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Cu/Mo/Cu laminated metal coiled strip and continuous machining method

A technology of layered metal and processing method, applied in the direction of metal layered products, chemical instruments and methods, layered products, etc., can solve the problems of complex plate method, dangerous production process, difficult realization, etc., and achieve the guarantee Product quality consistency, good production application value, and the effect of reducing production costs

Active Publication Date: 2016-06-01
重庆金荣金属有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] Commonly used preparation methods include welding compounding, electroplating compounding, explosive compounding, etc., such as the publication numbers CN1843691A and CN1850436A, and the public dates are October 11, 2006 and October 25, 2006. The plate-shaped copper-clad plate-shaped molybdenum is joined to form a compound Plates cannot be produced continuously, and need to undergo repeated annealing and rolling, the process is cumbersome, non-continuous large-scale production, low production efficiency, and difficult to control quality consistency
[0006] The invention patent of Zhu Yubin et al. "Preparation method of a copper-molybdenum-copper layered composite material", publication number CN102527747.A, cleans the surface of the copper plate and the molybdenum plate, cuts them into the same size, alternately superimposes and loads the pressing blocks, and stacks them Push it into the hydrogen furnace and keep it warm for (60-100) minutes to complete the three-metal diffusion bonding. The production efficiency is low and it is not suitable for large-scale production
[0007] The invention patent of Wang Zhifa and others "Manufacturing method of copper-molybdenum-copper three-layer composite board", such as publication number: CN1408485, adopts the principle of solid-liquid combination of melting and casting, places electrolytic copper plates on both sides of molybdenum ingots, and heats the copper plates to melt and molybdenum plates Solid-liquid combination of the billet, followed by hot rolling, annealing, and rolling to the finished product. The combination process is complicated, and the thickness ratio control of the molybdenum layer and the copper layer is limited, which cannot meet the product quality requirements
[0008] The invention patent of Wang Dezhi et al. "Preparation method of high bonding strength and high precision copper-molybdenum-copper laminated composite material", application number: 201210433614. Composite plates are thinned by cold rolling. Because molybdenum is easy to oxidize, the bonding strength of this process is not easy to control, and the product is only layered metal sheets, which leads to low production efficiency.
[0009] Zhang Jiayu and others invented the patent "A Preparation Method of Copper-Molybdenum-Copper Layered Composite Metal Material", patent number: CN102371719A, the method of obtaining a composite board through two explosive composites is relatively complicated, the production process is dangerous, and the cost is high. Suitable for large-scale production
[0010] U.S. patents (US4950554, US4988392, US4957823) use welding and rolling methods to prepare copper-molybdenum-copper materials, which have high requirements for welding equipment, are difficult to realize, and are prone to local welding defects, and the preparation cost is also high.

Method used

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  • Cu/Mo/Cu laminated metal coiled strip and continuous machining method
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  • Cu/Mo/Cu laminated metal coiled strip and continuous machining method

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Experimental program
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Effect test

Embodiment 1

[0040]1. Surface cleaning: Unwind the copper (Cu) tape with a thickness of 1.0mm on the equipment with the function of rewinding and unwinding, continuously degrease online, pickle with 10% dilute sulfuric acid, and polish with a round scouring pad , Rinse with pure water; Unwind the molybdenum (Mo) tape with a thickness of 1.8mm on the equipment with the function of rewinding and unwinding, continuously degrease online, pickle with 20% acid solution, polish with round steel wire brush wheel, clean Rinse with water.

[0041] 2. Hot-rolling and compounding: Unwind the cleaned (Cu, Mo, Cu) three-metal coils and strips, and enter the corresponding heating temperature zones of the heating furnace respectively, Cu enters the 750°C heating temperature zone, and Mo enters the 950°C heating Temperature zone, at 10m 3 / h Under the protection of ammonia decomposition gas or hydrogen, enter the 100-ton rolling mill at the same time, with a deformation of 33%, rolling to a thickness of 2...

Embodiment 2

[0049] 1. Surface cleaning: unwind the copper (Cu) tape with a thickness of 0.7mm, and continuously degrease, pickle with 15% dilute sulfuric acid, and polish with a round scouring pad polishing sheet on the equipment with the function of rewinding and unwinding Rinse with pure water; molybdenum (Mo 70 Cu) Tape, unwinding, continuous degreasing, 20% acid pickling, round steel wire brush wheel polishing, and pure water washing on the equipment with winding and unwinding functions.

[0050] 2. Hot-rolled composite: the cleaned (Cu, Mo 70 Cu, Cu) three metal coils and strips are unwound, respectively enter the corresponding heating temperature zone of the heating furnace, Cu enters the 700 ° C heating temperature zone, Mo 70 Cu enters the 900°C heating temperature zone, at 10m 3 / h Under the protection of ammonia decomposition gas or hydrogen, enter the 100-ton rolling mill at the same time, with a deformation of 42%, rolling to a thickness of 1.4mm, and completing the three-me...

Embodiment 3

[0058] 1. Surface cleaning: unwind the copper (Cu) tape with a thickness of 0.1mm, and continuously degrease, pickle with 15% dilute sulfuric acid, and polish with a round scouring pad polishing sheet on the equipment with the function of rewinding and unwinding Rinse with pure water; molybdenum (Mo 60 Cu) Tape, unwinding, continuous degreasing, 20% acid pickling, round steel wire brush wheel polishing, and pure water washing on the equipment with winding and unwinding functions.

[0059] 2. Hot-rolled composite: the cleaned (Cu, Mo 60 Cu, Cu) three metal coils and strips are unwound, respectively enter the corresponding heating temperature zone of the heating furnace, Cu enters the 600 ℃ heating temperature zone, Mo 60 Cu enters the 800°C heating temperature zone, at 3m 3 / h Under the protection of ammonia decomposition gas or hydrogen, enter the 45-ton rolling mill at the same time, with a deformation of 30%, and roll to a thickness of 0.4mm. At a rolling speed of 10m / min,...

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Abstract

The invention discloses a Cu / Mo / Cu laminated metal coiled strip and a continuous machining method. The method comprises the steps of surface cleaning, hot-rolling compositing, semi-finished product surface cleaning, semi-finished product rolling, continuous bright annealing, finished product rolling, finishing and striping. The length of the finished Cu / Mo / Cu laminated metal coiled strip manufactured by the adoption of the method can reach dozens of meters and even hundreds of meters, production efficiency can be improved, production cost can be lowered, uniformity of product quality is ensured, and the Cu / Mo / Cu laminated metal coiled strip is suitable for large-scale continuous production and has high production and application value.

Description

technical field [0001] The patent of the invention relates to the field of processing layered metal coils and strips, in particular to a CMC layered metal coils and strips with high thermal conductivity and low expansion coefficient and a continuous processing method. Background technique [0002] Cu / Mo / Cu(CMC) layered metal is a new type of electronic packaging material with high thermal conductivity and low expansion coefficient. It has excellent thermal conductivity and adjustable thermal expansion coefficient. It is the first choice for electronic packaging of high-power electronic components at home and abroad. Materials and heat sink heat dissipation materials are widely used in microwave, communication, radio frequency, aerospace, power electronics, high-power semiconductor lasers, medical and other industries. For example, the internationally popular BGA package uses this material as a substrate in large quantities. In addition, in the field of microwave packaging a...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B32B15/01C22F1/02C22F1/08C22F1/18
CPCB32B15/01B32B2250/03C22F1/02C22F1/08C22F1/18
Inventor 胡传凯
Owner 重庆金荣金属有限公司
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