High-toughness transparent thermal insulation nano glass coating and preparation method thereof

A nano-glass, high-toughness technology, applied in anti-fouling/underwater coatings, polyurea/polyurethane coatings, coatings, etc., can solve problems such as wrinkling and falling off, affecting heat insulation effect, nano-indium tin oxide denaturation, etc., to achieve Prevents water absorption denaturation, improves toughness and adhesion, and improves dispersibility

Inactive Publication Date: 2016-08-10
ANHUI RONGCHENG GLASS PROD CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] However, the coating film has certain water absorption and water permeability. After absorbing water, it is easy to cause wrinkles and fall off. Nano-indium tin oxide will be denatured under the action of long-term water, which will affect the heat insulation effect. Water resistance needs to be improved.
[0004] In addition, there are still some problems to be solved in the glass coating film, such as heat resistance, wear resistance, antistatic property, toughness, antibacterial property, acid and alkali resistance, transparency, scratch resistance, environmental performance, radiation resistance, anti-discoloration , Flame retardancy, UV resistance and other properties will have different requirements in different occasions. The current coatings still cannot meet the needs of all environments, and the performance needs to be further improved to meet the needs of production.

Method used

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Embodiment Construction

[0014] A high-toughness transparent heat-insulating nano-glass coating, made of the following raw materials in parts by weight (kg): 20 nanometer antimony tin oxide, dispersant SN-5040 0.2, water-based polyurethane resin 79, deionized water 30, cellulose acetate 0.6 , N, N'-dimethylformamide 40, 20% sulfuric acid solution 20, perfluorooctanoic acid 20, methyl methacrylate 3, potassium persulfate 0.1, isocyanate 3, nano rubber fiber 1.2, ascorbic acid 0.2.

[0015] The preparation method of described high-toughness transparent heat-insulating nano-glass coating comprises the following steps:

[0016] (1) Mix nano-antimony tin oxide, cellulose acetate and perfluorooctanoic acid into N,N'-dimethylformamide, ultrasonicate for 30 minutes, then add sulfuric acid solution dropwise while stirring, and then heat to 80°C to stir the reaction After 20 minutes, after finishing the reaction, filter and vacuum-dry to obtain fluorinated nano-indium tin oxide;

[0017] (2) Add dispersant SN-...

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Abstract

The invention discloses a high-toughness transparent thermal insulation nano glass coating .The high-toughness transparent thermal insulation nano glass coating is prepared from, by weight, 20-21 parts of nano tin antimony oxide, 0.2-0.3 part of a dispersing agent SN-5040, 79-81 parts of waterborne polyurethane resin, 30-35 parts of deionized water, 0.6-0.8 part of cellulose acetate, 40-50 parts of N,N'-dimethyl formamide, 20-22 parts of a 20% sulfuric acid solution, 20-22 parts of perfluoro caprylic acid, 3-4 parts of methyl methacrylate, 0.1-0.2 part of potassium peroxodisulfate, 3-3.5 parts of isocyanate, 1.2-1.3 parts of nano rubber fiber and 0.2-0.3 part of ascorbic acid .The ascorbic acid is used for modifying the nano rubber fiber, the ageing resistance of the nano rubber fiber is improvd, and the dispersity of the nano rubber fiber is further improved, so that the toughness and adhesive force of the coating are improved, and the toughness and mildew resistance of the coating are improved due to the adoption of cellulose acetate .

Description

technical field [0001] The invention relates to the technical field of glass coatings, in particular to a high-toughness transparent heat-insulating nano-glass coating and a preparation method thereof. Background technique [0002] As society pays more and more attention to energy saving and environmental protection requirements, insulating glass that can be used in different places has become a common demand of people, but the existing insulating glass has the disadvantages of imperfect performance, complicated process or high cost. Nano antimony tin oxide (ATO) has good visible light transmittance and infrared barrier, and is an ideal heat insulation material. The method of adding nano-tin antimony oxide into the paint to make a transparent heat-insulating paint can effectively solve the heat-insulating problem of glass. Compared with similar products, it has the advantages of simple process and low cost, and has extremely high application value and broad application value...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D175/04C09D101/12C09D5/14C09D7/12
CPCC08K2201/011C08L2201/10C08L2205/03C08L2205/16C09D5/14C09D7/62C09D7/63C09D7/65C09D175/04C08L1/12C08L21/00C08K9/04C08K3/2279C08K5/1535C08K5/29
Inventor 程言俊
Owner ANHUI RONGCHENG GLASS PROD CO LTD
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