A kind of metal rolling oil containing modified graphene oxide and preparation method thereof

A technology of metal rolling oil and oxide stone, which is applied in the petroleum industry, additives, lubricating compositions, etc., can solve the problems of difficult dispersion, weak interaction, strong intermolecular force, etc., achieve glossy surface reflectivity, and ensure cleanliness performance, high reflectivity

Active Publication Date: 2020-02-04
QUAKER CHEM CHINA
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Problems solved by technology

Graphene has good high temperature resistance and friction resistance, and has been applied in the fields of sheet sliding, friction and wear mechanism, and tribology, and there are many researches and reports; but the chemical properties of graphene are stable, and the interaction with other media is weak. There are strong intermolecular forces, making it difficult to disperse in many solvents

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  • A kind of metal rolling oil containing modified graphene oxide and preparation method thereof
  • A kind of metal rolling oil containing modified graphene oxide and preparation method thereof

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preparation example Construction

[0028] The preparation method of modified graphene oxide is: first by chemical oxidation, the graphene surface has oxygen-containing polar groups with high reactivity such as hydroxyl, carboxyl and epoxy groups, to obtain unmodified graphene oxide. Then, through the reaction of organic substances with C12-C22 alkyl groups and oxygen-containing polar groups, C12-C22 alkyl groups are grafted on the surface of unmodified graphene oxide, thereby introducing C12-C22 on the surface of graphene oxide. The grafting of alkyl groups yields modified graphene oxide. Compared with unmodified graphene oxide, modified graphene oxide has oil solubility and better dispersion in base oil, and can undergo coordination reaction with phosphorus-containing additives in base oil to form coordination compounds. Commonly used organic compounds with C12-C22 alkyl groups include oleic acid, castor oil, lauric acid, etc.

[0029] A metal rolling oil containing modified graphene oxide of the present inve...

Embodiment 1

[0045] Base oil: 51.0 parts by weight of trimethylolpropane oleate and 38.3 parts by weight of natural palm oil;

[0046] Antioxidant: 1.5 parts by weight of 2,6-di-tert-butyl-a-dimethylamino-p-cresol;

[0047] Rust inhibitor: 1.5 parts by weight of benzotriazole:

[0048] Sulfur-containing additive: 2.5 parts by weight of dialkyl polysulfide;

[0049] Auxiliary agent: 0.8 parts by weight of polyethylene glycol with a molecular weight of 1000;

[0050] Emulsifier: 0.9 parts by weight of C16-C18 fatty alcohol polyoxyethylene ether and 0.5 parts by weight of polyoxypropylene oxide glycerol ether;

[0051] Phosphorus-containing additives: 0.5 parts by weight of alkylamine phosphate and 0.5 parts by weight of oleyl alcohol polyoxyethylene phosphate;

[0052] Modified graphene oxide 2.0 parts by weight;

[0053] The weight ratio of the phosphorus-containing additive to the modified graphene oxide is 1:2. Modified graphene oxide surface grafted with castor oil.

Embodiment 2

[0055] Base oil: 45.0 parts by weight of tetraester of pentaerythritol coconut oil / oleic acid and 42.0 parts by weight of defatted lard;

[0056] Antioxidant: 0.8 parts by weight of dioctyl diphenylamine;

[0057] Rust inhibitor: 1.2 parts by weight of tolutriazole;

[0058] Sulfur-containing additive: 2.0 parts by weight of dodecyl polysulfur additive;

[0059] Phosphorus-containing additives: 1.5 parts by weight of alkylamine phosphate and 1.5 parts by weight of fatty alcohol polyoxyethylene phosphate;

[0060] Auxiliary agent: 0.9 parts by weight of hexanediol;

[0061] Emulsifier: α-hydrogen-ω-hydroxyl-polyoxyethylene, 1.3 parts by weight of D-sugar alcohol ether and 0.8 parts by weight of polyoxypropylene oxide ethylene glyceryl ether;

[0062] Modified graphene oxide 3.0 parts by weight.

[0063] The weight ratio of the phosphorus-containing additive to the modified graphene oxide is 1:1. Modified graphene oxide surface grafted with oleic acid.

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Abstract

The invention discloses metal rolling oil containing modified graphene oxide in the field of steel rolling. The metal rolling oil is prepared from the following components in parts by weight: 85 to 90 parts of base oil, 1 to 5 parts of a phosphorus-containing additive, 2 to 4 parts of an emulsifying agent, and 1 to 5 parts of the modified graphene oxide, wherein the surface of the modified graphene oxide is grafted with C12-C22 alkyl, and the modified graphene oxide and the phosphorus-containing additive generate a coordination compound in the base oil. The technical effects are as follows. The lubricating performance of the metal rolling oil is strong, flat steel rolled under high-speed and high-pressure high rolling force and multi-rolling reduction has a glossy surface and high reflectance, the anti-rusting performance of the surface of the flat steel is ensured, and the cleaning performance of a rolling machine can also be ensured. The invention also provides a preparation method of the metal rolling oil containing the modified graphene oxide.

Description

technical field [0001] The invention relates to a metal rolling oil containing modified graphene oxide and a preparation method thereof in the field of steel rolling. Background technique [0002] With the increasing demand for high-strength sheet steel (HSS) and ultra-high-strength sheet steel (UHSS) for automobile sheets and home appliance sheets, the requirements for rolling oil used in rolling are also getting higher and higher. In the case of high pressure, high speed, high rolling force and multiple reductions, the traditional lubricating oil can no longer meet the requirements for lubrication in the rolling process and the surface quality of strip steel. [0003] When rolling at high speed, high pressure, high rolling force and multiple reductions, a large amount of frictional heat is generated between the work rolls and the rolled plate and strip steel. Due to the accumulation of frictional heat on the surface of the work rolls, the surface temperature of the work ro...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C10M125/02C10M169/04C10M177/00C10N30/04C10N30/06C10N30/12C10N40/24
CPCC10M125/02C10M169/044C10M177/00C10M2201/041C10M2201/085C10M2201/14C10M2207/022C10M2207/046C10M2207/2835C10M2207/289C10M2207/401C10M2209/104C10M2209/105C10M2209/108C10M2215/04C10M2215/062C10M2215/064C10M2215/223C10M2219/082C10M2225/04C10N2030/04C10N2030/06C10N2030/12C10N2040/24
Inventor 王毅杰
Owner QUAKER CHEM CHINA
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