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A kind of preparation method of modified montmorillonite adsorbent for treating zinc-containing wastewater

A technology of montmorillonite and adsorbent, which is applied in the field of preparation of modified montmorillonite adsorbent, can solve the problems of not being able to achieve good treatment effect, increase the adsorption performance of zinc ions, and not have too many researches, and achieve high industrial utilization value , Reduce industrial costs, wide range of raw materials

Inactive Publication Date: 2019-07-09
LANZHOU UNIVERSITY OF TECHNOLOGY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The zinc ion adsorption performance of montmorillonite itself is not high, but after specific modification, its zinc ion adsorption performance can be greatly increased
At present, the research on the inorganic and organic modification of montmorillonite to increase its adsorption performance for specific pollutants has been very extensive, but there is not much research on the improvement of its treatment capacity for zinc-containing wastewater through modification. Therefore, applying montmorillonite to the treatment of zinc-containing wastewater often fails to achieve good treatment results.

Method used

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Examples

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Effect test

preparation example Construction

[0020] A preparation method of a modified montmorillonite adsorbent for treating zinc-containing wastewater of the present invention comprises the following steps:

[0021] (1) Preparation of montmorillonite suspension: Purify montmorillonite into 100-150 mesh fine powder materials by washing, drying, crushing, sieving and other pretreatment measures, and mix with distilled water according to the solid-liquid mass ratio of 0.1~0.2 to make montmorillonite suspension;

[0022] (2) Preparation of FN intercalation agent: Mix 1mol / L ferric nitrate solution and 1mol / L sodium hydroxide solution in the following proportions: 10-12mL of 1mol / L ferric nitrate solution, 20-1mol / L sodium hydroxide solution 25mL;

[0023] (3) Inorganic modification of FN intercalation agent: under constant temperature conditions of 60-80°C, the montmorillonite suspension prepared in step (1) and the FN intercalation agent prepared in step (2) were prepared according to 5 : Mix evenly in a ratio of 1 to 3...

Embodiment 1

[0034]The montmorillonite is cleaned, dried, crushed, and sieved, and the montmorillonite fine powder material with a particle size of 140-150 mesh is selected, and the montmorillonite is made into a suspension with a solid-to-liquid mass ratio of 0.1-0.2 with distilled water Prepare the FN intercalation agent with ferric nitrate solution and sodium hydroxide solution, and add it to the montmorillonite suspension for inorganic modification at a constant temperature of 60°C; the FN intercalation modified montmorillonite suspension is subjected to After centrifugation, precipitation, and cleaning for purification, prepare FN intercalation montmorillonite suspension with distilled water at a solid-to-liquid mass ratio of 0.1 to 0.2; prepare SDS intercalation agent with sodium dodecyl sulfate, nitric acid, and absolute ethanol , added to FN intercalated montmorillonite suspension for secondary organic modification; PAM flocculant was prepared with polyacrylamide, nitric acid and di...

Embodiment 2

[0038] The montmorillonite is cleaned, dried, crushed, and sieved, and the montmorillonite fine powder material with a particle size of 100-115 mesh is selected, and the montmorillonite is made into a suspension with a solid-to-liquid mass ratio of 0.1-0.2 with distilled water Prepare the FN intercalation agent with ferric nitrate solution and sodium hydroxide solution, and add it to the montmorillonite suspension for inorganic modification at a constant temperature of 60°C; the FN intercalation modified montmorillonite suspension is subjected to After centrifugation, precipitation, and cleaning for purification, prepare FN intercalation montmorillonite suspension with distilled water at a solid-to-liquid mass ratio of 0.1 to 0.2; prepare SDS intercalation agent with sodium dodecyl sulfate, nitric acid, and absolute ethanol , added to FN intercalated montmorillonite suspension for secondary organic modification; PAM flocculant was prepared with polyacrylamide, nitric acid and d...

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Abstract

A preparation method of a modified montmorillonite adsorbent for treating zinc-bearing wastewater includes the steps of (1), preparing montmorillonite turbid liquid, namely purifying montmorillonite into a fine powder material through pretreatment measurements and preparing the montmorillonite turbid liquid from the fine powder material and distilled water; (2), preparing an FN intercalator; (3), subjecting the FN intercalator to inorganic modification; (4), purifying FN intercalated montmorillonite; (5), preparing an SDS intercalator; (6), subjecting the SDS intercalator to organic modification; (7) preparing a PAM flocculant; (8), purifying SDS intercalated montmorillonite, dropwise adding the PAM flocculant into secondarily-modified montmorillonite turbid liquid obtained in the step (6), stirring evenly rapidly prior to high-speed centrifugation and filtration, washing filter residues with deionized water to be neutral, and drying at a low temperature so as to obtain purified SDS intercalated montmorillonite powder; (9), subjecting the SDS intercalated montmorillonite powder obtained in the step (8) to high-temperature roasting so as to obtain the modified montmorillonite adsorbent.

Description

technical field [0001] The invention relates to the field of industrial sewage treatment, in particular to the preparation technology of a modified montmorillonite adsorbent for treating zinc-containing wastewater. Background technique [0002] In recent years, with the development of the industrial field, people's demand for water resources has gradually increased, and at the same time, the global water pollution problem has become more prominent. Human industrial activities have caused a large amount of sewage discharge, resulting in a gradual increase in the concentration of heavy metal pollutants in the water on the earth's surface, which seriously threatens the survival and living environment of human beings. In particular, the treatment of some highly active heavy metal ion wastewater, such as zinc-containing wastewater, has attracted great attention from the public and many experts due to its difficulty in treatment, poor effect, and high cost, and has become a must i...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01J20/12C02F1/28B01J20/30
CPCB01J20/12C02F1/281
Inventor 周智芳孙寒雪赵霞张婷张庆芳贾小宁
Owner LANZHOU UNIVERSITY OF TECHNOLOGY
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