Preparing method of improved melamine resin essence microcapsule finishing agent
A technology of essence microcapsules and melamine resin, which is applied in the direction of microcapsule preparation, microsphere preparation, fiber treatment, etc. It can solve the problems of short fragrance retention time, low fragrance encapsulation rate, and low mechanical strength of capsule wall, etc., and achieves good results. , The effect of simplifying the finishing process
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[0024] A preparation method of a modified melamine resin essence microcapsule finishing agent, comprising the steps of:
[0025] (1) Preparation of styrene-maleic anhydride copolymer powder
[0026] Dissolve 5.4g of azobisisobutyronitrile in 60.0kg of 3-hexanone to form reaction solution A; 25.8kg of maleic anhydride and 82.3kg of styrene are mixed and dissolved to form reaction solution B;
[0027] The reaction medium in the reaction kettle is 103.5kg of 3-hexanone, the temperature of the reaction medium in the reaction kettle is controlled at 70°C by an oil bath, and the reaction solution A and the reaction solution B are respectively fed into the reaction continuously at a low price through different pipelines. Reactor, after the low price, react for 2 hours to end the reaction, increase the temperature, and distill 3-hexanone under reduced pressure, discharge the material from the reactor after melting, obtain a solid after cooling, and grind it into powder;
[0028] (2) ...
Embodiment 1
[0038] (1) Preparation of styrene-maleic anhydride copolymer powder
[0039] Dissolve 5.4g of azobisisobutyronitrile in 60.0kg of 3-hexanone to form reaction solution A; 25.8kg of maleic anhydride and 82.3kg of styrene are mixed and dissolved to form reaction solution B;
[0040]The reaction medium in the reaction kettle is 103.5kg of 3-hexanone, the temperature of the reaction medium in the reaction kettle is controlled at 70°C by an oil bath, and the reaction solution A and the reaction solution B are respectively fed into the reaction continuously at a low price through different pipelines. Reactor, after the low price, react for 2 hours to end the reaction, increase the temperature, and distill 3-hexanone under reduced pressure, discharge the material from the reactor after melting, obtain a solid after cooling, and grind it into powder;
[0041] (2) Preparation of styrene-maleic anhydride copolymer solution
[0042] Add 1 part of styrene-maleic anhydride copolymer powder...
Embodiment 2
[0051] (1) Preparation of styrene-maleic anhydride copolymer powder
[0052] The solution medium added to the reactor is 300kg of toluene, an oil bath, and the temperature is 90°C. The molar ratio of MAH and St is 1:1, wherein 38.812kg of maleic anhydride, 41.188kg of styrene, and 4kg of azobisisobutyronitrile (AIBN) as the initiator are dissolved and mixed with solvent trimethylbenzene 120kg and butanone 39kg to obtain a mixed solution . The mixed solution was added dropwise into the reactor for 4 hours, and the reaction was continued for 1 hour after the dropwise addition. Filtrate and dry to obtain styrene-maleic anhydride copolymer powder with a weight average molecular weight of 6635kg / mol.
[0053] (2) Preparation of styrene-maleic anhydride copolymer solution
[0054] Add 3 parts of styrene-maleic anhydride copolymer powder and 17 parts of deionized water into the four-necked bottle by weight, heat up to 85°C under stirring conditions, and adjust the pH to 10,5 with ...
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