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Composite wave-absorbing porous polyurethane material and preparation method thereof

A porous material, polyurethane technology, applied in chemical instruments and methods, other chemical processes, etc., can solve the problems of complicated manufacturing process and large size, and achieve the effect of simple preparation process, stable electrical performance and good conductivity

Inactive Publication Date: 2018-03-30
HENAN HAINADE NEW MATERIAL CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the material has defects such as large size and complicated manufacturing process.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0019] The embodiment of the present invention provides a polyurethane composite wave-absorbing porous material, which is obtained by polymerization of the following components by mass: 100 parts of polyether polyol, 30 parts of toluene diisocyanate, 0.05 parts of nano carbon sol, and nano white carbon black 0.2 parts, 10 parts of deionized water, 5 parts of dimethyl methyl phosphate, 2 parts of graphene oxide, 10 parts of ferrite, 1 part of zirconia, 2 parts of zinc borate, 0.02 parts of stannous octoate, triethylenediamine 0.03 parts, 0.2 parts of silicone surfactant, 2 parts of sodium bicarbonate.

[0020] The embodiment of the present invention also provides a preparation method of the above-mentioned polyurethane composite wave-absorbing porous material, which includes the following steps:

[0021] Mixing of raw materials: the above mass parts, polyether polyol, dimethyl methyl phosphate, nano-carbon sol, nano-silica, ferrite, zirconia, zinc borate, stannous octoate, trie...

Embodiment 2

[0028] The embodiment of the present invention provides a polyurethane composite wave-absorbing porous material obtained by polymerization of the following components by mass: 100 parts of polyether polyol, 40 parts of toluene diisocyanate, 0.15 parts of nano-carbon sol, and 0.3 parts of nano-silica , 13 parts of deionized water, 10 parts of dimethyl methyl phosphate, 4 parts of graphene oxide, 13 parts of ferrite, 2 parts of zirconia, 4 parts of zinc borate, 0.08 parts of stannous octoate, 0.12 parts of triethylenediamine , 1 part of silicone surfactant, 4 parts of sodium bicarbonate.

[0029] The embodiment of the present invention also provides a preparation method of the above-mentioned polyurethane composite wave-absorbing porous material, which is basically the same as the preparation method provided in Example 1, except that:

[0030] Reactive foaming: the room temperature foaming time in this step is 60 minutes;

[0031] Freeze-drying: This step includes first freezin...

Embodiment 3

[0035] The embodiment of the present invention provides a polyurethane composite wave-absorbing porous material, which is obtained by polymerization of the following components by mass: 100 parts of polyether polyol, 45 parts of toluene diisocyanate, 0.2 parts of nano-carbon sol, and nano-silica 0.35 parts, 15 parts of deionized water, 13 parts of dimethyl methyl phosphate, 5 parts of graphene oxide, 15 parts of ferrite, 3 parts of zirconia, 5 parts of zinc borate, 0.2 parts of stannous octoate, triethylenediamine 0.3 parts, 1.6 parts of silicone surfactant, 5 parts of sodium bicarbonate.

[0036]The embodiment of the present invention also provides a preparation method of the above-mentioned polyurethane composite wave-absorbing porous material, which is basically the same as the preparation method provided in Example 1, except that:

[0037] Reactive foaming: the room temperature foaming time in this step is 60 minutes;

[0038] Freeze-drying: This step includes first freez...

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Abstract

The invention provides a composite wave-absorbing porous polyurethane material. The composite wave-absorbing porous polyurethane material is obtained through a polymerization reaction of the followingcomponents, by mass, 100 parts of polyether polyol, 30-60 parts of toluene diisocyanate, 0.05-0.4 part of nano-carbon sol, 0.2-0.5 part of nanometer white carbon black, 10-20 parts of deionized water, 5-20 parts of dimethyl methylphosphate, 2-8 parts of graphene oxide, 10-20 parts of ferrite, 2-10 parts of zirconium oxide, 2-8 parts of zinc borate, 0.02-0.4 part of stannous octoate, 0.03-0.6 partof triethylenediamine, 0.2-3 parts of an organosilicone surfactant and 2-8 parts of sodium bicarbonate. The composite wave-absorbing porous polyurethane material has the characteristics of low smoke,low toxicity, flame retardancy, and wide absorption frequency distribution of absorbed waves. The invention also provides a preparation method of the composite wave-absorbing porous polyurethane material.

Description

technical field [0001] The invention belongs to the technical field of functional materials, and in particular relates to a polyurethane composite wave-absorbing porous material and a preparation method thereof. Background technique [0002] Absorbing materials refer to materials that can absorb most of the electromagnetic waves projected on its surface and convert them into other forms of energy with almost no reflection. With the development of modern science and technology, the impact of electromagnetic radiation on the environment is increasing. At the airport, flights are delayed due to electromagnetic wave interference; in hospitals, mobile phones often interfere with the normal work of various electronic medical instruments. In addition, electromagnetic radiation causes direct and indirect damage to the human body through thermal effects, non-thermal effects, and cumulative effects. Therefore, controlling electromagnetic pollution and finding a material that can res...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08G18/48C08K13/02C08K3/36C08K3/04C08K3/38C08K5/5333C08J9/08C09K3/00C08G101/00
CPCC08G18/48C08G2101/00C08J9/08C08J2203/02C08J2375/08C08K3/04C08K3/36C08K3/38C08K5/5333C08K13/02C08K2003/387C08K2201/001C08K2201/011C08L2201/02C09K3/00
Inventor 程相林张梅梅温毓敏
Owner HENAN HAINADE NEW MATERIAL CO LTD
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