Graphene modified rubber material with high bending strength

A technology of graphene modification and bending strength, which is applied in the field of graphene modified rubber materials with high bending strength, can solve the problems of poor flame retardancy and mechanical properties of rubber, achieve good flame retardancy, high flame retardancy, and avoid secondary The effect of secondary damage

Inactive Publication Date: 2017-02-22
黄宇
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0007] The technical problem to be solved by the present invention is to provide a graphene-modified rubber material with high bending strength to solve the problems of poor flame retardancy and other mechanical properties of existing rubber

Method used

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  • Graphene modified rubber material with high bending strength

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preparation example Construction

[0069] The preparation method of described high flexural strength graphene modified rubber material may further comprise the steps:

[0070] S1: Pulverize graphene and pass through a 300-500 mesh sieve to obtain powder. The obtained powder is under the conditions of magnetic field strength of 5830-6250GS, ultrasonic power of 350-480W, temperature of 42-53°C, and rotation speed of 200-300r / min , stirring for 22-36min to obtain graphene energy powder;

[0071] S2: adding a surfactant to the graphene energy powder prepared in step S1, and activating it for 0.9-1.4 hours at a temperature of 63-74° C. and a rotation speed of 120-150 r / min to obtain an activated graphene energy powder;

[0072] S3: Under nitrogen protection, add chlorohydrin rubber, neoprene rubber, tributoxyethyl phosphate, dibutyl phthalate, tris(2,4- Di-tert-butylphenyl) phosphite, acrylate stearate, maleic anhydride graft, magnesium hydroxide, kaolin, carbon black, calcium cetyl sulfonate, zinc diethyldithiocar...

Embodiment 1

[0084] A high bending strength graphene modified rubber material, in parts by weight, comprising the following raw materials: 76-104 parts of chlorohydrin rubber, 55 parts of neoprene rubber, 52 parts of graphene, 30 parts of tributoxyethyl phosphate , 20 parts of dibutyl phthalate, 22 parts of tris(2,4-di-tert-butylphenyl) phosphite, 14 parts of acrylate stearate, 20 parts of maleic anhydride graft, 5 parts of magnesium hydroxide 8 parts of kaolin, 7 parts of carbon black, 6 parts of calcium cetyl sulfonate, 8 parts of zinc diethyldithiocarbamate, 14 parts of chlorinated polyethylene, 14 parts of isoprene, 18 parts of amide wax 12 parts of polybutylene terephthalate fiber, 12 parts of simethicone, 10 parts of carbon fiber, 5 parts of polyamide fiber, 7 parts of carboxyethyl cellulose, 0.9 part of surfactant, 0.5 part of initiator , 0.7 parts of chain extender, 0.4 parts of crosslinking agent, 0.3 parts of degassing agent, 0.6 parts of leveling agent, 0.3 parts of catalyst, 0....

Embodiment 2

[0119] A high bending strength graphene modified rubber material, in parts by weight, comprising the following raw materials: 79 parts of chlorohydrin rubber, 50 parts of neoprene rubber, 43 parts of graphene, 24 parts of tributoxyethyl phosphate, ortho 16 parts of dibutyl phthalate, 15 parts of tris(2,4-di-tert-butylphenyl) phosphite, 12 parts of acrylate stearate, 16 parts of maleic anhydride graft, 4 parts of magnesium hydroxide, 7 parts of kaolin, 5 parts of carbon black, 4 parts of calcium cetyl sulfonate, 5 parts of zinc diethyldithiocarbamate, 12 parts of chlorinated polyethylene, 12 parts of isoprene, 14 parts of amide wax, 9 parts of polybutylene terephthalate fiber, 8 parts of dimethyl silicone oil, 7 parts of carbon fiber, 4 parts of polyamide fiber, 5 parts of carboxyethyl cellulose, 0.6 part of surfactant, 0.4 part of initiator, expansion 0.6 parts of chain agent, 0.3 parts of crosslinking agent, 0.3 parts of degassing agent, 0.4 parts of leveling agent, 0.2 parts...

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Abstract

The invention discloses a graphene modified rubber material with high bending strength. The material is prepared from the following raw materials: epichlorohydrin rubber, neoprene rubber, graphene, tributoxyethyl phosphate, dibutyl phthalate, tris(2,4-ditert-butylphenyl)phosphite, stearyl acrylate, maleic anhydride grafted polymer, magnesium hydroxide, kaolin, carbon black, calcium hexadecanesulfonate, zinc diethyldithiocarbamate, chlorinated polyethylene, isoprene, amide wax, polybutylene terephthalate fiber, dimethicone, carbon fiber, polyamide fiber, carboxyethyl cellulose, surfactant, initiator, chain extender, crosslinking agent, degassing agent, leveling agent, catalyst, promoting agent, plasticizer, dispersant, tackifier, curing agent, antibacterial agent, antioxidant, light stabilizer, heat stabilizer, anti-aging agent, ultraviolet absorber, flame retardant and smoke suppressant. The material has good flame retardancy and high impact resistance and toughness, can be widely used in manufacture of tires, hoses, tapes, cables and other products, and has significant economic and social benefits.

Description

technical field [0001] The invention belongs to the technical field of rubber material preparation, and in particular relates to a graphene-modified rubber material with high bending strength. Background technique [0002] Rubber: A highly elastic polymer material with reversible deformation. It is elastic at room temperature, can produce large deformation under a small external force, and can return to its original shape after the external force is removed. Rubber is a completely amorphous polymer, its glass transition temperature (Tg) is low, and its molecular weight is often large, greater than hundreds of thousands. [0003] The word rubber comes from the Indian word cau-uchu, which means "tearful tree". Natural rubber is made by coagulating and drying the latex that flows out from Hevea clover tree tapping. In 1770, British chemist J. Priestley discovered that rubber can be used to erase pencil writing. At that time, the material for this purpose was called rubber, a...

Claims

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Application Information

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IPC IPC(8): C08L71/03C08L11/00C08L67/02C08L83/04C08L77/00C08L1/28C08K13/06C08K9/00C08K3/04C08K3/34C08K7/06
CPCC08K2201/014C08L71/03C08L2201/02C08L2205/035C08L2205/16C08L11/00C08L67/02C08L83/04C08L77/00C08L1/286C08K13/06C08K9/00C08K3/04C08K3/346C08K7/06
Inventor 黄宇
Owner 黄宇
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