A kind of porous carrier of electrode catalyst for proton exchange membrane fuel cell
An electrode catalyst, proton exchange membrane technology, applied in fuel cells, battery electrodes, electrochemical generators, etc., can solve problems such as hindering catalyst use efficiency, catalyst poisoning, complexity, etc., to improve catalytic activity, utilization efficiency, and preparation cost. The effect of low and simple operation of the preparation process
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Embodiment 1
[0027] A kind of porous carrier of the electrode catalyst of proton exchange membrane fuel cell that the present invention proposes, described porous carrier is made of toluenesulfonyl chloride, SiO 2 After reacting with Vulcan XC-72, react with polydimethylsiloxane and azobisisobutylcyanide, and finally react with dimethyl sulfoxide and ethylene glycol dimethacrylate to make a porous carrier; the porous The carrier has a volatile and adjustable porous structure. After being dissolved by solvents with different ratios, it is attached to the electrode, and the negative time and thickness can be adjusted.
[0028] Its preparation method specifically comprises the following steps:
[0029] S1. Weigh toluenesulfonyl chloride and SiO respectively 2 15g each of Vulcan XC-72, heated and stirred with 150ml of dilute HCl, the heating temperature is 120°C, and the stirring time is 1h. After the reaction is complete, the organic phase is obtained by extraction, and excess benzyl peroxid...
Embodiment 2
[0035] A kind of porous carrier of the electrode catalyst of proton exchange membrane fuel cell that the present invention proposes, described porous carrier is made of toluenesulfonyl chloride, SiO 2 After reacting with Vulcan XC-72, react with polydimethylsiloxane and azobisisobutylcyanide, and finally react with dimethyl sulfoxide and ethylene glycol dimethacrylate to make a porous carrier; the porous The carrier has a volatile and adjustable porous structure. After being dissolved by solvents with different ratios, it is attached to the electrode, and the negative time and thickness can be adjusted.
[0036] Its preparation method specifically comprises the following steps:
[0037] S1. Weigh toluenesulfonyl chloride and SiO respectively 2 15g each of Vulcan XC-72, heated and stirred with 140ml of dilute HCl, the heating temperature is 115°C, and the stirring time is 1.2h. After the reaction is complete, the organic phase is obtained by extraction, and excess benzene pero...
Embodiment 3
[0043] A kind of porous carrier of the electrode catalyst of proton exchange membrane fuel cell that the present invention proposes, described porous carrier is made of toluenesulfonyl chloride, SiO 2 After reacting with Vulcan XC-72, react with polydimethylsiloxane and azobisisobutylcyanide, and finally react with dimethyl sulfoxide and ethylene glycol dimethacrylate to make a porous carrier; the porous The carrier has a volatile and adjustable porous structure. After being dissolved by solvents with different ratios, it is attached to the electrode, and the negative time and thickness can be adjusted.
[0044] Its preparation method specifically comprises the following steps:
[0045] S1. Weigh toluenesulfonyl chloride and SiO respectively 2 15g each of Vulcan XC-72, heated and stirred with 160ml of dilute HCl, the heating temperature is 130°C, and the stirring time is 0.8h. After the reaction is complete, the organic phase is obtained by extraction, and excess benzene pero...
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