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Fluorinated polyurethane and preparation method thereof

A technology of polyurethane and fluorine-containing alkyl polyether, applied in the field of polyurethane, can solve problems such as insufficient weather resistance and water resistance, reduce the mechanical properties of polyurethane products, and fail to reach modified polyurethane, etc. Cured, easy to store effect

Active Publication Date: 2017-05-17
UPCHEM CHINA
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the traditional polyurethane materials have insufficient weather resistance and water resistance. Since these polyurethanes use diisocyanates containing aromatic ring structures as the reactant, the products often turn yellow and produce macromolecules when they are exposed to ultraviolet light for a long time outdoors. degradation
When fluorine-containing polyurethane is prepared by addition and chain extension of small-molecule fluorine-containing diols and diisocyanates, the weather resistance of the product can be improved, but the use of small-molecule diols reduces the mechanical properties of polyurethane products, reduces the The amount of alcohol can not achieve the purpose of modifying polyurethane

Method used

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  • Fluorinated polyurethane and preparation method thereof
  • Fluorinated polyurethane and preparation method thereof
  • Fluorinated polyurethane and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0038] (1) Synthesis of nonafluorooxetane monomer

[0039] In a 1000mL three-necked flask equipped with a thermometer, ice-water bath and magnetic stirrer protection, add 16.1g allyl butyl acetate, 26.2g sodium bicarbonate, 55.8g sodium dithionite, 227g N,N-dimethylformamide, 202g of water was added dropwise with 55.3g of perfluorobutyl iodide, reacted at -13°C for 3h, slowly raised to room temperature, and incubated for 2h. After the completion of the reaction, extraction was performed three times with 180 g of toluene. The extracts were combined and washed 3 times to obtain a 4-nonafluorobutyl-3-iodobutyl acetate solution, which was added to a 1000mL three-necked flask, and 310g of sodium hydroxide solution with a mass concentration of 20% was added dropwise, and the solution was kept at 12°C for 3h. After the reaction was completed, the layers were separated. The organic layer was washed three times with water, dried and distilled under reduced pressure to obtain 32.6 g ...

Embodiment 2

[0047] (1) Synthesis of nonafluorooxetane monomer

[0048] In a 1000mL three-necked flask equipped with a thermometer, ice-water bath and magnetic stirrer protection, add 16.5g of butyl acetate, 26.4g of sodium bicarbonate, 53.6g of sodium dithionite, 230g of N,N-dimethylformamide, 210g of water was added dropwise with 55.5g of perfluorobutyl iodide, reacted at -15°C for 3h, slowly raised to room temperature, and kept for 2h. After the reaction was completed, extraction was performed three times with 180 g of toluene. The extracts were combined, washed 3 times with water to obtain a solution of 4-nonafluorobutyl-3-iodobutyl acetate, which was added to a 1000mL three-necked flask, and 310g of sodium hydroxide solution with a mass concentration of 20% was added dropwise and kept at React at 11°C for 3h. After the reaction, the layers were separated. The organic layer was washed three times with water, dried and distilled under reduced pressure to obtain 34.2 g of 3-(1H,1H-non...

Embodiment 3

[0056] (1) Synthesis of tridecafluorooxetane monomer

[0057] In a 1000mL three-necked flask equipped with a thermometer, ice-water bath and magnetic stirrer protection, add 16.5g of butyl acetate, 28.2g of sodium bicarbonate, 55.5g of sodium dithionite, 221g of N,N-dimethylformamide, 230g of water, 73.0g of perfluorohexyl iodide was added dropwise, and the addition was completed in 50 minutes. After the addition, it was reacted at -12°C for 6 hours, slowly raised to room temperature, and kept for 3 hours. After the reaction was finished, extract with 180g trifluorotoluene in 3 times. The extracts were combined and washed 3 times to obtain a 4-tridecafluorohexyl-3-iodobutyl acetate solution. The solution was directly added to a 1000mL three-necked flask, and 550g of mass concentration was added dropwise to a 10% sodium hydroxide solution. Insulate and react at 13°C for 8h. After the reaction, the layers were separated. The organic layer was washed three times with water, dr...

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Abstract

The invention discloses fluorinated polyurethane and a preparation method thereof. The fluorinated polyurethane is prepared through the steps: fluoroalkyl-containing polyether glycol and diisocyanate perform addition polymerization reaction, a tin catalyst is utilized to catalyze, a chain extender is utilized to extend a chain, and an amino silane coupling agent is added to seal ends. A product contains a fluorine-containing polyether block, the fluorine content is high, fluoroalkyl on a polyether lateral group is prone to generating microphase separation and surface migration, polyurethane surface energy is low, and the fluorinated polyurethane is easy to store and cure as the silane coupling agent is utilized to seal the ends. A water contact angle of a coating prepared from the fluorinated polyurethane is higher than 110 degrees, and the coating has excellent water repellency.

Description

technical field [0001] The invention relates to a polyurethane, in particular to a fluorine-containing polyurethane obtained by addition polymerization of side chain perfluoroalkyl polyether glycol and diisocyanate and a preparation method thereof, belonging to the field of polyurethane and fine chemicals. Background technique [0002] Polyurethane is a block-type polymer formed by the addition polymerization of polyether and diisocyanate with alternately bonded soft segments and hard segments. Its unique molecular structure and aggregated structure enable polyurethane to have excellent mechanical properties such as toughness and strength. And has excellent oil resistance, wear resistance and other properties. Because of this, polyurethane has become one of the most widely used polymer materials today. However, traditional polyurethane materials have insufficient weather resistance and water resistance. Because these polyurethanes use diisocyanates containing aromatic ring ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08G18/66C08G18/50C08G18/32C08G18/38C09D175/08C09D5/16C08G65/28
CPCC08G18/3206C08G18/3893C08G18/5015C08G65/2609C09D5/1662C09D175/08
Inventor 李战雄陈蕾遇娜刘群
Owner UPCHEM CHINA
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