Pre-synthesized mineralizing agent for silica brick and preparation method thereof
A mineralizer and pre-synthesis technology, applied in crucible furnaces, electric furnaces, drum furnaces, etc., can solve the problems of unstable iron scale composition, impurity ferrous oxide, etc., and achieve controllable ferrous oxide content and iron content distribution Uniform, high ferrous content effect
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[0033] A preparation method of a pre-synthesized silica brick mineralizer, the method is to combine non-ferrous metal smelting and smelting slag composition control, control the smelting slag composition, reaction process and mineral composition, and control the smelting slag by cooling treatment, It is then ground and re-selected, and used as a mineralizer in the production of silica bricks.
[0034] combine figure 1 , the preparation method of described a kind of pre-synthesized silica brick mineralizer, comprises the following steps:
[0035] Step 1. Selection of raw materials, pretreatment and control of slag composition: the silica diluent used, SiO 2 %≥99, the silica raw material must be washed with water to reduce impurities such as loess and alumina introduced into the mountain belt; only add silica to the slag in the later stage of smelting to adjust the composition of the slag; using silica as a diluent and a component adjuster can not only make the slag in the late...
Embodiment 1
[0043] Step 1: Selection of raw materials, pretreatment and control of slag composition. Silica diluent used, SiO 2 %=99.07, the silica raw material is washed with a roller screen;
[0044] Step 2, smelting reaction process and mineral composition control. The copper matte smelting process is adopted, the smelting temperature is 1280 ℃, and the oxidizing atmosphere is controlled for smelting. The conversion result of the composition of the copper smelting charge is (per 100kg): Cu is 26.12kg, Pb+Ag+Zn=4.01kg, S is 31.24kg, Al 2 O 3 1.09kg, SiO 2 is 9.68kg and Fe is 25.67kg. According to SiO 2 : FeO=1:2.08 ratio calculation, FeO of 25.67kg is converted into FeO is 33.02kg, need to add silica 15.88kg. Remove the original 9.68kg of SiO 2 , an additional 6.20kg of SiO is required 2 (i.e. silica); after smelting is completed, after the smelting matte is separated from the slag, the composition test before the slag furnace: the total amount of aluminum oxide, titanium oxide...
Embodiment 2
[0051] The difference between this embodiment and the first embodiment is: according to the iron in the copper ore raw material is converted into ferrous oxide, adding silica to control the mass ratio of SiO 2 : FeO=1:1.9.
[0052] Pre-synthesized silica brick mineralizer composition test: by mass percentage, the total amount of solvents such as aluminum oxide, titanium oxide, potassium oxide and sodium oxide is 0.63% (the above four components in the flux each contain aluminum oxide 0.38% , titanium oxide 0.09%, potassium oxide 0.05%, sodium oxide 0.11%, total flux 0.63%), calcium oxide content 6.52%, silicon oxide content 27.98%, ferrous oxide content 60.94%, iron oxide content 2.03%, oxide The copper content is 0.62%, and the balance of other components is 1.28%. The theoretical iron silicate content in the slag is 85.95%. The results of comparative analysis show that there is almost no difference from Example 1, and the product quality and performance are stable.
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