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Natural polymer for filtrate loss reducer for drilling fluid and preparation method thereof

A technology of natural polymer and fluid loss control agent, which is applied in the field of fluid loss control agent for drilling fluid and petroleum drilling aids, which can solve problems such as unspecified guidance plan, land environmental pollution, strong alkalinity, etc., and achieve reduction in drilling Complicated accidents, reduced fluid loss, and good performance

Inactive Publication Date: 2017-07-11
石家庄华莱鼎盛科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The above technology uses strong alkali (NaOH), which is highly alkaline and easy to cause environmental pollution to the land
The above technologies have not given specific guidance on how to use fluid loss reducers for drilling fluids to fully reduce the fluid loss of drilling fluids, avoid complex drilling accidents, improve drilling quality and efficiency, and have environmental protection functions.

Method used

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  • Natural polymer for filtrate loss reducer for drilling fluid and preparation method thereof
  • Natural polymer for filtrate loss reducer for drilling fluid and preparation method thereof
  • Natural polymer for filtrate loss reducer for drilling fluid and preparation method thereof

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Embodiment 1

[0033] Embodiment 1: the fluid loss reducer natural high molecular polymer for drilling fluid of the present invention is to be made from the raw material of following weight ratio (weight part, mass part):

[0034]

[0035] The oxygen scavenger is sodium sulfite, and the initiator is sodium persulfate.

[0036] The preparation method of described fluid loss reducer natural polymer for drilling fluid comprises the following processing steps: 1. starch hydrolysis: in reactor, 10 parts of starch (corn starch) are dissolved in 72 parts of water, and the dissolution temperature is controlled Prepare starch solution at 35°C; ②Acidification of starch solution: Dissolve 5 parts of AMPS and 13 parts of AM in the starch solution prepared in step ①, control the dissolution temperature at 35°C, and adjust the pH of the solution to 4 with NaOH , to obtain starch acid solution; ③ deoxygenation of starch acid solution: raise the temperature of the starch acid solution to 62 ° C, add 0.5 ...

Embodiment 2

[0037] Embodiment 2: the fluid loss reducer for drilling fluid of the present invention is made from the raw materials of the following weight ratio (parts by weight, parts by mass):

[0038]

[0039] The oxygen scavenger is magnesium oxide, and the initiator is sodium persulfate.

[0040] The preparation method of described fluid loss reducer natural polymer for drilling fluid comprises the following process steps: 1. starch hydrolysis: in reactor, 12 parts of starch (potato starch) are dissolved in 76 parts of water, and the dissolution temperature is controlled Prepare starch solution at 45°C; ②Acidification of starch solution: Dissolve 5 parts of AMPS and 12 parts of AM in the starch solution prepared in step ①, control the dissolution temperature at 46°C, and adjust the pH of the solution to 5 with NaOH , to obtain the starch acid solution; ③ deoxygenation of the starch acid solution: the temperature of the starch acid solution was raised to 68 ° C, and 0.9 parts of ox...

Embodiment 3

[0041] Embodiment 3: the fluid loss control agent for drilling fluid of the present invention The natural polymer is made of the raw materials of the following weight ratio (parts by weight, parts by mass):

[0042]

[0043] The oxygen scavenger is sodium sulfite, and the initiator is potassium persulfate.

[0044] The preparation method of described fluid loss reducer natural polymer for drilling fluid comprises the following process steps: 1. Starch hydrolysis: dissolve 10 parts of starch (wheat starch) in 70 parts of water in a reactor, and the dissolution temperature is controlled Prepare starch solution at 50°C; ②Acidification of starch solution: Dissolve 6 parts of AMPS and 14 parts of AM in the starch solution prepared in step ①, control the dissolution temperature at 48°C, and adjust the pH of the solution to 6 with NaOH , to obtain starch acid solution; ③ deoxygenation of starch acid solution: raise the temperature of the starch acid solution to 70 ° C, add 0.7 par...

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Abstract

A natural polymer for a filtrate loss reducer for a drilling fluid and a preparation method thereof are disclosed, the natural polymer is prepared from the following raw materials by weight: 5-15 parts of starch, 2-6 parts of AMPS, 10-15 parts of AM, 0.1-1 part of an initiator, 60-80 parts of water and 0.1-1 part of a deoxidizer. The preparation method comprises the following steps: starch hydrolysis, acidification of a starch solution, deoxidization of a starch acid solution and graft copolymerization of the starch acid solution. The performance of the natural polymer is as follows: 4% saline API filtration loss is equal to or less than 8.0mL, after aging at 150 DEG C, the API filtration loss is equal to or less than 14.0mL, saturated brine API filtration loss is equal to or less than 8.0mL, after aging at 150 DEG C, API filtration loss is equal to or less than 13.0mL, compound brine API filter loss is equal to or less than 13.0mL, after aging at 150 DEG C, API filtration loss is equal to or less than 18.0mL. The natural polymer has good performance, can reduce the filtrate loss of the drilling fluid, avoids or reduces the occurrence of complex drilling accidents, improves drilling quality and efficiency, and produces a good environmental protection effect.

Description

technical field [0001] The invention relates to a fluid loss reducer for drilling fluid, which belongs to petroleum drilling aids, in particular to a natural high molecular weight fluid loss reducer for drilling fluid. The invention also relates to a preparation method of the natural high molecular polymer of the fluid loss control agent for drilling fluid. Background technique [0002] Drilling fluid is an important fluid in drilling engineering, and its performance is directly related to the quality of drilling, and plays a crucial role in the oil recovery efficiency of an oil field. There are various types of fluid loss control agents currently on the market, but they often cannot be both efficient and environmentally friendly. Among the commonly used fluid loss additives for drilling fluids, only starch and modified starch fluid loss additives can meet the requirements of environmental protection, but their performance has certain deficiencies, making it difficult to ef...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08F251/00C08F220/56C08F220/58C09K8/035
CPCC08F251/00C09K8/035C08F220/585
Inventor 陈利赵秀平
Owner 石家庄华莱鼎盛科技有限公司
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