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Reverse osmosis concentrated water treatment method

A technology for reverse osmosis concentrated water and a treatment method, which is applied in the field of reverse osmosis concentrated water treatment and can solve the problems of high salt content, large solution chromaticity and high content of dissolved organic matter

Active Publication Date: 2016-12-14
WANHUA CHEM GRP CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, after the reverse osmosis treatment, in addition to obtaining reused water, reverse osmosis concentrated water concentrated 3-5 times (relative to the reclaimed water before reverse osmosis) will be produced. The reverse osmosis concentrated water produced has the following defects: High content of sexual organic matter, large solution chroma, high salt content, poor biodegradability
In summary, the bottleneck of the popularization and application of reverse osmosis concentrated water near-zero discharge process lies in the treatment of high-salt and difficult-to-treat concentrated water obtained after desalination, so it is necessary to develop an efficient and economical reverse osmosis concentrated water near-zero discharge process

Method used

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Effect test

Embodiment 1

[0099] Embodiment 1: the preparation of 1# catalyst

[0100] Take 15g (about 50ml) of spherical alumina carrier from Shandong Zibo Wufeng Aluminum Magnesium Co., Ltd. and place it in a vacuum impregnation bottle for vacuum pretreatment. The vacuum pretreatment time is 30min and the vacuum degree is 96.0KPa; 0.15g / ml nickel nitrate aqueous solution 12ml, iron 0.10g / ml ferric nitrate aqueous solution 2.3ml, manganese 0.10g / ml manganese nitrate aqueous solution 3.0ml, cerium 0.15g / ml cerium nitrate aqueous solution 2.0ml, add into an ethanol aqueous solution with an ethanol concentration of 10 wt%, to prepare an immersion solution with a total volume of 25 ml. Add the above impregnation solution into the vacuum impregnation bottle equipped with the above spherical alumina carrier and mix evenly, then impregnate the above spherical alumina carrier with equal volume, after immersion for 30 minutes, take it out and dry it in an oven at 110°C for 3 hours, and then put it in the Calc...

Embodiment 2

[0102] Embodiment 2: the preparation of 2# catalyst

[0103] Take 15g (about 30ml) of spherical alumina carrier from Shandong Yantai Baichuan Huitong Technology Co., Ltd. and place it in a vacuum impregnation bottle for vacuum pretreatment. The vacuum pretreatment time is 30min and the vacuum degree is 98.0KPa; g / ml nickel nitrate aqueous solution 16ml, ferric nitrate aqueous solution 0.9ml containing iron 0.10g / ml, manganese nitrate aqueous solution 1.5ml containing manganese 0.10g / ml, cerium nitrate aqueous solution 2.5ml containing cerium 0.15g / ml, add to In deionized water, prepare an impregnation solution with a total volume of 21ml. Add the above impregnation solution into the vacuum impregnation bottle equipped with the above spherical alumina carrier and mix evenly, then impregnate the above spherical alumina carrier with an equal volume. After 60 min of impregnation, take it out and dry it in an oven at 130°C for 2 hours, and then put it in the Calcined at 480°C for ...

Embodiment 3

[0105] Embodiment 3: the preparation of 3# catalyst

[0106] Take 15g (about 30ml) of spherical alumina carrier from Shandong Yantai Baichuan Huitong Technology Co., Ltd. and place it in a vacuum impregnation bottle for vacuum pretreatment. The vacuum pretreatment time is 20min and the vacuum degree is 97.5KPa; Add 6.0ml of cerium nitrate aqueous solution per ml to the ethanol aqueous solution with ethanol concentration of 30wt%, and prepare an impregnation solution with a volume of 21ml, add the impregnation solution into a vacuum impregnation bottle and mix evenly, then impregnate the spherical alumina carrier with equal volume , after immersion for 30min, take it out and place it in an oven to dry at 120°C for 3h, and then bake it in a muffle furnace at 500°C for 4h to obtain a cerium-modified alumina carrier. In the obtained cerium-modified alumina carrier, the content of cerium is 2.0wt% based on the weight of alumina.

[0107] Take 15g (about 30ml) of the above-mentione...

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Abstract

The invention discloses a reverse osmosis concentrated water treatment method which comprises the following steps: (1) adding a precipitator and an oxidizing agent into reverse osmosis concentrated water, filtering to obtain a clear liquid, and adding a catalyst used for water treatment into the clear liquid to implement catalytic oxidation to obtain primary treatment water, wherein the acquisition of the primary treatment water further preferentially comprises adsorbing a liquid subjected to catalytic oxidation; (2) performing reverse osmosis treatment on the primary treatment water to obtain secondary reverse osmosis water and secondary reverse osmosis concentrated water; (3) adding the oxidizing agent into the secondary reverse osmosis concentrated water for oxidation to obtain an effluent, wherein the effluent is used for direct discharge, and the acquisition of the effluent further preferentially comprises adsorbing a liquid subjected to oxidation. According to the reverse osmosis concentrated water treatment method, 75-85wt% of water is recycled, the overall use ratio of the water is improved, meanwhile, a small part of water left is treated to reach the discharge standard, the economic input is low, and the method is simple and is easy to operate.

Description

technical field [0001] The invention belongs to the technical field of waste water treatment in environmental engineering, and more specifically relates to a treatment method for concentrated reverse osmosis water. Background technique [0002] In recent years, with the rapid development of the petrochemical industry, the shortage of water resources has become an important factor restricting my country's economic and social development, so the utilization of water resources has received more and more attention. Reverse osmosis can not only effectively remove inorganic salt ions in water, but also remove impurities such as colloids, bacteria, viruses, bacterial endotoxins and most organic substances in water, and has high system stability and low operating costs, so it has become a reclaimed water reuse technology. main technical means. However, after the reverse osmosis treatment, in addition to the reused water, reverse osmosis concentrated water (compared to the reclaimed...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C02F9/04B01J23/889
CPCB01J23/8892C02F9/00C02F1/28C02F1/722C02F1/725C02F1/66C02F1/5236C02F1/76C02F2301/08B01J37/088B01J23/002B01J37/0201B01J2523/00C02F1/283C02F1/441B01J35/31B01J35/40B01J35/51B01J35/615B01J35/638B01J35/651B01J2523/3712B01J2523/72B01J2523/842B01J2523/847C02F1/44B01J21/04B01J37/0207B01J37/0213B01J37/0236
Inventor 张宏科范珍龙王俊俊刘小高段美荣周波王瑞衡华华卫琦
Owner WANHUA CHEM GRP CO LTD
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