Expanding material composition, self-suspension propping agent, method for preparing same and application of self-suspension propping agent
A technology of expansive materials and compositions, which is applied in drilling compositions, chemical instruments and methods, and earthwork drilling and production, and can solve problems such as difficulty in fracturing fluid transportation, formation pollution, and blockage of oil outlet pores, so as to reduce viscosity , reduce pollution, avoid the effects of organic solvents
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[0030] The present invention also provides the preparation method of above-mentioned self-suspending proppant, and this method comprises the following steps:
[0031] (1) Disperse and mix the proppant body, binder and curing agent uniformly at the first temperature to obtain granular aggregate with binder and / or curing agent attached, wherein, relative to 100 parts by weight of proppant agent body, the amount of the binder is 1-30 parts by weight, and the amount of the curing agent is 0.1-2 parts by weight;
[0032] (2) Dispersing and mixing the granular aggregate and the expansive material composition at a second temperature so that the expansive material composition is coated on the granular aggregate to obtain a granular self-suspending proppant , wherein, relative to 100 parts by weight of the proppant body, the amount of the expansion material composition is 5-40 parts by weight.
[0033] The preparation method of the self-suspending proppant of the present invention can...
Embodiment 1
[0040] This example is used to illustrate the expansion material composition of the present invention and the preparation method and self-suspension proppant prepared from the expansion material composition.
[0041] The expansion material composition of this embodiment is 100 parts by weight of polyacrylamide (purchased from Ciba, Switzerland, with a weight average molecular weight of 22 million) and 1 part by weight of epoxy resin E44 (purchased from Nantong Xingchen Synthetic Materials Co., Ltd.).
[0042] (1) Using quartz sand (6-10 mesh in particle size) as raw material, after scrubbing and drying at 120°C for 5 hours, screen 6-40 mesh quartz sand as aggregate;
[0043] (2) Take 100 parts by weight of screened quartz sand, heat it to 240°C, add 1 part by weight of epoxy resin E-51 (618), 0.1 part by weight of curing agent phthalic anhydride, stir and mix evenly to obtain a binder package Covered granular aggregate;
[0044] (3) When the temperature of the above-mentioned...
Embodiment 2
[0047] This example is used to illustrate the expansion material composition of the present invention and the preparation method and self-suspension proppant prepared from the expansion material composition.
[0048] The expansion material composition of this embodiment is 100 parts by weight of polyacrylic acid (purchased from Changzhou Runyang Chemical Co., Ltd., GY-303, with a weight average molecular weight of 20000) and 12 parts by weight of epoxy resin E14 (purchased from Nantong Xingchen Synthetic Materials Co., Ltd. Ltd.).
[0049] (1) Take 100 parts by weight of ceramsite (particle size is 100-200 mesh), heat to 190 ° C, add 30 parts by weight of binder bisphenol A type unsaturated polyester 3301, add curing agent phthalic anhydride 2 parts by weight, stirred and mixed evenly to obtain binder-coated granular aggregate;
[0050] (2) When the temperature of the above-mentioned binder-coated granular aggregate drops to 70° C., add 40 parts by weight of the above-mention...
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