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Low temperature thermoplastic material

A low-temperature thermoplastic and compounding technology, applied in the field of medical polymer materials, can solve the problems of inability to maintain shape, high price, high price, etc., and achieve strong X-ray permeability, strong plasticity, and good memory Effect

Inactive Publication Date: 2018-05-29
广州天泓医疗科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, polycaprolactone itself also has some defects. It softens too quickly above 60°C. If it is heated for a long time, it will sag due to gravity, and even cannot maintain its shape. If it is not handled properly, it may stick together and cannot be used.
In addition, its strength at room temperature is suitable for immobilization of fingers or upper limbs, but it is still slightly insufficient for lower limbs or trunk, and there is a certain gap compared with plaster
Finally, polycaprolactone is a special polymer material, and the current price is high, so the low-temperature thermoplastic board made is also expensive

Method used

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Examples

Experimental program
Comparison scheme
Effect test

specific Embodiment approach 2

[0014] This specific embodiment differs from specific embodiment one in that its components consist of 70 parts of polycaprolactone, 2 parts of crosslinking aids, 30 parts of fillers, 2 parts of diffusing oil, and 2 parts of pigments; its production process steps : 1. Mixing, 2. Granulation, 3. Extrusion / injection molding, 4. Punching and cutting, 5. Irradiation, the radiation dose is 8KGy. If the irradiation is less than 0.1kGy, the cross-linking is not enough and it is inconvenient to operate after heating, and the elongation at break of the material greater than 20KGy is too low, and it is easy to break. If polycaprolactone is less than 60 parts, its elongation at break is too low, it is easy to break, and its memory is less than 50%, and its strength is insufficient if it is greater than 90 parts.

[0015] The cross-linking auxiliary agent is composed of one or more combinations: multifunctional acrylate, trimethylolpropane triacrylate, trimethylolpropane trimethacrylate, ...

specific Embodiment approach 3

[0018] The difference between this specific embodiment and the specific embodiment one is that the component consists of 80 parts of polycaprolactone, 3 parts of crosslinking auxiliary agent, 40 parts of filler, 4 parts of diffusion oil, and 4 parts of pigment; its production process steps: 1. Mixing, 2. Granulation, 3. Extrusion / injection molding, 4. Punching and cutting, 5. Irradiation, the irradiation dose is 15KGy. If the irradiation is less than 0.1kGy, the cross-linking is not enough and it is inconvenient to operate after heating, and the elongation at break of the material greater than 20KGy is too low, and it is easy to break. If polycaprolactone is less than 60 parts, its elongation at break is too low, it is easy to break, and its memory is less than 50%, and its strength is insufficient if it is greater than 90 parts.

[0019] The cross-linking auxiliary agent is composed of one or more combinations: multifunctional acrylate, trimethylolpropane triacrylate, trimeth...

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PUM

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Abstract

The invention relates to a medical polymer material, in particular to a polymer thermoplastic material. The polymer thermoplastic material is composed of 60-90 parts of polycaprolactone, 0.1-5 parts of a crosslinking assistant, and 10-50 parts of filler. The production process steps include: 1. material mixing, 2. granulation, 3. extrusion / injection molding, 4. punching and cutting, and 5. irradiation at an irradiation dose of 0.1KGy-20KGy. If the irradiation is less than 0.1kGy, the crosslinking is insufficient, and operation after heating is inconvenient, if the irradiation is greater than 20KGy, the elongation at break of the material is too low, and the material fractures easily. The thermoplastic material provided by the invention can be softened and molded into arbitrary shape at lowtemperature, can restore the hardness and strength of plastic itself after cooling, and has the advantages of light weight, strong plasticity, certain strength, strong X ray permeability, good memory, strong repeat mouldability, no irritation to skin and easy rapid degradation in soil after abandonment, thus being an ideal medical external fixation material. The low temperature thermoplastic material provided by the invention is mainly used for fixation of radioactive therapy, bone surgery fixation, making of orthopaedic and rehabilitation braces, etc.

Description

technical field [0001] The invention relates to a medical polymer material, in particular to a polymer thermoplastic material. Background technique [0002] The low-temperature thermoplastic sheets currently on the market are generally made of polycaprolactone as the main raw material. The melting point of polycaprolactone is only 60°C. It has a certain strength below 60°C, but it softens rapidly in a water bath above 60°C. After taking it out of the water bath, the temperature can quickly drop to about 45°C and continue to maintain a softened state. Shaped and does not cause harm to the patient's skin, it is very suitable as an immobilization material. However, polycaprolactone itself also has some defects. It softens too quickly above 60°C. If it is heated for a long time, it will sag due to gravity, and even cannot maintain its shape. If it is not handled properly, it may stick together and cannot be used. In addition, its strength at room temperature is suitable for im...

Claims

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Application Information

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IPC IPC(8): C08L67/04C08K13/04C08K13/02C08J3/28C08J3/24
CPCC08K13/04C08J3/24C08J3/28C08J2367/04C08K13/02C08L67/04
Inventor 何海梁秋严刘健升袁祖国
Owner 广州天泓医疗科技有限公司
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