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Core-shell structure Si/C material, preparation method and application

A core-shell structure, suspension technology, applied in structural parts, electrical components, battery electrodes, etc., can solve the problems of long synthesis process, complex preparation method, difficult material performance, etc., achieve excellent electrochemical performance, simplify Preparation process, the effect of promoting decomposition

Active Publication Date: 2017-10-13
HUAZHONG UNIV OF SCI & TECH
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  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0004] According to the above research, the core-shell structure Si / C composite has excellent electrochemical performance. However, when preparing the core-shell structure Si / C composite, the decomposition of the polymer to form a carbon layer requires a special polymer coating method. Compared with the general use of acetylene gas to wrap carbon, the use of acetylene to wrap carbon to prepare Si / C composites with a core-shell structure has the following problems: (1) A high concentration of acetylene gas is required during the preparation process, so the preparation method is very complicated and unsafe , (2) low concentration C 2 h 2 It is difficult for gas to deposit directly on the Si surface, therefore, C 2 h 2 When the gas is low, the performance of the prepared material is difficult to meet the needs of use (3) The preparation method has a long synthesis process and requires a professional CVD device, which increases the cost and difficulty of preparation

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  • Core-shell structure Si/C material, preparation method and application
  • Core-shell structure Si/C material, preparation method and application
  • Core-shell structure Si/C material, preparation method and application

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preparation example Construction

[0038] figure 1 It is a schematic diagram of the Si / C material preparation method of the core-shell structure Si / C material of the present invention. As shown in the figure, the preparation method of the core-shell structure Si / C material of the present invention specifically includes the following steps:

[0039] (1) Prepared Fe(NO 3 ) 3 Dissolved in deionized water to obtain Fe(NO 3 ) 3 solution, and take Si powder for use, wherein the Si powder is nano Si powder or micron Si powder, and the mass ratio range of Fe and Si is 5:1~1:1;

[0040] (2) Put the weighed Si powder into Fe(NO 3 ) 3 solution, and add a dispersant, and ultrasonically stir the Si powder to disperse evenly to form a suspension. The dispersant includes a non-polar liquid, preferably absolute ethanol;

[0041] (3) Pour the suspension obtained in step (2) into a low-temperature resistant container, and pour clean liquid nitrogen into the suspension to freeze to form ice-state Si / Fe(NO 3 ) 3 , preferab...

Embodiment 1

[0052] Take by weighing the nano-Si powder of 100mg for subsequent use, take by weighing an appropriate amount of Fe(NO 3 ) 3Dissolve in 20mL deionized water; put the weighed nano-Si powder into Fe(NO 3 ) 3 solution, and Fe:Si=3:1 (mass ratio), add 3mL of absolute ethanol to help the dispersion of nano-Si powder, ultrasonically stir and disperse evenly to form a suspension; pour the above suspension into a plastic container, pour Clean liquid nitrogen is frozen to form ice Si / Fe(NO 3 ) 3 ; the above ice Si / Fe (NO 3 ) 3 Put it into the pre-cooled freeze dryer for freeze-drying, turn on the vacuum pump, the temperature of the cold well of the freeze dryer is -70°C, the vacuum degree is 1Pa, and the freeze-drying time is 48h; take out the above-mentioned freeze-dried samples and put them into a tube furnace, N 2 Warm up to 400°C under atmosphere, N 2 Change the atmosphere to C 2 h 2 Change back to N after the atmosphere is kept warm for 40 minutes 2 , cooled to room te...

Embodiment 2

[0054] Take by weighing the nano-Si powder of 100mg for subsequent use, take by weighing an appropriate amount of Fe(NO 3 ) 3 Dissolve in 20mL deionized water; put the weighed nano-Si powder into Fe(NO 3 ) 3 solution, and Fe:Si=3:1 (mass ratio), add 3mL of absolute ethanol to help the dispersion of nano-Si powder, ultrasonically stir and disperse evenly to form a suspension; pour the above suspension into a plastic container, pour Clean liquid nitrogen is frozen to form ice Si / Fe(NO 3 ) 3 ; the above ice Si / Fe (NO 3 ) 3 Put it into the pre-cooled freeze dryer for freeze-drying, turn on the vacuum pump, the temperature of the cold well of the freeze dryer is -70°C, the vacuum degree is 1Pa, and the freeze-drying time is 48h; take out the above-mentioned freeze-dried samples and put them into a tube furnace, N 2 Warm up to 500°C under atmosphere, N 2 Change the atmosphere to C 2 h 2 Change back to N after the atmosphere is kept warm for 40 minutes 2 , cooled to room t...

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Abstract

The invention belongs to the field of lithium ion batteries and particularly relates to a preparation method of a core-shell structure Si / C material. The method comprises the following steps of (1) preparing Fe(NO3)3 solution; (2) uniformly stirring Si powder in the solution to form turbid liquid; (3) dropping liquid nitrogen into the turbid liquid to form icy Si / Fe(NO3)3; (4) carrying out vacuum freeze drying to obtain an Si / Fe(NO3)3 sample; (5) carrying out high-temperature carbon coating on the Si / Fe(NO3)3 sample to obtain Si / C powder including Fe3O4; and (6) carrying out acid pickling and drying to obtain the core-shell structure Si / C material. The invention also discloses the core-shell structure Si / C material and application thereof. The core-shell structure Si / C material prepared by the method of the invention has excellent electrochemical performance, no high-concentration acetylene and professional CVD device and higher operability and safety.

Description

technical field [0001] The invention belongs to the field of lithium-ion batteries, and more specifically relates to a core-shell structure Si / C material and its preparation method and application. The core-shell structure Si / C material is especially suitable for lithium-ion batteries Negative material. Background technique [0002] As early as the emergence of Si-based negative electrode materials, Si / C composite materials were considered the most potential Si-based materials. Carbon materials have good electrical conductivity and cycle stability. Carbon in Si / C materials can improve the performance of Si-based materials. The role of conductivity, stabilizing the SEI film and buffering the volume effect. [0003] The earliest preparation of Si / C composite materials is mainly the composite of simple Si and carbon source. Kumta and Kim et al. used polystyrene (PS) as C source, Si powder as Si source, and prepared Si / C composite by high-energy ball milling in an inert atmosph...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01M4/36H01M4/38H01M4/62H01M10/0525
CPCH01M4/366H01M4/386H01M4/62H01M4/625H01M4/628H01M10/0525Y02E60/10
Inventor 胡先罗赵前进
Owner HUAZHONG UNIV OF SCI & TECH
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