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Efficient sulfur/carbon coated lithium nickelate cathode material and preparation method thereof

A cathode material, lithium nickelate technology, which is applied in the field of high-efficiency sulfur/carbon-coated lithium nickelate cathode material and its preparation, can solve the problems of restricting development prospects, lack of nickel resources, toxicity, etc., and achieve extended storage time, Improved self-discharge, the effect of a simple method

Inactive Publication Date: 2016-05-25
王晓伟
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  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0002] Since the commercialization of lithium-ion batteries, most of the positive electrode materials used in lithium-ion batteries are lithium nickelate, lithium manganate or ternary materials, etc., and its components are mainly lithium nickelate plus conductive agent and then binder. Lithium oxide is lithium nickelate, lithium manganate or ternary, etc.; most of the negative electrode materials use graphite as the active material, and then add some conductive agent and binder; its advantages are high capacity and long cycle life, but nickel resources are scarce, Expensive and toxic, so it is an important research direction for lithium-ion batteries to seek affordable, reliable, and environmentally friendly cathode materials
Spinel-type positive electrode materials represented by lithium manganate and layered oxides of ternary materials have been widely studied in the past decade, but their development prospects are restricted by their respective defects.

Method used

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Embodiment Construction

[0011] The high-efficiency sulfur / carbon-coated lithium nickelate positive electrode material is prepared by the following components according to the ratio shown in parts by weight, sulfur / carbon composite material 45%, lithium nickelate 45%, 45% lithium iron nitrate solution 30% , flake graphite 8, bonding material 8. The 45% lithium iron nitrate solution is a 60% lithium iron nitrate solution. The positive electrode material is lithium nickelate. The conductive agent is flake graphite

[0012] The preparation method of the high-efficiency sulfur / carbon-coated lithium nickelate cathode material comprises the following steps:

[0013] (1) Put the carbon material and sublimated sulfur or sulfur powder into a zirconia or agate ball mill jar according to the above weight ratio, inject the ball mill jar into a high-purity inert gas in the glove box, and place it on a planetary ball mill for 5 hours. The ball milling speed is 500r / min, the mass ratio of elemental sulfur and car...

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Abstract

The invention relates to an efficient sulfur / carbon coated lithium nickelate cathode material and a preparation method thereof. The efficient sulfur / carbon coated lithium nickelate cathode material is prepared from the following components in parts by weight: 45 parts of sulfur / carbon composite material, 45 parts of lithium nickelate, 30 parts of 45% lithium iron nitrate solution, 8 parts of flake graphite and 8 parts of binding material. The efficient sulfur / carbon coated lithium nickelate cathode material overcomes the defect of failure of lithium ion batteries caused by self-discharge of protection boards, so that self-discharge of the whole battery pack is improved, the aim of prolonging the storage time of lithium batteries is achieved, and the lithium batteries can be stored for a longer time under the condition that users do not charge electric appliances after using the electric appliances.

Description

technical field [0001] The invention relates to a high-efficiency sulfur / carbon coated lithium nickelate cathode material and a preparation method thereof. Background technique [0002] Since the commercialization of lithium-ion batteries, most of the positive electrode materials used in lithium-ion batteries are lithium nickelate, lithium manganate or ternary materials, etc., and its components are mainly lithium nickelate plus conductive agent and then binder. Lithium oxide is lithium nickelate, lithium manganate or ternary, etc.; most of the negative electrode materials use graphite as the active material, and then add some conductive agent and binder; its advantages are high capacity and long cycle life, but nickel resources are scarce, It is expensive and toxic, so it is an important research direction for lithium-ion batteries to seek cheap, reliable, and environmentally friendly cathode materials. Spinel-type cathode materials represented by lithium manganate and lay...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01M4/36H01M4/38H01M4/525H01M4/587H01M10/0525
CPCH01M4/366H01M4/38H01M4/525H01M4/587H01M10/0525Y02E60/10
Inventor 王晓伟
Owner 王晓伟
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