C09D163/00C09D171/00C09D175/04C09J11/06
Inventor 熊文韬王琳夏斌王小荣
Owner TONGJI UNIV
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