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Photochromic lead and cadmium free low temperature frit and preparation method thereof

A photochromic, low-temperature frit technology, applied in the field of ceramics, can solve the problem of high toxicity

Inactive Publication Date: 2017-02-15
佛山市高明区诚睿基科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, in order to reduce the temperature of the traditional low-temperature frit, a large amount of chemical substances containing lead and cadmium are used. Although the effect of reducing the melting temperature can be achieved, the chemical substances of lead and cadmium are highly toxic.
At the same time, there are few reports about multifunctional low-temperature frits such as antibacterial and photochromic, and the existing technology still needs to be improved and developed.

Method used

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  • Photochromic lead and cadmium free low temperature frit and preparation method thereof

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Effect test

Embodiment 1

[0035] A photochromic lead-free cadmium low-temperature frit and a preparation method thereof, the preparation method comprising the following steps:

[0036] Mixing A: Mix and grind 12% quartz, 12% feldspar, 15% borax, 6% carbonate, 35% boric acid, 5% spodumene, 4% fluoride, and 2% kaolin, then add 1 % antibacterial compound and 8% photochromic compound, grind evenly to make mixture; described feldspar is obtained by mixing potassium feldspar and albite in a weight ratio of 4:1; described carbonate is made of potassium carbonate, Sodium carbonate, barium carbonate, lithium carbonate and calcium carbonate are mixed in a weight ratio of 3:1:3:2:1; the fluoride salt is composed of sodium fluoride, calcium fluoride and lithium fluoride in a weight ratio of 4:2 :1 mixed;

[0037] B melting: the mixture prepared in step A is spread and put into a refractory sagger, and the high temperature melting at 1250-1320 °C is performed to obtain a molten slurry; the high temperature melting...

Embodiment 2

[0049] A photochromic lead-free cadmium low-temperature frit and a preparation method thereof, the preparation method comprising the following steps:

[0050] Mixing A: Mix and grind 15% quartz, 7% feldspar, 22% borax, 9% carbonate, 25% boric acid, 8% spodumene, 3% fluoride, and 3% kaolin, then add 3 % antibacterial compound and 5% photochromic compound, grind evenly to make mixture; described feldspar is obtained by mixing potassium feldspar and albite in a weight ratio of 4:1; described carbonate is made of potassium carbonate, Sodium carbonate, barium carbonate, lithium carbonate and calcium carbonate are mixed in a weight ratio of 3:1:3:2:1; the fluoride salt is composed of sodium fluoride, calcium fluoride and lithium fluoride in a weight ratio of 4:2 :1 mixed;

[0051] B melting: the mixture prepared in step A is spread and put into a refractory sagger, and the high temperature melting at 1250-1320 °C is performed to obtain a molten slurry; the high temperature melting ...

Embodiment 3

[0063] A photochromic lead-free cadmium low-temperature frit and a preparation method thereof, the preparation method comprising the following steps:

[0064] Mixing A: Mix and grind 18% quartz, 5% feldspar, 25% borax, 12% carbonate, 20% boric acid, 6% spodumene, 3% fluoride, and 5% kaolin, then add 5% % antibacterial compound and 1% photochromic compound, grind evenly to make mixture; described feldspar is obtained by mixing potassium feldspar and albite in a weight ratio of 4:1; described carbonate is made of potassium carbonate, Sodium carbonate, barium carbonate, lithium carbonate and calcium carbonate are mixed in a weight ratio of 3:1:3:2:1; the fluoride salt is composed of sodium fluoride, calcium fluoride and lithium fluoride in a weight ratio of 4:2 :1 mixed;

[0065] B melting: the mixture prepared in step A is spread and put into a refractory sagger, and the high temperature melting at 1250-1320 °C is performed to obtain a molten slurry; the high temperature meltin...

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Abstract

The invention discloses a photochromic lead and cadmium free low temperature frit and a preparation method thereof. The preparation method comprises the steps of: A. material mixing: mixing and grinding 10-18% of quartz, 5-12% of feldspar, 15-25% of borax, 3-12% of carbonate, 20-35% of boric acid, 3-8% of spodumene, 1-4% of fluoride salt, and 0-5% of kaolin evenly, then adding 1-5% of an antibacterial compound and 1-10% of a photochromic compound, and grinding the substances uniformly to obtain a mixture; B. melting; and C. cooling molding. Compared with existing low temperature frits, the low temperature frit prepared by the method provided by the invention has the characteristics of scientific compounding, reasonable preparation and stable performance, no lead, cadmium or other extremely toxic substances, and through reasonable collocation with photochromic compounds and antibacterial composite materials, the frit has excellent antibacterial and photochromic properties, thus further broadening the application scope of the low temperature frit. The low temperature frit can be used as the raw material for preparation of rich building materials, like photochromic antibacterial mosaics, photochromic antibacterial microcrystal ceramic composite plates, photochromic antibacterial low-temperature ceramic inks and the like.

Description

technical field [0001] The invention relates to the technical field of ceramics, in particular to a photochromic lead-free cadmium low-temperature frit and a preparation method thereof. Background technique [0002] Bacteria and molds, as pathogenic bacteria, do great harm to humans, animals and plants, affect people's health and even endanger their lives, and bring about significant economic losses. Therefore, the research on antibacterial materials and their products has attracted more and more attention, and the demand for antibacterial products will constitute a huge market. [0003] Photochromism refers to photochromism caused by different light sources and color changes caused by physical phenomena such as reflection, refraction and interference. Photochromic materials are divided into organic photochromic materials and inorganic photochromic materials, among which there are few studies on inorganic photochromic materials, mainly including transition metal oxides, met...

Claims

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Application Information

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IPC IPC(8): C03C8/06A01N25/08A01N59/16A01P1/00A01P3/00C09K9/00
CPCC03C8/06A01N25/08A01N59/16C09K9/00
Inventor 黎淑娟
Owner 佛山市高明区诚睿基科技有限公司
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