Isoindigo conjugated polymer, semiconductor CNT ink, and preparation method and application of polymer

A conjugated polymer, isoindigo technology, applied in semiconductor/solid-state device manufacturing, semiconductor devices, applications, etc., to achieve the effects of convenient use, high purity and low cost

Active Publication Date: 2017-09-12
SUZHOU INST OF NANO TECH & NANO BIONICS CHINESE ACEDEMY OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

There has not been any report on the selective separation of carbon nanotubes by isoindigo polymers to obtain semiconducting carbon nanotube inks

Method used

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  • Isoindigo conjugated polymer, semiconductor CNT ink, and preparation method and application of polymer
  • Isoindigo conjugated polymer, semiconductor CNT ink, and preparation method and application of polymer
  • Isoindigo conjugated polymer, semiconductor CNT ink, and preparation method and application of polymer

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preparation example Construction

[0056] In some embodiments, the preparation method of the isoindigo conjugated polymer may include: selecting a compound having the structure shown in formula ① to carry out a polymerization reaction with a compound containing an Ar group, so as to obtain the isoindigo conjugated polymer conjugated polymers,

[0057]

[0058] The compound containing the Ar group has at least any one of the following structures:

[0059]

[0060] where M includes –SnMe 3 or –B (OR) 2 , R 1 At least be selected from straight chain or branched chain alkyl or heteroalkyl with carbon number of 1~20, R is at least selected from hydrogen atom or C 1 -C 20 straight-chain or branched-chain alkyl groups.

[0061] Further, the polymerization reaction is a polycondensation reaction catalyzed by a transition metal, for example, it may preferably be selected from metal-catalyzed Suzuki polymerization or metal-catalyzed Stille polymerization.

[0062] In some more preferred embodiments, the prepa...

Embodiment 1- Embodiment 4

[0089] One, embodiment 1-embodiment 4 relates to the synthesis of multiple typical isoindigo conjugated polymers

Embodiment 1

[0090] Example 1: Preparation of poly[N,N'-bis(2-octyldodecyl)-isoindigo-co-(9,9-dioctylfluorenyl-2,7-diyl)]:

[0091] The structural formula of the poly[N,N'-di(2-octyldodecyl)-isoindigo-co-(9,9-dioctylfluorenyl-2,7-diyl)] is as follows:

[0092]

[0093] Its synthesis process route is:

[0094]

[0095] Under the condition of nitrogen protection, 0.1mmoL 9,9-dioctylfluorenyl-2,7-diboronate, 0.1mmoL N,N′-di(2-octyldodecyl)-6,6 Add ′-dibromoisoindigo, 0.005mmoL tetrakis(triphenylphosphine)palladium, 0.01mmoL tetrabutylammonium bromide and 0.5mmoL potassium carbonate to a 10mL Schlenk tube, then add 5m1 toluene and 0.5mL water, and heat to 100 React at ℃ for 72 hours to obtain a polymer, settle the polymer in methanol, filter, and then sequentially extract with methanol and n-hexane in a Soxhlet extractor. In order to obtain a product with higher purity, the n-hexane extract can be concentrated again Settled in methanol, filtered and dried under vacuum to give a brown s...

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Abstract

The invention discloses an isoindigo conjugated polymer, a semiconductor CNT ink, and a preparation method and an application of the polymer. The isoindigo conjugated polymer comprises a composition unit represented by a formula shown in the description; and in the formula, R1 comprises any one of a heteroalkyl group, and a C1-20 linear or branched alkyl group, R2 comprises any one of a hydrogen atom, a heteroalkyl group, a halogen atom, a C1-20 linear or branched alkyl group, Ar comprises a conjugate unit composed of any one or two or more of one to four five- or six-membered aromatic ring, five- or six-membered aromatic heterocyclic group and a polybasic aromatic fused ring, and n is any integer in a range of 2-500. The isoindigo conjugated polymer can specifically bind to semiconductor carbon nanotubes, so the isoindigo conjugated polymer can be used in the highly selective separation of the semiconductor carbon nanotubes in commercial carbon nanotubes; and the isoindigo conjugated polymer can form the semiconductor carbon nanotube (CNT) ink having high purity, and the ink can be used for constructing a semiconductor device having superior performances.

Description

technical field [0001] The invention belongs to the field of printed nanoelectronics, and in particular relates to an isoindigo conjugated polymer, a carbon nanotube selective separation method based on the isoindigo conjugated polymer, a semiconductor CNT ink, a semiconductor device and a preparation method thereof. Background technique [0002] Due to its simple printing process and non-selectivity to substrate materials, printed electronic devices have incomparable advantages in the application of large-area, flexible, and low-cost electronic devices, and are becoming an emerging technology. Therefore, the development of printed electronics technology has attracted widespread attention from people all over the world, and has become a multidisciplinary and comprehensive cutting-edge research hotspot. In order to build printed electronic components and develop their related applications, the development of high-performance new printed electronic ink has become one of the mo...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08G61/12C01B32/17B82Y30/00H01L51/00H01L51/05C09D11/102C09D11/03
CPCC09D11/03C09D11/102B82Y30/00C08G61/124C08G61/126C01P2004/13C01P2004/64C08G2261/1414C08G2261/414C08G2261/334C08G2261/344C08G2261/92H10K71/13H10K85/221H10K10/46
Inventor 周春山赵建文崔铮
Owner SUZHOU INST OF NANO TECH & NANO BIONICS CHINESE ACEDEMY OF SCI
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