A kind of preparation method of modified montmorillonite adsorbent for treating zinc-containing wastewater
A technology of montmorillonite and adsorbent, which is applied in the field of preparation of modified montmorillonite adsorbent, can solve the problems of not being able to achieve good treatment effect, increase the adsorption performance of zinc ions, and not have too many researches, and achieve high industrial utilization value , Reduce industrial costs, wide range of raw materials
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[0020] A preparation method of a modified montmorillonite adsorbent for treating zinc-containing wastewater of the present invention comprises the following steps:
[0021] (1) Preparation of montmorillonite suspension: Purify montmorillonite into 100-150 mesh fine powder materials by washing, drying, crushing, sieving and other pretreatment measures, and mix with distilled water according to the solid-liquid mass ratio of 0.1~0.2 to make montmorillonite suspension;
[0022] (2) Preparation of FN intercalation agent: Mix 1mol / L ferric nitrate solution and 1mol / L sodium hydroxide solution in the following proportions: 10-12mL of 1mol / L ferric nitrate solution, 20-1mol / L sodium hydroxide solution 25mL;
[0023] (3) Inorganic modification of FN intercalation agent: under constant temperature conditions of 60-80°C, the montmorillonite suspension prepared in step (1) and the FN intercalation agent prepared in step (2) were prepared according to 5 : Mix evenly in a ratio of 1 to 3...
Embodiment 1
[0034]The montmorillonite is cleaned, dried, crushed, and sieved, and the montmorillonite fine powder material with a particle size of 140-150 mesh is selected, and the montmorillonite is made into a suspension with a solid-to-liquid mass ratio of 0.1-0.2 with distilled water Prepare the FN intercalation agent with ferric nitrate solution and sodium hydroxide solution, and add it to the montmorillonite suspension for inorganic modification at a constant temperature of 60°C; the FN intercalation modified montmorillonite suspension is subjected to After centrifugation, precipitation, and cleaning for purification, prepare FN intercalation montmorillonite suspension with distilled water at a solid-to-liquid mass ratio of 0.1 to 0.2; prepare SDS intercalation agent with sodium dodecyl sulfate, nitric acid, and absolute ethanol , added to FN intercalated montmorillonite suspension for secondary organic modification; PAM flocculant was prepared with polyacrylamide, nitric acid and di...
Embodiment 2
[0038] The montmorillonite is cleaned, dried, crushed, and sieved, and the montmorillonite fine powder material with a particle size of 100-115 mesh is selected, and the montmorillonite is made into a suspension with a solid-to-liquid mass ratio of 0.1-0.2 with distilled water Prepare the FN intercalation agent with ferric nitrate solution and sodium hydroxide solution, and add it to the montmorillonite suspension for inorganic modification at a constant temperature of 60°C; the FN intercalation modified montmorillonite suspension is subjected to After centrifugation, precipitation, and cleaning for purification, prepare FN intercalation montmorillonite suspension with distilled water at a solid-to-liquid mass ratio of 0.1 to 0.2; prepare SDS intercalation agent with sodium dodecyl sulfate, nitric acid, and absolute ethanol , added to FN intercalated montmorillonite suspension for secondary organic modification; PAM flocculant was prepared with polyacrylamide, nitric acid and d...
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